Abstract
Experimental results obtained by thermal hydroperoxidation of l-isopropyl-3-tert-butylbenzene, in the temperature region of 120-130 °C, using disodium adipate as additive substance and a Vodnár-l type apparatus with discontinuous operation are presented. Based on the results, the activation energy (E = 91 kJ/mol), enthalpy calculated.
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REFERENCES
J. Vodnár: J. Appl. Chem., 20, 99 (1970).
J. Vodnár, S. Békássy, J. Farkas: React. Kinet. Catal. Lett., 68, 213 (1999).
Vodnár J., Békássy S., Farkas J.: Múzeumi Füzetek, 8, 69 (1999).
Vodnár J., Békássy S., Farkas J., Dragan M., Chis A.: Múzeumi Füzetek, 8, 64 (1999).
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed., Vol. 13, p. 39. John Wiley and Sons/Interscience, New York-London-Sydney-Toronto 1981.
J. Vodnár: Rev. Chim., (Bucharest) 27, 11 (1976).
J. Vodnár: Romanian Patent 57328 (1969).
M.A. Dikii, O.I. Gevus, V.A. Puchin: Zh. Org. Khim., 22, 38 (1986).
K. Hashimoto, H. Nambu, K. Watari: Eur. Patent, Appl. 21848 (1981).
D. Wilhelm, T. Clark, P.v.R. Schleyer, J.L. Courtneidge, A.G. Davies: J. Am. Chem. Soc., 106, 361 (1984).
J. Vodnár: Rev. Chim., (Bucharest) 43, 60 (1992).
Vodnár J.: Magy. Kém. Lapja, 48, 125 (1993).
J. Vodnár: Romanian Patent 96372 (1987).
Vodnár J., Kolozsi J.: Műszaki Szemle (Kolozsvár, RO), 3-4, 46 (1998).
J. Vodnár: Hung. J. Ind. Chem., 21, 167 (1993).
F.H. Dickey, F.F. Rust, W.M. Vaughan: J. Am. Chem. Soc., 71, 1432 (1949).
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Vodnár, J., Békássy, S. Study of Chemical Reactions, Absorption And Extraction, Using Apparatuses With Serpentine Pipe For Pelliclizing-Bubbling, XVIII. Hydroperoxidation Of 1-Isopropyl-3-tert-Butylbenzene. Reaction Kinetics and Catalysis Letters 73, 161–167 (2001). https://doi.org/10.1023/A:1013905812081
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DOI: https://doi.org/10.1023/A:1013905812081