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Synthesis and Properties of 2-(Diorganylphosphorylhydroxymethyl)-1-organylimidazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1-Organyl-2-formylimidazoles and -benzimidazoles react with diorganylphosphine oxides under mild conditions (room temperature, dioxane, 1 h) to give in practically quantitative yields 2-(diorganylphosphorylhydroxymethyl)-1-organylimidazoles - highly reactive synthons and polydentate ligands for the design of metal complex catalysts.

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Gusarova, N.K., Arbuzova, S.N., Reutskaya, A.M. et al. Synthesis and Properties of 2-(Diorganylphosphorylhydroxymethyl)-1-organylimidazoles. Chemistry of Heterocyclic Compounds 38, 65–70 (2002). https://doi.org/10.1023/A:1014855309771

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  • DOI: https://doi.org/10.1023/A:1014855309771

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