Abstract
The influence of 30% (v/v) organic cosolvent in 1.0 mol dm−3 HClO4 on the OER electrode kinetics, surface properties and electrode stability of IrO2-based electrodes was investigated by cyclic voltammetry and polarization curves. The Tafel coefficients in the presence of cosolvent are explained in terms of the change of the rate-determining step (r.d.s.) of the OER electrode mechanism, coating dissolution and/or cosolvent oxidation. Of the several cosolvents investigated t-BuOH and PC show less effects on the OER and electrode properties making them the best choice for organic eletrosynthesis applications, in contrast to AN, which causes coating dissolution, and DMF and DMSO which show an anticipation of the voltammetric current.
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References
S. Trasatti (Ed.), ‘Electrodes ofConductive Metallic Oxides', Parts A and B (Elsevier Science, Amsterdam, 1980/1981).
J. Krýsa, J. Maixner, R. Mráz and I. Rousar, J. Appl. Electrochem. 28 (1998) 369.
J. Krýsa, L. Kule, R. Mráz and I. Rousar, J. Appl. Electrochem. 26 (1996) 999.
Ch. Comninellis and A. De Battisti, J. Chim. Phys. 93 (1996) 673.
G. Fóti, D. Gandini and Ch. Comninellis, Curr. Top. in Eletrochem. 5 (1997) 71.
A.M. Couper, F.C. Walsh and D. Pletcher, Chem. Rev. 90 (1990) 837.
C.L.P.S. Zanta, A.R. de Andrade and J.F.C. Boodts, Electrochim. Acta 44 (1999) 3333.
A.R. de Andrade, J.F.C. Boodts and C.L.P.S. Zanta, Abstract 964, p. 1206, The Electrochemical Society Meeting Abstracts, Vol. 96-1, Los Angeles, CA, 5–10, May (1996).
P.G. Pickup and V.I. Birss, J. Electrochem. Soc. 135 (1988) 41.
L.A. Silva, V.A. Alves, M.P.A. Silva, S. Trasatti and J.F.C. Boodts, Electrochim. Acta. 42 (1997) 271.
E.J.M. O'sullivan and J.R. White, J. Electrochem. Soc. 136 (1989) 2576.
D.T. Sawyer and J.L. Roberts, Jr, ‘Experimental Electrochemistry for Chemists’ (J. Wiley & Sons, 1974), p. 174.
Y. Marcus, Chem. Soc. Rev. (1993) 409.
M. Sandström, I. Person and P. Person, Acta Chem. Scand. 44 (1990) 653.
R.N. Singh, J.F. Köenig, G. Poillerat and P. Chartier, J. Electrochem. Soc. 137 (1990) 1408.
P. Siviglia, A. Daghetti and S. Trasatti, Colloids Surf. 7 (1983) 15.
D.M. Shub and M.F. Reznik, Elektrokhimiya 21 (1985) 855.
D.M. Shub, M.F. Reznik and V.V Shalaginov, Elektrokhimiya 21 (1985) 937.
S. Trasatti, in H. Wendt (Ed.), ‘Electrochemical Hydrogen Technologies’ (Elsevier Science, Amsterdam, 1990).
L.I. Krishtalik, Electrochim. Acta 26 (1981) 329.
G.N. Martelli, R. Ornelas and G. Faita, Electrochim. Acta 39 (1994) 1551.
S.M. Lin and T-C. Wen, J. Electrochem. Soc. 140 (1993) 2265.
T.A.F. Lassali, J.F.C. Boodts and L.S. Bulhões, J. Appl. Electrochem. 30 (2000) 625.
V.V. Gorodetskii, V.A. Neburchilov and M.M. Pecherskii, Russ. J. Electrochem. (Transl. Elektrokhimiya) 30 (1994) 916.
T.A.F. Lassali, J.F.C. Boodts and L.O.S. Bulhões, Electrochim. Acta. 44 (1999) 4203.
L.A. Silva, V.A. Alves, M.P.A. Silva, S. Trasatti and J.F.C. Boodts, Can. J. Chem. 75 (1997) 1483.
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Rossi, A., Boodts, J. Ir-based oxide electrodes: oxygen evolution reaction from mixed solvents. Journal of Applied Electrochemistry 32, 735–741 (2002). https://doi.org/10.1023/A:1020153519978
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DOI: https://doi.org/10.1023/A:1020153519978