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Synthesis and Stereochemistry of Substituted 1,3-Dioxa-2-silacyclohexanes: VII. Synthesis and Stereochemistry of Substituted 2-Vinyl-2-methyl-1,3-dioxa-2-silacyclohexanes

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Abstract

The stereochemistry of substituted 2-vinyl-2-methyl-1,3-dioxa-2-silacyclohexanes was studied by 1Hand 13C NMR spectroscopy. The configurational and conformational assignment of a mixture of 2-vinyl-2,4-dimethyl-1,3-dioxa-2-silacyclohexane diastereomers with various ratios of the cis and trans forms was made. The molecules of both conformers occur chiefly in the chair conformartion with equatorial location of the methyl group at the C4 atom. The experimental data were confirmed by AM1 and MM+ optimization of the molecular geometry.

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  1. Research Institute of Low-Tonnage Chemical Products and Reagents, Ufa, Bashkortostan, Russia

    S. V. Gvozdik, S. M. Shorin, R. M. Makaeva, R. R. Musavirov, L. V. Spirikhin, V. N. Urazbaev & R. S. Musavirov

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  1. S. V. Gvozdik
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  2. S. M. Shorin
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  3. R. M. Makaeva
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  4. R. R. Musavirov
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  5. L. V. Spirikhin
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  6. V. N. Urazbaev
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  7. R. S. Musavirov
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Gvozdik, S.V., Shorin, S.M., Makaeva, R.M. et al. Synthesis and Stereochemistry of Substituted 1,3-Dioxa-2-silacyclohexanes: VII. Synthesis and Stereochemistry of Substituted 2-Vinyl-2-methyl-1,3-dioxa-2-silacyclohexanes. Russian Journal of General Chemistry 71, 724–728 (2001). https://doi.org/10.1023/A:1012353217534

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