Skip to main content
SpringerLink
Log in

Thermal Decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) Thiocyanates

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Thermal decomposition of Bi(SCN)3, Cd(SCN)2, Pb(SCN)2 and Cu(SCN)2 has been studied. The thermal analysis curves and the diffraction patterns of the solid intermediate and final products of the pyrolysis are presented. The gaseous products of the decomposition (SO2 and CO2) were detected and quantitatively determined. Thermal, X-ray and chemical analyses have been used to establish the nature of the reactions occurring at each stage in the decomposition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Cygański, Talanta, 24 (1977) 361.

    Google Scholar 

  2. B. Ptaszyński and E. Skiba, Thermochim. Acta, 217 (1993) 199.

    Google Scholar 

  3. B. Ptaszyński and E. Skiba, Thermochim. Acta, 223 (1993) 93.

    Google Scholar 

  4. T. Majewski and A. Cygański, Chem. Anal., 31 (1986) 811.

    Google Scholar 

  5. T. Majewski and A. Cygański, Chem. Anal., 29 (1984) 377.

    Google Scholar 

  6. T. Majewski and A. Cygański, Chem. Anal., 32 (1987) 189.

    Google Scholar 

  7. A. Cygański and T. Majewski, Talanta, 30 (1983) 699.

    Google Scholar 

  8. F. Gallais and J. Familliandes, Bull. Soc. Chim. France, 19 (1952) 487.

    Google Scholar 

  9. Gmelins Handbuch der Anorganischen Chemie, System-Numer 33, Verlag Chemie, GMBH, Weiheim/Bergstrasse 1959, p. 658.

  10. J. Supniewski, Preparatyka Nieorganiczna, PWN, Warszawa 1958, p. 651.

    Google Scholar 

  11. Gmelins Handbuch der Anorganischen Chemie, System-Numer 60, Teil B, Lieferung 2, Verlag Chemie, GMBH, Weiheim/Bergstrasse 1961, p. 874.

  12. P. W. West and G. C. Gaeke, Anal. Chem., 28 (1956) 1816.

    Google Scholar 

  13. A. Cygański, Roczniki Chem., 51 (1977) 869.

    Google Scholar 

  14. W. W. Wendlandt, Standard Methods of Chemical Analysis, Princeton, N. Y. 1963, p. 243.

  15. E. Söderback, Sv. Kem. Tidsk., 21 (1909) 116.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of General and Ecological Chemistry, Technical University, 90-924, Łódż, Poland

    B. Ptaszyński, E. Skiba & J. Krystek

Authors
  1. B. Ptaszyński
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Skiba
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Krystek
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ptaszyński, B., Skiba, E. & Krystek, J. Thermal Decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) Thiocyanates. Journal of Thermal Analysis and Calorimetry 65, 231–239 (2001). https://doi.org/10.1023/A:1011501307497

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011501307497

Search

Navigation