Abstract
Tri(p-tolyl)antimony dichloride was prepared by oxidation of tri(p-tolyl)stibine with chlorine or copper(II) chloride. As found by X-ray diffraction analysis, the antimony atom in tri(p-tolyl)antimony dichloride has the configuration of trigonal bipyramid with axially located chlorine atoms. The Sb-Cl and Sb-C distances are 2.476(2) and 2.104(7) Å, and the CSbC and ClSbCl angles are 120 and 180°, respectively.
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Sharutin, V.V., Sharutina, O.K., Pakusina, A.P. et al. Synthesis and Structure of Tri(p-tolyl)antimony Dichloride. Russian Journal of General Chemistry 72, 392–393 (2002). https://doi.org/10.1023/A:1015491517061
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DOI: https://doi.org/10.1023/A:1015491517061