Abstract
A number of compounds is investigated for DSC calibration during cooling. Adamantane and Zn show fast reversible transitions and can be applied both for temperature and for heat calibrations. A third compound, namely 4,4’-azoxyanisole, has a liquid crystal to isotropic liquid transition at 409K. This compound can be used for temperature calibration. Heat calibration with this compound is more problematic because of the small heat effect and the construction of the baseline. Other compounds like NaNO3, In, Hg and Pb, show a slight supercooling. Nevertheless they can be used for heat calibration. The use of large samples of NaNO3 and In gives the possibility to construct the equilibrium onset temperatures of the cooling peaks, so these two compounds are also appropriate for temperature calibration on cooling.
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E. Gmelin, S. M. Sarge, G. W. H. Höhne, H. K. Cammenga, W. Eysel and W. F. Hemminger, NATAS Notes, 29 (1997) 14.
E. Gmelin, and S. M. Sarge, Pure & Appl. Chem., 67 (1995) 1789.
G. Hakvoort and C. M. Hol, J. Thermal Anal., 52 (1998) 195.
G. Hakvoort and C. M. Hol, J. Therm. Anal. Cal., 56 (1999) 717.
G. Hakvoort and C. M. Hol, Proc. TPPM 99, Singapore (1999) 10.
E. F. Westrum, Jr., J. Phys. Chem. Solids, 18 (1961) 83.
G. Hakvoort, J. Thermal Anal., 41 (1994) 1551.
I. Barin, ‘Thermochemical Data of Pure Substances', VCH Verlagsgeselschaft, Weinheim 1989.
P. J. van Ekeren, C. M. Hol and A. J. Witteveen, J. Thermal Anal., 49 (1997) 1105.
Kirk- Othmer, Encyclopedia of Chemical Technology, executive editor, J. I. Kroschwitz, editor M. Howe-Grant, 4th Ed., 15 (1995) 378.
K. N. Marsh (Ed.): ‘Recommended Reference Materials for the Realization of Physicochemical Properties', Blackwell Scientific Publications, Oxford 1987.
R. Sabbah, An Xu-wu, J. S. Chickos, M. L. Planas Leitã o, M. V. Roux and L. A. Torres, Thermochim. Acta, 331 (1999) 121.
J. A. Martens and J. J. C. Cruz-Pinto, Thermochim. Acta, 332 (1999) 179.
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Hakvoort, G., Hol, C.M. & van Ekeren, P.J. DSC Calibration During Cooling. A survey of possible compounds. Journal of Thermal Analysis and Calorimetry 64, 367–375 (2001). https://doi.org/10.1023/A:1011534423634
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DOI: https://doi.org/10.1023/A:1011534423634