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Ligand oxidation as a method for intramolecular activation of metal complexes

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Abstract

The results of investigations of organometallic and coordination compounds whose ligands contain redox fragments based on 2,6-di-tert-butylphenol and linked to the metal by various coordinating groups are summarized. The redox properties of σ-aryl, π- and σ-allyl complexes, β-diketonates, hydrazides, hydroxamates, glyoximates, and metalloporphyrins and metallophthalocyanines are considered. The possibility of changing the reactivity of organometallic and coordination compounds by changing the magnetic state due to oxidation of the redox-active phenolic group in the ligand is demonstrated. It is proposed to use ligand oxidation as a method for intramolecular activation of metal complexes.

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  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    E. R. Milaeva

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Milaeva, E.R. Ligand oxidation as a method for intramolecular activation of metal complexes. Russian Chemical Bulletin 50, 573–586 (2001). https://doi.org/10.1023/A:1011356421926

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