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Kinetic On-line Evaluation of Chemical Reactions

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Abstract

A computer program was developed for kinetic evaluations of calorimetric experiments to predict the further reaction run under adiabatic conditions. Kinetic modeling is based on elementary reaction steps whose rate laws form a set of differential equations. For the continuous parameter optimization time-temperature data and their derivatives are used. A special calorimeter of the ACTRON series with safety equipment was applied to investigate the kinetics of chemical reactions and to test kinetic on-line evaluations. In the paper, examples for the reaction of n-propanol with o-chlornitrobenzene and for the alcoholysis of phenyl isocyanate are given.

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Authors and Affiliations

  1. University of Greifswald, Institute of Physical Chemistry, Soldtmannstr. 23, D 17489, Greifswald, Germany

    A. Kemmler, H. L. Anderson, K. Heldt, D. Haberland & B. Hinz

Authors
  1. A. Kemmler
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  2. H. L. Anderson
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  3. K. Heldt
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  4. D. Haberland
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  5. B. Hinz
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Kemmler, A., Anderson, H.L., Heldt, K. et al. Kinetic On-line Evaluation of Chemical Reactions. Journal of Thermal Analysis and Calorimetry 52, 187–194 (1998). https://doi.org/10.1023/A:1010130727481

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  • DOI: https://doi.org/10.1023/A:1010130727481

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