Abstract
The phase diagram of the binary AgNO3–CsNO3 system was constructed using differential thermal analysis (DTA) technique in the range 300–700 K. The apparatus is described briefly. The results exhibit a congruently melting compound CsNO3·AgNO3 (m.p.=453 K) characterized by two allotropic varieties α and β, an incongruently melting compound AgNO3·CsNO3 (m.p.=450 K) with three forms α′, β′ and γ′, two eutectics (16 mol% CsNO3, 442 K and 32.5 mol% CsNO3, 445 K) and a peritectic (38mol% CsNO3, 450 K). The occurrence of the transitions of intermediates was confirmed by X-ray diffraction at variable temperatures. The phase diagram exhibits also two plateaus at 429 K and 435 K corresponding to the phase transitions of CsNO3 and AgNO3, respectively.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. Zamali and M. Jemal, AFCAT, Journées 20–22 Mai 1985, Montpellier, France, Vol. 16, 1985, 298.
H. Zamali and M. Jemal, XVème J.E.E.P., Grenoble, France (1989) 83.
H. Zamali and M. Jemal, J. Thermal Anal., 41 (1994) 1091.
H. Zamali and M. Jemal, J. Phase Equilib., 16 (1995) 235.
N. Bélaid-Drira, H. Zamali and M. Jemal, J. Thermal Anal., 46 (1996) 1449.
A. P. Palkin, Zh. Fiz. Khim., 60 (1928) 317.
G. Flor and C. Sinistri, Ric. Sci., 38 (1968) 227.
D. Leonesi, M. Braghetti and A. Cingolani, Annual Meeting, Chimica Inorganica (1969) cited in ref. 9.
G. Gioia Lobbia and A. Cingolani, Ann. Chim., 65 (1975) 361.
D. Leonesi, M. Braghetti and A. Cingolani, Ann. Chim., 66 (1976) 489.
A. Mustajoki, Ann. Acad. Sci. Fenn., A6 (1957) 7.
H. E. Flotow, P. A. G. O'Hare and J. Boerio-Goates, J. Chem. Thermodyn., 13 (1981) 477.
P. W. Bridgman, Proc. Amer. Acad., 51 (1916) 581.
T. Jriri, J. Rogez, C. Bergman and J.-C. Mathieu, Thermochim. Acta, 266 (1995) 147.
I. Kazuhiko and M. Toshiyuki, Bull. Chem. Soc. Jpn., 56 (1983) 2093.
A. Tadashi, K. Mineo and T. Hiroshi, Nagoya Kogyo Gijutsu Shikensho Hokoku (Reports Government Industrial Research Institute Nagoya), 29 (1980) 25.
G. G. Diogenov and I. F. Sarapulova, Russ. J. Inorg. Chem., 10 (1965) 1055.
B. B. Owens, J. Chem. Phys., 42 (1965) 2259.
G. J. Janz and D. W. James, J. Chem. Phys., 35 (1961) 739.
O. J. Kleppa and F. G. McCarty, J. Chem. Eng. Data, 8 (1963) 331.
D. J. Hissink, Z. Phys. Chem., 32 (1900) 537.
A. Ussow, Z. Anorg. Chem., 38 (1904) 419.
P. Franzosini and C. Sinistri, Ric. Sci., Rend. Sez., A3 (1963) 439.
D. M. Newns and L. A. K. Staveley, Chem. Rev., 66 (1966) 267.
V. C. Reinsborough and F. E. W. Wetmore, Aust. J. Chem., 20 (1967) 1.
N. R. Thompson, Comprehensive Inorganic Chemistry, 3, Ed. Wilson & Wilson's Elsevier, Amsterdam 1973, 104.
K. Mészáros Szécsenyi, K. Tomor and G. Pokol, J. Thermal Anal., 41 (1994) 125.
H. Zamali, Thèse Doct. Sci. Phys., Noo D194, (1996), Faculté des Sciences de Tunis, Tunisia.
E. Rhodes and A. R. Ubbelohde, Proc. Roy. Soc., A (1959) 156.
M. Bakes, J. Dupuy and J. Guion, Compt. Rend., 256 (1963) 2376.
T. B. Douglas, Trans. Asme, 79 (1957) 23.
G. J. Janz, D. W. James and J. Goodkin, J. Phys. Chem., 64 (1960) 937.
H. M. Goodwin and H. T. Kalmus, Phys. Rev., 28 (1909) 1.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hellali, D., Zamali, H., Sebaoun, A. et al. Phase Diagram of the AgNO3–CsNO3 System. Journal of Thermal Analysis and Calorimetry 57, 569–574 (1999). https://doi.org/10.1023/A:1010188613487
Issue Date:
DOI: https://doi.org/10.1023/A:1010188613487