Skip to main content
SpringerLink
Log in

Tri(meta-tolyl)antimony chloro(benzenesulfonate): synthesis and structure

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Tri(meta-tolyl)antimony chloro(benzenesulfonate) (I) has been synthesized by the reaction between tri(meta-tolyl)antimony bis(benzenesulfonate) and tri(meta-tolyl)antimony dichloride (toluene; 0.5 h, 100°C). According to X-ray diffraction data, the antimony atoms in two crystallographically independent molecules Ia and Ib have a distorted trigonal bipyramidal coordination to chlorine and oxygen atoms in axial positions: OSbCl, 177.8(4)° (Ia), 178.6(4)° (Ib); CSbC, 114.0(9)°‒127.6(8)° (Ia), CSbC, 114.4(8)°‒128.0(8)° (Ib); Sb‒C, 2.01(2)‒2.139(18) Å, Sb‒Cl, 2.453(7) Å, Sb‒O, 2.163(13) Å (Ia), Sb‒C, 2.07(2)‒2.14(2) Å, Sb‒Cl, 2.442(7) Å; Sb‒O, 2.187(14) Å (Ib).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. K. Sharutina and V. V. Sharutin, Molecular Structures of Organic Compounds of Antimony(V) (Izdat. Tsentr YuUrGU, Chelyabinsk, 2012) [in Russian].

    Google Scholar 

  2. V. V. Sharutin, O. K. Sharutina, and O. V. Molokova, Butlerov. Soobshch. 28 (19), 45 (2011).

    Google Scholar 

  3. V. V. Sharutin, O. K. Sharutina, and V. S. Senchurin, Russ. J. Inorg. Chem. 60, 166 (2015).

    Article  CAS  Google Scholar 

  4. L. Quan, H. Yin, and D. Wang, Acta Crystallogr., Sect. E 64, m1302 (2008).

    Article  Google Scholar 

  5. L. Quan, H. Yin, J. Cui, et al., J. Organomet. Chem. 694, 3708 (2009).

    Article  CAS  Google Scholar 

  6. SMART and SAINT-Plus: Data Collection and Processing Software for the SMART System. Versions 5.0 (Bruker, Madison, WI, USA, 1998).

    Google Scholar 

  7. Bruker (1998). SHELXTL/PC: An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Versions 5.10 (Bruker, Madison, WI, USA, 1998).

    Google Scholar 

  8. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009).

    Article  CAS  Google Scholar 

  9. V. V. Sharutin, O. K. Sharutina, T. P. Platonova, et al., Zh. Obshch. Khim. 73, 380 (2003).

    Google Scholar 

  10. V. V. Sharutin, O. K. Sharutina, I. I. Pavlushkina, et al., Zh. Obshch. Khim. 70, 1308 (2000).

    Google Scholar 

  11. S. S. Batsanov, Zh. Neorg. Khim. 36, 3015 (1991).

    CAS  Google Scholar 

  12. T. N. Polynova and M. A. Porai-Koshits, Zh. Strukt. Khim. 1, 159 (1960).

    CAS  Google Scholar 

  13. M. J. Begley and D. B. Sowerby, Acta Crystallogr., Sect. C 49, 1044 (1993).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. South Ural State University (National Research University), 76, Lenin prospekt, Chelyabinsk, Russia, 454080

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

Authors
  1. V. V. Sharutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. K. Sharutina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Senchurin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Sharutin.

Additional information

Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 6, pp. 744–747.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharutin, V.V., Sharutina, O.K. & Senchurin, V.S. Tri(meta-tolyl)antimony chloro(benzenesulfonate): synthesis and structure. Russ. J. Inorg. Chem. 61, 708–711 (2016). https://doi.org/10.1134/S0036023616060164

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023616060164

Search

Navigation