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Structural characterization of a mixed-ligand complex of copper(II) with 1,10-phenanthroline and the m-aminobenzoate ion

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Abstract

A new copper(II) complex of 1,10-phenanthroline (C12H8N2) and the meta-aminobenzoate ion (m-amb; C7H6NO −2 ), having the formula Cu(C12H8N2)(C7H6NO2)Cl∙0.5H2O, is prepared and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The structure is built up from monomeric units in which the coordination environment around the metal ion is a square plane arising from a bidentate 1,10-phenanthroline molecule, a monodentate m-amb anion, and a chloride ion. A very long (Cu–N = 2.856(5) Å) bond to the nitrogen atom of an adjacent m-amb ion generates [101] polymeric chains in the crystal. The crystal structure is consolidated by N–H∙∙∙O and O–H∙∙∙O hydrogen bonds and C–H∙∙∙O, C–H∙∙∙Cl, and aromatic π–π stacking interactions. Crystal data: C19H15ClCuN3O2.5, M r = 424.33, monoclinic, P21/n (No. 14), a = 9.8200(5) Å, b = 10.9291(7) Å, c = 16.3803(9) Å, β = 105.293(3)°, V = 1695.74(17) Å3, Z = 4, R(F) = 0.043, wR(F 2) = 0.122.

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Authors and Affiliations

  1. Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan

    S. S. Batool & S. R. Gilani

  2. Department of Physics, Sargodha University, Sargodha, Pakistan

    M. N. Tahir

  3. Department of Chemistry, University of Aberdeen, Aberdeen, Scotland

    W. T. A. Harrison

Authors
  1. S. S. Batool
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  2. S. R. Gilani
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  3. M. N. Tahir
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  4. W. T. A. Harrison
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Corresponding author

Correspondence to S. R. Gilani.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 1041-1046, June-July, 2016.

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Batool, S.S., Gilani, S.R., Tahir, M.N. et al. Structural characterization of a mixed-ligand complex of copper(II) with 1,10-phenanthroline and the m-aminobenzoate ion. J Struct Chem 57, 991–996 (2016). https://doi.org/10.1134/S0022476616050206

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  • DOI: https://doi.org/10.1134/S0022476616050206

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