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Synthesis, Spectral and Thermal Studies of o-vanillin Oxime Complexes of Zinc(II), Cadmium(II) and Mercury(II)

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Abstract

Zinc(II), cadmium(II) and mercury(II) complexes of o-vanillin oxime have been synthesized and characterized by different physicochemical techniques. All the complexes have been subjected to non-isothermal decomposition studies in nitrogen atmosphere using thermogravimetry. The kinetic parameters for the decomposition of these complexes were evaluated using different methods and comparatively better results were obtained by these different methods. It has also been found that the decomposition processes of all these complexes follow first order kinetics.

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Authors and Affiliations

  1. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, 682 022, Kerala, India

    M. R. Prathapachandra Kurup & K. Muraleedharan

  2. Department of Chemistry, S. D. College, Alappuzha, 688 003, Kerala, India

    S. V. Chandra

Authors
  1. M. R. Prathapachandra Kurup
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  2. S. V. Chandra
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  3. K. Muraleedharan
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Prathapachandra Kurup, M.R., Chandra, S.V. & Muraleedharan, K. Synthesis, Spectral and Thermal Studies of o-vanillin Oxime Complexes of Zinc(II), Cadmium(II) and Mercury(II). Journal of Thermal Analysis and Calorimetry 61, 909–914 (2000). https://doi.org/10.1023/A:1010154810885

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