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Arylantimony Derivatives of Three-Coordinated Carbon

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Abstract

New ionic antimony complexes with a three-coordinated carbon atom in their cations, namely, [(Ph4SbO)3C]+[OSO2C6H3(NO2)2-2,4]– ⋅ 3PhH (32%) and [(p-Tol4SbO)3C]+Br– (traces), have been isolated when the products of reactions between pentaphenylantimony and 2,4-dinitrobenzenesulfonic acid and between penta(p-tolyl)antimony and hydrobromic acid were crystallized from a benzene–octane mixture in air along with the target products, such as tetraphenylantimony 2,4-dinitrobenzenesulfonate and tetra(p-tolyl)antimony bromide. The cations have nearly planar СO3Sb3 cores. The ОСО and COSb angles are close to 120°, whereas the C–O bonds vary within 1.277(4)–1.290(3) Å, and the Sb–O distances (2.266(2)–2.299(2) Å) exceed the sum of the covalent radii of antimony and oxygen atoms. It has been experimentally established that these complexes are formed as a result of interactions between the target products of the above-mentioned reactions with bis(tetraarylantimony) carbonates, which are also formed under the conditions of these reactions from pentaarylantimony and atmospheric carbon dioxide.

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REFERENCES

  1. M. Hirai, M. Myahkostupov, F. N. Castellano, et al., Organometallics 35, 1854 (2016). https://doi.org/10.1021/acs.organomet.6b00233

    Article  CAS  Google Scholar 

  2. D. Tofan and F. P. Gabbai, Chem. Sci. 7, 6768 (2016). https://doi.org/10.1039/C6SC02558G

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. S. Sen, I.-S. Ke, and F. P. Gabbai, Organometallics 36, 4224 (2017). https://doi.org/10.1021/acs.organomet.7b00654

    Article  CAS  Google Scholar 

  4. L. Saleem, A. A. Altaf, and A. Badshah, et al., Inorg. Chim. Acta 474, 148 (2018). https://doi.org/10.1016/j.ica.2018.01.036

    Article  CAS  Google Scholar 

  5. M. Hirai, J. Cho, and F. P. Gabbai, Chem.-Eur. J. 22, 6537 (2016). https://doi.org/10.1002/chem.201600971

    Article  CAS  PubMed  Google Scholar 

  6. S. Sen, I.-S. Ke, and F. P. Gabbai, Inorg. Chem. 55 (18), 9162 (2016). https://doi.org/10.1021/acs.inorgchem.6b01290

    Article  CAS  PubMed  Google Scholar 

  7. M. Yang and F. P. Gabbai, Inorg. Chem. 56, 8644 (2017). https://doi.org/10.1021/acs.inorgchem.7b00293

    Article  CAS  PubMed  Google Scholar 

  8. S. Sarwar, T. Iftikhar, and M. K. Rauf, Inorg. Chim. Acta 476, 12 (2018). https://doi.org/10.1016/j.ica.2018.02.005

    Article  CAS  Google Scholar 

  9. K. A. Kocheshkov, A. P. Skoldinov, and N. N. Zemlyanskii, The Methods of Organoelement Chemistry. Antimony and Bismuth (Nauka, Moscow, 1976) [in Russian].

    Google Scholar 

  10. V. V. Sharutin and V. S. Senchurin, Named Reactions in the Chemistry of Organoelement Compounds (YuUrGU Press, Chelyabinsk, 2011) [in Russian].

  11. G. K. Fukin, M. A. Samsonov, A. V. Arapova, et al., J. Solid State Chem. 254, 32 (2017). https://doi.org/10.1016/j.jssc.2017.06.030

    Article  CAS  Google Scholar 

  12. A. I. Poddel’sky, M. V. Arsenyev, T. V. Astaf’eva, et al., J. Organomet. Chem. 835, 17 (2017). https://doi.org/10.1016/j.jorganchem.2017.02.035

    Article  CAS  Google Scholar 

  13. T. Iftikhar, M. K. Rauf, S. Sarwar, et al., J. Organomet. Chem. 851, 89 (2017). https://doi.org/j.jorganchem.2017.09.002

    Article  CAS  Google Scholar 

  14. A. I. Poddel’sky, I. V. Smolyaninov, G. K. Fukin, et al., J. Organomet. Chem. 824, 1 (2016). https://doi.org/10.1016/j.jorganchem.2016.09.021

    Article  CAS  Google Scholar 

  15. A. I. Poddel’sky, I. V. Smolyaninov, G. K. Fukin, et al., J. Organomet. Chem. 867, 238 (2018). https://doi.org/10.1016/j.jorganchem.2017.12.006

    Article  CAS  Google Scholar 

  16. C.-H. Chen and F. P. Gabbai, Angew. Chem., Int. Ed. Engl. 56, 1799 (2017). https://doi.org/10.1002/anie.201611009

    Article  CAS  Google Scholar 

  17. A. M. Christianson and F. P. Gabbai, Chem. Commun. 53, 2471 (2017). https://doi.org/10.1039/C6CC09205E

    Article  CAS  Google Scholar 

  18. X.-Y. Zhang, L. Cui, X. Zhang, et al., J. Mol. Struct. 1134, 742 (2017). https://doi.org/10.1016/j.molstruc.2017.01.039

    Article  CAS  Google Scholar 

  19. SMART and SAINT-Plus: Data Collection and Processing Software for the SMART System, Versions 5.0 (Bruker, Madison, 1998).

  20. SHELXTL/PC: An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Versions 5.10 (Bruker, Madison, 1998).

  21. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  22. V. V. Sharutin, O. K. Sharutina, T. P. Platonova, et al., Russ. J. Gen. Chem. 71 (10), 1550 (2001).https://doi.org/10.1023/A:1013938600798

  23. G. Ferguson and D. M. Hawley, Acta Crystallogr. 30, 103 (1974). https://doi.org/10.1107/S0567740874002299

    Article  Google Scholar 

  24. V. V. Sharutin, O. K. Sharutina, L. P. Panova, and V. K. Bel’skii, Koord. Khim. 23, 513 (1997).

    Google Scholar 

  25. V. V. Sharutin, I. V. Egorova, A. P. Pakusina, et al., Russ. J. Coord. Chem. 33, 168 (2007).

    Article  CAS  Google Scholar 

  26. G. Kolks, S. J. Lippard, and J. V. Waszczak, J. Am. Chem. Soc. 102, 4832 (1980). https://doi.org/10.1021/ja00534a045

    Article  CAS  Google Scholar 

  27. A. Escuer, R. Vicente, E. Penalba, et al., Inorg. Chem. 35, 248 (1996). https://doi.org/10.1021/ic950331q

    Article  CAS  PubMed  Google Scholar 

  28. F. H. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc., Perkin Trans. II (12), S1 (1987).

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Funding

This work was supported by the Ministry of Education and Science of the Russian Federation (grant no. 4.6151.2017/8.9).

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Authors and Affiliations

  1. National South Ural State Research University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. N. Efremov
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Correspondence to V. V. Sharutin.

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Translated by E. Glushachenkova

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Sharutin, V.V., Sharutina, O.K. & Efremov, A.N. Arylantimony Derivatives of Three-Coordinated Carbon. Russ. J. Inorg. Chem. 65, 45–51 (2020). https://doi.org/10.1134/S0036023620010155

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