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Tris(2-methoxy-5-chlorophenyl)antimony Dicarboxylates as Novel Hypercoordinate Antimony Compounds

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Abstract

The reaction of tris(2-methoxy-5-chlorophenyl)antimony with pentafluoropropionic, heptafluorobutanoic, pentafluorobenzoic, or 2-methoxybenzoic acids in the presence of hydrogen peroxide (1 : 2 : 1 molar ratio) in diethyl ether has afforded tris(2-methoxy-5-chlorophenyl)antimony dicarboxylates (2-MeO-5-ClC6H3)3Sb[OC(O)R]2, R = C2F5, C3F7, C6F5, or C6H4ОMe-2. Structures of the synthesized compounds have been investigated.

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Authors and Affiliations

  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & O. A. Khaybullina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 9, pp. 1446–11452 https://doi.org/10.31857/S0044460X2109016X.

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Sharutin, V.V., Sharutina, O.K. & Khaybullina, O.A. Tris(2-methoxy-5-chlorophenyl)antimony Dicarboxylates as Novel Hypercoordinate Antimony Compounds. Russ J Gen Chem 91, 1724–1729 (2021). https://doi.org/10.1134/S1070363221090164

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