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Investigation of the AgGaS2–PbS and Some Properties of Phases of Variable Composition

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

The quasi-binary section AgGaS2–PbS in the ternary system Ag2S–Ga2S3–PbS was studied by physicochemical analysis methods (differential thermal, X-ray powder diffraction, and metallographic analyses). The state diagram of the system was constructed, and the quaternary compound AgPb2GaS4 was detected to form by a peritectic reaction at 1225 K. Its formation conditions were identified, and its physicochemical properties were investigated. The compound AgPb2GaS4 was determined to crystallize in the orthorhombic system with the unit cell parameters a = 8.20 Å, b = 6.84 Å, c = 6.62 Å, and space group Pmn21. From the physicochemical analysis data, the existence of narrow ranges of solid solutions based on the initial components was determined.

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Authors and Affiliations

  1. Azerbaijan State Pedagogical University, AZ1010, Baku, Azerbaijan

    S. K. Jahangirova

  2. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, AZ1143, Baku, Azerbaijan

    Sh. H. Mammadov, D. S. Ajdarova & O. M. Aliyev

  3. Azerbaijan State Oil and Industrial University, AZ1010, Baku, Azerbaijan

    G. R. Gurbanov

Authors
  1. S. K. Jahangirova
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  2. Sh. H. Mammadov
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  3. D. S. Ajdarova
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  4. O. M. Aliyev
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  5. G. R. Gurbanov
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Correspondence to Sh. H. Mammadov.

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Translated by V. Glyanchenko

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Jahangirova, S.K., Mammadov, S.H., Ajdarova, D.S. et al. Investigation of the AgGaS2–PbS and Some Properties of Phases of Variable Composition. Russ. J. Inorg. Chem. 64, 1169–1171 (2019). https://doi.org/10.1134/S0036023619090092

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  • DOI: https://doi.org/10.1134/S0036023619090092

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