Abstract
Tri(o-tolyl) antimony dioximates were synthesized by the reaction of tri(o-tolyl) antimony with 5-nitrofurfural and thiophen-2-carbaldehyde oximes in ether in the presence of hydrogen peroxide or tert-butylhydroperoxide (1: 2: 1 mol). Antimony atoms in the reaction products have distorted trigonal-bipyramidal coordination with the intramolecular distances Sb···N shorter than the sum of the van der Waals radii of Sb and N by ~1 Å.
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Tiekink, E.R.T., Crit. Rev Oncol. Hematol., 2002, vol. 42, no. 3, p. 217. doi 10.1016/S1040-8428(01)00217-7
Ozturk, I.I., Banti, C.N., Manos, M.J., Tasiopoulos, A.J., Kourkoumelis, N., Charalabopoulos, K., and Hadjikakou, S.K., J. Inorg. Biochem., 2012, vol. 109, p. 57. doi 10.1016/j.jinorgbio.2012.01.014
Ali, M.I., Rauf, M.K., Badshah, A., Kumar, I., Forsyth, C.M., Junk, P.C., Kedzierski, L., and Andrews, P.C., Dalton Trans., 2013, vol. 42, no. 1, p. 16733. doi 10.1039/C3DT51382C
Yu, L., Ma, Y.-Q., Wang, G.-C., and Li, J.-S., Heteroatom Chem., 2004, vol. 15, p. 32. doi DOI/hc.10208
Bajpai, K. and Srivastava, R.C., Synth. Inorg. Met.-Org. Chem., 1981, vol. 11, no. 1, p. 7. doi 10.1080/00945718108059270
Nakamura, H., Iitaka, Y., Sakakibara, H., and Umezawa, H., J. Antibiotics, 1974, no. 27, p. 894. doi 10.7164/antibiotics.6. 27.894
Handong, Y., Li, Q, and Linwei, L., Inorg. Chem. Commun., 2008, no. 11, p. 1121. doi 10.1016/j.inoche.2008.06.017
Gupta, A., Sharma, R.K., Bohra, R., Jain, V.K., Drake, J.E., Hursthouse, M.B., and Light, M.E., Polyhedron, 2002, vol. 21, no. 23, p. 2387. doi 10.1016/S0277-5387(02)01155-5
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Gerasimenko, A.V., and Gerasimenko, E.A., Russ. J. Coord. Chem., 2002, vol. 28, no. 7, p. 464. doi 10.1023/A:1016293009968
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Gerasimenko, A.V., Sergienko, A.S., Bukvetskii, B.V., and Popov, D.Yu., Russ. J. Coord. Chem., 2002, vol. 28, no. 8, p. 544. doi 10.1023/A:1019701511840
Dodonov, V.A, Gushchin, A.V., Gor’kaev, D.A., Fukin, G.K., Starostina, T.I., Zakharov, L.N., Kurskii, Ju.A., and Shavyrin, A.S., Russ. Chem. Bull., 2002, no. 6, p. 1051. doi 10.1023/A:1019634307064
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Bondar’, E.A., Krivolapov, D.B., Gubaidullin, A.T., and Litvinov, I.A., Russ. J. Gen. Chem., 2001, vol. 71, no. 9, p. 1426. doi 10.1023/A:1013910120594
Sharutin, V.V., Molokova, O.V., Sharutina, O.K., and Smirnova, S.A., Russ. J. Inorg. Chem., 2012, vol. 57, no. 9, p. 1252. doi 10.1134/S0036023612090185
Dong, L., Yin, H., Wen, L., and Wang, D., Acta Cryst.(E), 2009, vol. 65, no. 11, p. m1438. doi 10.1107/S1600536809043542
Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V., and Makerova, M.S., Vestn. YuUrGU, Ser. Khimiya, 2014, vol. 8, no. 2, p. 5.
Sharutin, V.V. and Sharutina, O.K., Russ. J. Inorg. Chem., 2014, vol. 59, no. 11, p. 1263. doi 10.1134/S0036023614110229
Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V., and Makerova, M.S., Russ. J. Inorg. Chem., 2015, vol. 60, no. 2, p. 207. doi 10.1134/S0036023615020138
Doak, G.O., Long, G.G., and Freedman, L.D., J. Organomet. Chem., 1965, vol. 4, no. 1, p. 82. doi 10.1016/S0022-328X(0000)823700-0
Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.
Bruker (1998). Smart and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (1998). SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data. Bruker AXS Inc., Madison, Wisconsin, USA.
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Original Russian Text © V.V. Sharutin, O.K. Sharutina, E.V. Artem’eva, M.S. Makerova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 12, pp. 2039–2044.
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Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V. et al. Synthesis and structure of tri(o-tolyl) antimony dioximates. Russ J Gen Chem 86, 2671–2676 (2016). https://doi.org/10.1134/S1070363216120161
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DOI: https://doi.org/10.1134/S1070363216120161