Abstract
Methods for the synthesis of unknown 2-styrylbenzothiazoles containing crown ether moieties with different combinations of O, S, and N-heteroatoms based on the Wittig reaction or condensation of 2-methylbenzothiazole with crown-ether benzaldehydes in the presence of strong bases or acids are proposed. The condensation in the presence of bases is accompanied by complex formation with participation of the crown ether moiety of the benzaldehyde. The complex formation has a pronounced influence on the yield of the target product and the pattern of condensation of 2-methylbenzothiazole with crown-ether benzaldehydes.
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Fedorova, O.A., Andryukhina, E.N., Lindeman, A.V. et al. Synthesis of crown-containing 2-styrylbenzothiazoles. Effect of alkali metal cations on the condensation of crown-ether benzaldehydes with 2-methylbenzothiazole. Russian Chemical Bulletin 51, 319–325 (2002). https://doi.org/10.1023/A:1015416029124
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DOI: https://doi.org/10.1023/A:1015416029124