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Ternary metal sulfides MzMoS2: synthesis using single-layer dispersions of molybdenum disulfide and study of the structure

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Abstract

The sulfur atoms of negatively charged (MoS2)x– layers in aqueous single-layer dispersions of molybdenum disulfide covalently bind the M2+ cations (M = Pb, Cd, Hg, Pd). This makes it possible to obtain ternary metal sulfides MzMoS2 containing “guest” M atoms in octahedral or tetrahedral vacancies between the S—Mo—S layers at room temperature. In the case of Pd and Hg, the formation of MzMoS2 is accompanied by the reduction of a fraction of PdII to Pd0 and HgII to HgI. During dispersion followed by the formation of ternary sulfides, the MoS2 layers undergo structural transformations resulting in the formation of Mo—Mo bonds.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. S. Golub, Ya. V. Zubavichus, N. D. Lenenko & Yu. L. Slovokhotov

  2. Jean Rouxel Institute of Materials, National Research Center, University of Nantes, 2 Rue de la Houssinière, BP 32229, 44332, Nantes, France

    M. Danot & Yu. N. Novikov

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  1. A. S. Golub
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  2. Ya. V. Zubavichus
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  3. N. D. Lenenko
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  4. Yu. L. Slovokhotov
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  5. M. Danot
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  6. Yu. N. Novikov
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Golub, A.S., Zubavichus, Y.V., Lenenko, N.D. et al. Ternary metal sulfides MzMoS2: synthesis using single-layer dispersions of molybdenum disulfide and study of the structure. Russian Chemical Bulletin 50, 2293–2303 (2001). https://doi.org/10.1023/A:1015058823903

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