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A comparative study of V species in ß zeolite by photoluminescence, diffuse reflectance UV-Visible and 51V NMR spectroscopies

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Abstract

In calcined and rehydrated VSiß zeolite prepared following a method described earlier, three kinds of tetrahedral VV species can be clearly identified by photoluminescence spectroscopy even at low V content, in contrast to 51V NMR and diffuse reflectance UV-Visible spectroscopies which do not allow them to be distinguished. A comparative study by photoluminescence and 51V NMR spectroscopies leads to the suggestion that there is a correlation between the vibrational energy of the V=O bond and the corresponding chemical shift of the 51V NMR signal.

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Authors
  1. Stanislaw Dzwigaj
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  2. Masaya Matsuoka
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  3. Masakazu Anpo
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  4. Michel Che
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Dzwigaj, S., Matsuoka, M., Anpo, M. et al. A comparative study of V species in ß zeolite by photoluminescence, diffuse reflectance UV-Visible and 51V NMR spectroscopies. Catalysis Letters 72, 211–214 (2001). https://doi.org/10.1023/A:1009072908710

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  • DOI: https://doi.org/10.1023/A:1009072908710

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