Skip to main content
SpringerLink
Log in

Intrinsic Kinetics of the Alkylation of Benzene with Propylele over β Zeolite Catalyst

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The kinetics of benzene alkylation with propylene over H β zeolite catalyst was investigated in an autoclave with a stirrer, as internal and external diffusion resistance were eliminated. A Langmuir-Hinshelwood type kinetic model was proposed on the basis of the experiments. The model parameters were evaluated, and the model was justified by variance analysis and residual analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Soave, G., Chem. Eng. Sci., 1972, vol. 27, p. 1197.

    Google Scholar 

  2. Thiele, W., Ind. Eng. Chem., 1939, vol. 31, p. 916.

    Google Scholar 

  3. Zel'dovich, Ya.B., Zhur. Fiz. Khim., 1939, vol. 13, p. 163.

    Google Scholar 

  4. Wheeler, Catalysis, Emmett, P.H., Ed., New York: Reinold, 1955, vol. 2, p. 123.

    Google Scholar 

  5. Wheeler, dv. Catal., 1951, vol. 3, p. 249.

    Google Scholar 

  6. Kärger and Ruthven, D.M., Diffusion in Zeolities and other Microporous Solids, New York: Wiley, 1992, p. 538.

    Google Scholar 

  7. Bellussi, G., Pazzuconi, G., Perego, C., et al., J. Catal., 1995, vol. 157, p. 227.

    Google Scholar 

  8. Han, M., Lin, S., Chen, S., Zhang, J., Petrochem. Eng., 1999, vol. 28, p. 1.

    Google Scholar 

  9. Han, M., Lin, S., Chen, S., Zhang, J., Petrochem. Eng., 1999, vol. 28, p. 73.

    Google Scholar 

  10. Li, Z., Basis of Reaction Kinetics of Heterogenous, Beijing: Beijing University, 1990.

    Google Scholar 

  11. Li, S., Chemical and Catalytic Reaction Engineering, Beijing: Chemical Industry Press, 1986.

    Google Scholar 

  12. Zhu, Z., Dai, Y., Data Proceeding of Chemical Datas and Experiment Designing; Beijing: Hydrocarbon Processing Press, 1989.

    Google Scholar 

  13. Han, M., Study of the Alkylation of Benzene with Propylene over β Zeolite Catalyst, Ph.D. Dissertation, Beijing: University of Petroleum, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China

    M. Han

  2. Chemical Research Center, Beijing Institute of Clothing Technology, Beijing, 100029, China

    X. Li

  3. National Heavy Oil Research Laboratory, University of Petroleum, Beijing, 102200, China

    S. Lin

Authors
  1. M. Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Han, M., Li, X. & Lin, S. Intrinsic Kinetics of the Alkylation of Benzene with Propylele over β Zeolite Catalyst. Kinetics and Catalysis 42, 533–538 (2001). https://doi.org/10.1023/A:1010581708069

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010581708069

Keywords

Search

Navigation