Skip to main content
SpringerLink
Log in

Temperature Control Modes in Thermal Analysis

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Now we can use several temperature control modes, i.e., the isothermal run including stepwise heating and cooling, constant rate heating (or cooling), temperature control for sample thermal history, sample controlled thermal analysis (SCTA or controlled-rate thermal analysis, CRTA), temperature jump, rate jump, temperature modulation and repeated temperature scanning. Their advantages and drawbacks are reviewed with some illustrative examples, especially for application to kinetic analysis. The combined use of these varieties of temperature control mode is recommended by showing examples. Temperature modulation and repeated temperature scanning are discussed in comparison with temperature modulated DSC, and common and analogous points are elucidated. In relation to this, the possibility that an imaginary part of overall reaction rate constant in complex reaction is postulated. Finally,these modes are classified and tabulated from two viewpoints and other possible modes are shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Ozawa, Thermochim. Acta, 355 (2000) 35.

    Article  CAS  Google Scholar 

  2. For example, H. Yoshida, J. Thermal Anal., 36 (1995) 4805.

    Google Scholar 

  3. For example, T. Arii, A. Kishi and Y. Kobayashi, Thermochim. Acta, 325 (1999) 151.

    Article  CAS  Google Scholar 

  4. For example, T. Ozawa, T. Arii and A. Kishi, Thermochim. Acta, 352/353 (2000) 177.

    Article  Google Scholar 

  5. For example, K. Ogasawara, M. Sorai and H. Suga, Mol. Cryst. Liq. Cryst., 71 (1981) 189.

    Google Scholar 

  6. J. Rouquerol, Thermochim. Acta, 144 (1989) 209.

    Article  CAS  Google Scholar 

  7. B. Dickens, J. Polym. Sci.-Polym. Chem., 20 (1982) 1065.

    Article  CAS  Google Scholar 

  8. J. Rouquerol, J. Thermal Anal., 5 (1973) 203.

    Article  CAS  Google Scholar 

  9. M. Reading, E. Elliot and V. L. Hill, J. Thermal Anal., 40 (1993) 949.

    CAS  Google Scholar 

  10. P. S. Gill, S. R. Sauerbrumn and M. Reading, J. Thermal Anal., 40 (1993) 931.

    CAS  Google Scholar 

  11. R. L. Blaine and B. K. Hahn, J. Therm. Anal. Cal., 54 (1998) 695.

    Article  CAS  Google Scholar 

  12. T. Ozawa, Thermochim. Acta, 356 (2000) 173.

    Article  CAS  Google Scholar 

  13. H. L. Friedman, J. Polym. Sci., C6 (1964) 183.

    Google Scholar 

  14. T. Ozawa, J. Thermal Anal., 31 (1986) 547.

    Article  CAS  Google Scholar 

  15. J. Varga, J. Thermal Anal., 31 (1986) 165.

    Article  CAS  Google Scholar 

  16. J. Varga, J. Thermal Anal., 35 (1989) 1891.

    Article  CAS  Google Scholar 

  17. T. Ozawa, Bull. Chem. Soc. Jpn., 38 (1965) 1881.

    CAS  Google Scholar 

  18. T. Ozawa, A. Negishi, Y. Takahashi, R. Sakamoto and H. Ihara, Thermochim. Acta, 124 (1988) 147.

    Article  CAS  Google Scholar 

  19. H. Staub and W. Perron, Anal. Chem., 46 (1974) 128.

    Article  CAS  Google Scholar 

  20. T. Ozawa, K. Kaneko and T. Sunose, J. Thermal Anal., 47 (1996) 1105.

    Article  CAS  Google Scholar 

  21. T. Ozawa, M. Kanazashi and R. Sakamoto, Thermochim. Acta, 109 (1986) 285.

    Article  CAS  Google Scholar 

  22. T. Ozawa, J. Therm. Anal. Cal., 59 (2000) 375.

    Article  CAS  Google Scholar 

  23. J. H. Flynn and L. A. Wall, J. Polym. Sci., B4 (1966) 323.

    Google Scholar 

  24. H. E. Kissinger, Anal. Chem., 29 (1957) 1702.

    Article  CAS  Google Scholar 

  25. T. Akahira and T. Sunose, Report Chiba Inst. Tech., 16 (1971) 22.

    Google Scholar 

  26. T. Arii, S. Ichihara, H. Nakagawa and N. Fujii, Thermochim. Acta, 319 (1998) 139.

    Article  CAS  Google Scholar 

  27. S. Ichihara, N. Nakagawa and Y. Tsukazawa, Kobunshi Rombunshu, 51 (1994) 459.

    CAS  Google Scholar 

  28. T. Ozawa, Thermochim. Acta, 203 (1992) 159.

    Article  CAS  Google Scholar 

  29. T. Ozawa, J. Thermal Anal., 2 (1970) 301.

    Article  CAS  Google Scholar 

  30. T. Ozawa, Thermochim. Acta, 100 (1986) 109.

    Article  CAS  Google Scholar 

  31. T. Ozawa and K. Kanari, Thermochim. Acta, 234 (1994) 41.

    Article  CAS  Google Scholar 

  32. T. Ozawa, J. Thermal Anal., 39 (1993) 1117.

    CAS  Google Scholar 

  33. A. Hishiki and T. Ozawa, Thermochim. Acta (to be submitted).

  34. P. K. Gallagher, J. Thermal Anal., 49 (1997) 33.

    Article  CAS  Google Scholar 

  35. T. Ozawa and K. Kanari, J. Therm. Anal. Cal., 59 (2000) 257.

    Article  CAS  Google Scholar 

  36. H. H. G. Jellinek, ‘Degradation of Vinyl Polymers’, Academic Press, New York 1955.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chiba Institute of Technology, Tsudanuma, 275-0016, Japan

    T. Ozawa

Authors
  1. T. Ozawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ozawa, T. Temperature Control Modes in Thermal Analysis. Journal of Thermal Analysis and Calorimetry 64, 109–126 (2001). https://doi.org/10.1023/A:1011580811822

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011580811822

Search

Navigation