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Effect of Irradiation on Hydrodynamic Properties of Extraction Mixtures Based on Carboxylic Acid Diamides in FS-13 Diluent

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Abstract

The hydrodynamic properties of three promising extraction mixtures, 0.05 M solutions of 2,2′-bi-pyridine-6,6′-dicarboxylic acid di(N-ethyl-4-hexylanilide) (DYP-7), 2,6-pyridinedicarboxylic acid di(N-ethyl-4-fluoroanilide) [Et(pFPh)DPA)], and 2,2′-bipyridine-6,6′-dicarboxylic acid di(N-ethyl-4-ethylanilide) (DYP-9) in trifluoromethyl phenyl sulfone (FS-13), were studied. The density, viscosity, surface tension, and settling rates in the steps of nitric acid extraction, stripping, and regeneration with sodium carbonate solutions were determined for these systems before and after the action of ionizing radiation. The concentrations of the extrac-tants in the irradiated samples were determined, and the radiation-chemical yields of their decomposition were calculated. The density and surface tension increase upon irradiation to a dose of 100 kGy but decrease upon further irradiation.

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References

  1. Herbst, R.S., Law, J.D., Todd, T.A., et al., Solvent Extr. Ion Exch., 2002, vol. 20, pp. 429–445.

    Article  CAS  Google Scholar 

  2. Law, J.D., Herbst, R.S., Todd, T.A., et al., Solvent Extr. Ion Exch., 2001, vol. 19, pp. 23–36.

    Article  CAS  Google Scholar 

  3. Herbst, R.S., Law, J.D., Todd, T.A., et al., Sep. Sci. Technol., 2003, vol. 38, pp. 2685–2708.

    Article  CAS  Google Scholar 

  4. Herbst, R.S., Luther, T.A., Peterman, D.R., et al., ACS Symp. Ser., 2006, vol. 943, pp. 171–185.

    Article  CAS  Google Scholar 

  5. Charbonnel, M.C. and Musicas, C., Solvent Extr. Ion Exch., 1989, vol. 7, no. 6, pp. 1007–1025.

    Article  CAS  Google Scholar 

  6. Shen, C., Bao, B., Zhu, J., et al., J. Radioanal. Nucl. Chem. Lett., 1996, vol. 212, no. 3, pp. 187–196.

    Article  CAS  Google Scholar 

  7. Nigond, L., Condamines, N., Cordier, P.Y., et al., Sep. Sci. Technol., 1995, vol. 30, pp. 2075–2099.

    Article  CAS  Google Scholar 

  8. Nakamura, T. and Miyake, C., Solvent Extr. Ion Exch., 1995, vol. 13, no. 2, pp. 253–273.

    Article  Google Scholar 

  9. Sasaki, Y. and Choppin, G.R., Radiochim. Acta, 1998, vol. 80, no. 2, pp. 85–88.

    Article  CAS  Google Scholar 

  10. Morita, Y., Sasaki, Y., and Tachimori, S., Proc. Int. Conf. Global’ 2001, Paris (France), Sept. 9–13, 2001, paper 036.

    Google Scholar 

  11. Borisova, N.E., Korotkov, N.E., Ivanov, A.V., et al., Radiochemistry, 2016, vol. 58, no. 6, pp. 606–616.

    Article  CAS  Google Scholar 

  12. Alyapyshev, M.Yu., Babain, V.A., Tkachenko, L.I., et al., Solvent Extr. Ion Exch., 2014, vol. 32, no. 2, pp. 138–152.

    Article  CAS  Google Scholar 

  13. Alyapyshev, M.Yu., Babain, V.A., Tkachenko, L.I., et al., Solvent Extr. Ion Exch., 2011, vol. 29, no. 4, pp. 619–636.

    Article  CAS  Google Scholar 

  14. Sinha, P.K., Kumar, S., Shekhar, K., et al., J. Radioanal. Nucl. Chem., 2011, vol. 289, pp. 899–901.

    Article  CAS  Google Scholar 

  15. Procedure to Perform Studies with Actinide-Containing Solutions, Irradiation, and Dosimetry, Moscow: Inst. of Physical Chemistry and Electrochemistry, Russ. Acad. Sci., 2015.

  16. Dzhivanova, Z.V., Belova, E.V., Tkhorzhnitskii, G.P., et al., Radiochemistry, 2015, vol. 57, no. 2, pp. 143–151.

    Article  CAS  Google Scholar 

  17. Borisova, N.E., Ivanov, A.V., Matveev, P.I., et al., Chem. Select., 2018, vol. 3, pp. 1983–1989.

    CAS  Google Scholar 

  18. Kadyko, M., Skvortsov, I., and Belova, E., Abstracts of Papers, Int. Conf. RAD 2017, Budva (Montenegro), June 2017, p. 157.

    Google Scholar 

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Funding

The study was financially supported by the Russian Science Foundation (project no. 16-19-00 191).

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow, 119071, Russia

    M. I. Kadyko, I. V. Skvortsov, E. V. Belova & B. F. Myasoedov

  2. Department of Chemistry, Moscow State University, Moscow, Russia

    A. V. Ivanov & B. F. Myasoedov

  3. Interdepartmental Center for Analytical Research on Problems in the Field of Physics, Chemistry, and Biology, Presidium of the Russian Academy of Sciences, Profsoyuznaya ul. 65, str. 6, Moscow, 117342, Russia

    B. F. Myasoedov

Authors
  1. M. I. Kadyko
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  2. I. V. Skvortsov
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  3. A. V. Ivanov
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  4. E. V. Belova
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  5. B. F. Myasoedov
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Corresponding author

Correspondence to E. V. Belova.

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Conflict of Interest

The authors declare that they have no conflict of interest.

Russian Text © The Author(s), 2019, published in Radiokhimiya, 2019, Vol. 61, No. 5, pp. 404–408.

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Kadyko, M.I., Skvortsov, I.V., Ivanov, A.V. et al. Effect of Irradiation on Hydrodynamic Properties of Extraction Mixtures Based on Carboxylic Acid Diamides in FS-13 Diluent. Radiochemistry 61, 579–584 (2019). https://doi.org/10.1134/S1066362219050096

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  • DOI: https://doi.org/10.1134/S1066362219050096

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