Abstract
Time-resolved fluorescence up-conversion experiments have been performed for a few fluorescent organic charge transfer molecules in liquid solution. Dynamic Stokes shifts have been measured, with a time resolution of 150 fs, for the probe molecules in alcoholic and ethereal solvents. The results reveal solvation dynamics determined by “inertial free streaming” motions of the solvent molecules in the solvent cages and rotational diffusion motions of the solvent molecules. Simulations of the temporal changes in the fluorescence spectra based on the Smoluchowski diffusion equation are also briefly discussed.
Similar content being viewed by others
References
B.M. Kosower and D. Huppert: Ann. Rev. Phys. Chem.37 (1986) 127.
J.D. Simon: Acc. Chem. Res.21 (1988) 128.
M. Maroncelli, J. MacIniis, and G.R. Fleming: Science243 (1989) 1674.
B. Bagchi: Annu. Rev. Phys. Chem.40 (1989) 115.
P.F. Barbara and W. Jarzeba: Adv. Photochem.15 (1990) 1.
J.T. Hynes: Nature369 (1994) 439.
P.J. Rossky and J.D. Simon: Nature370 (1994) 263.
G.R. Fleming:Chemical Applications of Ultrafast Spectroscopy, Oxford Univ. Press, New York, 1986.
H. Zhang, A.M. Jonkman, P. van der Meulen, and M. Glasbeek: Chem. Phys. Lett.224 (1994) 551.
E.R. Middelhoek, H. Zhang, J.W. Verhoeven, and M. Glasbeek: Chem. Phys.211 (1996) 489.
P. van der Meulen, H. Zhang, A.M. Jonkman, and M. Glasbeek: J. Phys. Chem.100 (1996) 5367.
A.M. Jonkman, P. van der Meulen, H. Zhang, and M. Glasbeek: Chem. Phys. Lett.256 (1996) 21.
E.R. Middelhoek, H. Zhang, J.W. Verhoeven, and M. Glasbeek: Chem. Phys. Lett.267 (1997) 525.
M. Maroncelli and G.R. Fleming: J. Chem. Phys.86 (1987) 6221.
D. Chandler:Introduction to modern statistical mechanics, Oxford University Press, New York, 1987.
M.L. Horng, J. Gardecki, A. Papazyan, and M. Maroncelli: J. Phys. Chem.99 (1995) 17311 and references therein.
P. van der Meulen, A.M. Jonkman, and M. Glasbeek: J. Phys. Chem.102 (1998) 19.
K. Tominaga, G.C. Walker, W. Jarzeba, and P.F. Barbara: J. Phys. Chem.95 (1991) 10475.
K. Tominaga, G.C. Walker, T.J. Kang, P.F. Barbara, and T. Fonseca: J. Phys. Chem.95 (1991) 10485.
E.R. Middelhoek, R. Brown, and M. Glasbeek: to be published.
Author information
Authors and Affiliations
Additional information
This work was supported in part by the Netherlands Foundation for Chemical Research (SON) with financial aid from the Netherlands Organization for Scientific Research (NWO).
Rights and permissions
About this article
Cite this article
Glasbeek, M. Femtosecond solvation and charge transfer dynamics in liquid solution. Czech J Phys 48, 417–422 (1998). https://doi.org/10.1023/A:1021237607884
Received:
Issue Date:
DOI: https://doi.org/10.1023/A:1021237607884