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Synthesis and Crystal Structures of Complexes of Zinc, Silver, Copper Assembled by Uniconazole

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Abstract

Three coordination polymers [ZnL4Cl2]n(1), [(AgL2·NO3)2]n(2), [CuL4·2NO3]n(3) (L = uniconazole) have been synthesised and structurally characterized by element analysis, infrared spectra and X-ray crystal diffraction. Complex 1 is the triclinic system, space group P-1 with a = 8.9407(10) Å, b = 13.2994(15) Å, c = 14.9242(17) Å, α = 93.8180(10)°, β = 99.0250(10)°, γ = 104.7690(10)°, V = 1684.1(3) Å3. Complex 2 is the Triclinic system, space group P-1 with a = 8.997(3) Å, b = 16.941(5) Å, c = 24.113(7) Å, α = 89.182(4)°, β = 86.440(4)°, γ = 86.440(4)°, V = 3483.0(19) Å3. Complex 3 is the triclinic system, space group P-1 with a = 8.7387(5) Å, b = 13.4087(8) Å, c = 15.4353(9) Å, α = 87.8870(10)°, β = 80.7150(10)°, γ = 71.3930(10)°, V = 1691.42(17) Å3. In 1 and 3, Each six-coordinated Zn(II), Cu(II) ions adopts a distorted octahedral geometry. 1 and 3 was linked into a one dimensional chain by intermolecular hydrogen bonds. But in 2, each Ag(I) ion is two-coordinated in a linear mode. Althought there is many intermolecular hydrogen bonds, but the complex is zero dimensional.

Graphical Abstract

Three new coordination polymers [ZnL4Cl2]n(1), [(AgL2·NO3)2]n(2), [CuL4·2NO3]n(3) (L = uniconazole) have been synthesised and structurally characterized by element analysis, infrared spectra and X-ray crystal diffraction.

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Acknowledgements

This work was supported by The National Natural Science Foundation of China (Nos. 21563014), The Research Foundation of Educational Department of Jiangxi Province [No. GJJ160382]. X-ray data were collected at Instrumental Analysis Center Nanchang Hangkong University, Nanchang, 330063, People’s Republic of China.

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Authors and Affiliations

  1. Key Laboratory of Natural Product Research and Development, Nanchang, 330045, China

    Xu-Liang Nie & Xin-Chen Shang-Guan

  2. College of Forestry, Jiangxi Agricultural University, Nanchang, 330045, China

    Xu-Liang Nie

  3. College of Science, Jiangxi Agricultural University, Nanchang, 330045, China

    Xu-Liang Nie, Xiu-Ying Song, Chang-Gan Huang & Lei Gong

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  1. Xu-Liang Nie
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  2. Xiu-Ying Song
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Correspondence to Xin-Chen Shang-Guan.

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Nie, XL., Song, XY., Huang, CG. et al. Synthesis and Crystal Structures of Complexes of Zinc, Silver, Copper Assembled by Uniconazole. J Chem Crystallogr 47, 120–127 (2017). https://doi.org/10.1007/s10870-017-0688-9

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  • DOI: https://doi.org/10.1007/s10870-017-0688-9

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