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Micelle Formation by Sodium Perfluorooctanoate and Decyltrimethylammonium Bromide in 18-Crown-6 + β-Cyclodextrin + Water Systems

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Abstract

The conductances of sodium perfluorooctanoate (SPFO) and decyltrimethylammoniumbromide (DeTAB) have been determined in 18-crown-6 + water (CR + W). β-cyclodextrin + water(CD + W) and in CR + CD + W mixtures with a fixed 0.0151 mol dm−3 concentration of CR andvarying amounts of CD with overall change in the mole fraction range of CD from 0.0 to 0.5 in CR +CD + W mixtures at 30°C. From the conductivity data, the critical micellar concentration (cmc), thedegree of counter-ion association (α) the free energy of transfer of the surfactant hydrocarbon chainfrom the medium to the micelle (ΔG 0 HP ), and the free energy of transfer of surface contributions(ΔG 0 S ) of SPFO and DeTAB have been computed. It has been found that the micelles of SPFO arestabilized in CR + W mixtures in comparison to pure water, whereas micelles of DeTAB remain comparatively unaffected upon addition of CR in water. On the other hand, micelles of SPFO andDeTAB are denatured upon addition of CD in CR + CD + W mixtures. The denaturation effect isstronger on the micelles of SPFO in comparison to that of DeTAB.

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References

  1. D.F. Evans, D.J. Mitchell, and B.W. Ninham: J. Phys. Chem. 88, 6344 (1984).

    Google Scholar 

  2. G.C. Kresheck: in F. Franks (ed.), Water, a Comprehensive Treatise, Plenum, New York (1975).

    Google Scholar 

  3. T. Asakawa, T. Fukita, and S. Miyagishi: Langmuir 7, 2112 (1991).

    Google Scholar 

  4. G. Roux-Desgranges, S. Bordere, and A.H. Roux: J. Colloid Interface Sci. 162, 284 (1994).

    Google Scholar 

  5. H.N. Singh and S. Swarup: Bull. Chem. Soc. Jpn. 51, 1534 (1948).

    Google Scholar 

  6. H.N. Singh, S. Swarup, and S.M. Saleem: J. Colloid Interface Sci. 68, 128 (1979).

    Google Scholar 

  7. M.S. Bakshi: J. Chem. Soc. Faraday Trans. 89, 2343 (1993).

    Google Scholar 

  8. M.S. Bakshi, R. Crisantino, R. De Lisi, and S. Milioto: Langmuir 10, 423 (1994).

    Google Scholar 

  9. M.S. Bakshi: Indian J. Chem. 34A, 896 (1995).

    Google Scholar 

  10. M.S. Bakshi: Bull. Chem. Soc. Jpn. 69, 2723 (1996).

    Google Scholar 

  11. J.M. Lehn: Acc. Chem. Res. 11, 49 (1978).

    Google Scholar 

  12. G. Gokel: Crown Ethers and Cryptands, Royal Society of Chemistry, Cambridge (1991).

    Google Scholar 

  13. S. Li and W.C. Purdy: Chem. Rev. 92, 1457 (1992).

    Google Scholar 

  14. M.L. Bender and M. Komiyama: Cyclodextrin Chemistry, Springer-Verlag, New York (1978).

    Google Scholar 

  15. J. Szejtli: Cyclodextrins and Their Inclusion Complexes, Akademiai Kiado, Budapest (1982).

    Google Scholar 

  16. F. Cramer and H. Hettler: Naturwissenschaften 54, 625 (1967).

    Google Scholar 

  17. M.S. Bakshi: J. Solution Chem. 25, 409 (1996).

    Google Scholar 

  18. S. Milioto, M.S. Bakshi, R. Crisantino, and R. De Lisi: J. Solution Chem. 24, 103 (1995).

    Google Scholar 

  19. M.S. Bakshi, P. Kohli, and G. Kaur: Bull. Chem. Soc. Jpn. 71, 1539 (1998).

    Google Scholar 

  20. G. Sugihara and P. Mukerjee: J. Phys. Chem. 85, 1612 (1981).

    Google Scholar 

  21. P. Mukerjee and Alex Y. S. Yang: J. Phys. Chem. 80, 1388 (1976).

    Google Scholar 

  22. P. K. Misra, B.K. Misra, and G.B. Behera: Colloids Surfaces 57, 1 (1991).

    Google Scholar 

  23. R. Zana: J. Colloid Interface Sci. 78, 330 (1980).

    Google Scholar 

  24. E. Junquera, G. Taradajos, and E. Aicart: Langmuir 9, 1213 (1993).

    Google Scholar 

  25. E. Junquera, J. González Benito, L. Peña, and E. Aicart: J. Colloid Interface Sci. 163, 355 (1994).

    Google Scholar 

  26. I. Miyata, A. Takada, M. Yonese, and H. Kishimoto: Bull. Chem. Soc. Jpn. 63, 3502 (1990).

    Google Scholar 

  27. B. Sesta, A. D'Aprano, A. Princi, C. Filippi, and M. Iammarino: J. Phys. Chem. 96, 9545 (1992).

    Google Scholar 

  28. R.A. Robinson and R.H. Stokes: Electrolyte Solutions, 2nd edn, Butterworths, London, Chh. 2, 6, 7 (1970).

    Google Scholar 

  29. D.F. Evans and B.W. Ninham: J. Phys. Chem. 87, 5025 (1983).

    Google Scholar 

  30. M. Ueno, Y.H. Tsao, J.B. Evans, and D.F. Evans: J. Solution Chem. 21, 445 (1992).

    Google Scholar 

  31. P. Mukerjee, K.J. Mysels, and P. Kapauan: J. Phys. Chem. 71, 4166 (1967).

    Google Scholar 

  32. R. Jha and J.C. Ahluwalia: J. Phys. Chem. 95, 7782 (1991).

    Google Scholar 

  33. N. Funasaki: in K. Ogino and M. Abe (eds.), Mixed Surfactant Systems, Marcel Dekker, New York (1992).

    Google Scholar 

  34. W. Saenger and A. Muller-Fahron: Angew. Chem. Int. Ed. Engl. 92, 3537 (1988).

    Google Scholar 

  35. B. Asgharian, D.A. Cadenhead, and E.D. Goddard: Colloids Surf. 34, 143 (1988).

    Google Scholar 

  36. E.S. Aman and D. Serve: J. Colloid Interface Sci. 138, 365 (1990).

    Google Scholar 

  37. R. Palepu and V.C. Reinsborough: Can. J. Chem. 66, 325 (1988).

    Google Scholar 

  38. T. Okubo, H. Kitano, and N. Ise: J. Phys. Chem. 80, 2661 (1976).

    Google Scholar 

  39. T. Asakawa, M. Hashikawa, K. Amada, and S. Miyagishi: Langmuir 11, 2376 (1995).

    Google Scholar 

  40. R. Palepu, J.E. Richardson, and V.C. Reinsborough: Langmuir 5, 218 (1989).

    Google Scholar 

  41. I. Satake, T. Ikenoue, T. Takeshita, K. Hayakawa, and T. Maeda: Bull. Chem. Soc. Jpn. 58, 2746 (1985).

    Google Scholar 

  42. H.E. Edwards and J.K. Thomas: Carbohydr. Res. 65, 173 (1978).

    Google Scholar 

  43. R.A. Femia and L.J. Cline Love: J. Colloid Interface Sci. 108, 271 (1985).

    Google Scholar 

  44. K. Shinoda and T. Soda: J. Phys. Chem. 67, 2072 (1963).

    Google Scholar 

  45. K. Shinoda, M. Hato, and T. Hayashi: J. Phys. Chem. 76, 909 (1972).

    Google Scholar 

  46. J. F. Wojcik and R.P. Rohrbach: J. Phys. Chem. 79, 2251 (1975).

    Google Scholar 

  47. R.L. Kay: in R. Frank (ed.), Water, a Comprehensive Treatise, Vol. 3, Plenum Press, New York (1973), p. 194.

    Google Scholar 

  48. R.L. Kay: in R.F. Gould (ed.), Advance Chemical Series, No. 73, American Chemical Society, Washington (1968), p. 1.

    Google Scholar 

  49. H. Hoiland, J.A. Ringseth, and T.S. Brun: J. Solution Chem. 8, 779 (1979).

    Google Scholar 

  50. J.J. Christensen, D.J. Eatough, and R.M. Izatt: Chem. Rev. 74, 351 (1974).

    Google Scholar 

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  1. Department of Chemistry, Guru Nanak Dev University, Amritsar, 143005, India

    Mandeep Singh Bakshi

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Bakshi, M.S. Micelle Formation by Sodium Perfluorooctanoate and Decyltrimethylammonium Bromide in 18-Crown-6 + β-Cyclodextrin + Water Systems. Journal of Inclusion Phenomena 33, 263–276 (1999). https://doi.org/10.1023/A:1008036026106

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