Abstract
The X-ray structure of a novel mononuclear heptacoordinated compound chlorodiphenylantimony(V) bis(2-methyl benzoate), SbPh2CI(O2C—2—Me—C6H4)2 is described. Crystal data are: Monoclinic, P21/c, a = 8.791(3), b = 21.687(3), c = 13.488(4) Å, β = 103.78(2)°, and Z = 4. A distorted pentagonal bipyramidal geometry for antimony with both the carboxylates chelating is found in the solid state.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Wieber, M.; Fetzer-Kremling, I.; Reith, H.; Burschka, C.Z. Naturforsch., Teil B, 1987, 42, 815.
Silvestru, C.; Haiduc, I.; Ebert, K.H.; Breunig, H.J.; Sowerby, D.B. J. Organomet. Chem., 1994, 468, 113.
Stevens, J.G.; Trooster, J.M.; Meinema, H.A. Inorg. Chim. Acta, 1980, 40, 263.
Said, M.A.; Kumara Swamy, K.C.; Poojary, D.M.; Clearfield, A.; Veith; M.; Huch, V. Inorg. Chem., 1996, 35, 3235.
Sowerby, D.B.; Begley, M.J.; Millington, P.L. J. Chem. Soc. Chem. Commun., 1984, 896; (b) Said, M.A.; Kumara Swamy, K.C.; Babu, K.; Aparna, K.; Netaji, M. J. Chem. Soc., Dalton Trans., 1995, 2151.
Blösl, S.; Schwarz, W.; Schmidt, A. Z. Naturforsch., Teil B 1983, 38, 143; (b) Lauster, M.; Klinkhammer, K.-W.; Schmidt, A. Main Group Metal Chem. 1998, 21, 769.
Sheldrick, G.M. SHELXS 86, Program for crystal structure solution, University of Göttingen, 1986; (b) Sheldrick, G.M. SHELXL-93; University of Go¨ ttingen, Germany, 1993.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kumara Swamy, K., Said, M.A. & Netaji, M. A heptacoordinated mononuclear diphenylantimony carboxylate. Journal of Chemical Crystallography 29, 1103–1106 (1999). https://doi.org/10.1023/A:1009505724312
Issue Date:
DOI: https://doi.org/10.1023/A:1009505724312