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Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5)

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Abstract

Reaction of tetrabutylammonium salts of [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5) anions with water results in N-borylated iminols (Bu4N)[2-B10H9NH=C(OH)R], and in the presence of an alkali, corresponding N-substituted amides (Bu4N)2[2-B10H9NH-C(=O)R] are formed. The compounds obtained are identified by IR, ESI/MS, and 1H, 11B, and 13C NMR spectroscopy. The crystal structure of compound (Bu4N)[2-B10H9(Z-{NHC(OH)C2H5})] is studied by X-ray diffraction.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. P. Zhdanov, A. Yu. Bykov, A. S. Kubasov, I. N. Polyakova, G. A. Razgonyaeva, K. Yu. Zhizhin & N. T. Kuznetsov

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  1. A. P. Zhdanov
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  2. A. Yu. Bykov
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  3. A. S. Kubasov
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  4. I. N. Polyakova
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  5. G. A. Razgonyaeva
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  6. K. Yu. Zhizhin
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  7. N. T. Kuznetsov
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Correspondence to A. P. Zhdanov.

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Original Russian Text © A.P. Zhdanov, A.Yu. Bykov, A.S. Kubasov, I.N. Polyakova, G.A. Razgonyaeva, K.Yu. Zhizhin, N.T. Kuznetsov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 4, pp. 467–475.

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Zhdanov, A.P., Bykov, A.Y., Kubasov, A.S. et al. Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5). Russ. J. Inorg. Chem. 62, 468–475 (2017). https://doi.org/10.1134/S0036023617040210

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