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Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine

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Abstract

The structure of poly-μ-pyrazine-bis(pyrazine)(dinitrato-O)copper(II), Cu(pyz)3(NO3)2, has been investigated by X-ray diffraction. The compound crystallizes in the triclinic space group \(P\bar 1\) with a = 6.8040 (10), b = 7.2860 (10), c = 9.289 (2) Å, α = 69.65 (2), β = 68.51 (2), γ = 67.51 (2)°, and Z = 1. The structure consists of linear chains of copper ions bridged by bidentate pyrazine groups, with monodentate terminal pyrazine and nitrate groups completing the distorted octahedral geometry about the copper ions.

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Authors and Affiliations

  1. Department of Chemistry, Moore 337, Eastern Kentucky University, Richmond, Kentucky, 40475-3102

    Tom Otieno, Ann M. Gipson & Sean Parkin

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  1. Tom Otieno
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  2. Ann M. Gipson
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  3. Sean Parkin
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Correspondence to Tom Otieno.

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Otieno, T., Gipson, A.M. & Parkin, S. Synthesis and X-ray characterization of a polymeric 1:3 complex of copper(II) nitrate with pyrazine. Journal of Chemical Crystallography 32, 81–85 (2002). https://doi.org/10.1023/A:1015612810446

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