Skip to main content
SpringerLink
Log in

Mechanochemical Reactions in Mixtures of Lead Oxides

  • Published:
Inorganic Materials Aims and scope

Abstract

The mechanochemical processes, including mechanochemical synthesis of mixed-valence lead oxides, in mixtures of PbO, Pb3O4 , and PbO2were studied by x-ray diffraction. The results demonstrate that the reduction of Pb4+is accompanied by the formation of Pb2O3 , Pb3O4 , and possibly PbO1.37 . Phases of variable composition close in structure to minium, Pb3O4 , are shown to coexist during mechanical processing. The structure of the metastable oxide Pb3O4 – x with Pb2+: Pb4+> 2 (@O4 – 2x ) is tentatively determined. The sequence of the observed transformations is interpreted in terms of the model for the reaction zone, with consideration for primary and secondary interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Zyryanov, V.V., Sysoev, V.F., and Boldyrev, V.V., Mechanochemical Ceramic Processing, Dokl. Akad. Nauk SSSR, 1988, vol. 300, no. 1, pp. 162–165.

    Google Scholar 

  2. Gleiter, H., Nanocrystalline Materials, Prog. Mater. Sci., 1989, vol. 33, pp. 223–315.

    Google Scholar 

  3. Zyryanov, V.V., Mechanochemical Ceramic Processing: Developments and Prospects, Mekhanokhimicheskii sintez v neorganicheskoi khimii (Mechanochemical Synthesis in Inorganic Chemistry), Avvakumov, E.G., Ed., Novosibirsk: Nauka, 1991, pp. 102–125.

    Google Scholar 

  4. Zyryanov, V.V., USSR Inventor's Certificate no. 1403439, 1988.

  5. Zyryanov, V.V., RF Patent 2065768, 1996.

  6. Zyryanov, V.V., Sysoev, V.F., Boldyrev, V.V., and Korosteleva, T.V., USSR Inventor's Certificate no. 1375328, Otkrytiya, Izobret., 1988, no. 7, p. 39.

  7. Zyryanov, V.V., A Model for the Reaction Zone in Powders Mechanically Activated in a Planetary Mill, Neorg. Mater., 1998, vol. 34, no. 12, pp. 1525–1534 [Inorg. Mater. (Engl. Transl.), vol. 34, no. 12, pp. 1290-1298].

    Google Scholar 

  8. Butyagin, P.Yu., Physical and Chemical Relaxation Processes in Solids: Mechanochemical Reactions in Binary Systems, Mekhanokhimicheskii sintez v neorganicheskoi khimii (Mechanochemical Synthesis in Inorganic Chemistry), Avvakumov, E.G., Ed., Novosibirsk: Nauka, 1991, pp. 32–52.

    Google Scholar 

  9. Fleischer, M., Wilcox, R.E., and Matzko, J.J., Microscopic Determination of Nonopaque Minerals, US Geol. Surv. Bull., 1984, no. 1627. Translated under the title Mikroskopicheskoe opredelenie prozrachnykh mineralov, Leningrad: Nedra, 1987.

  10. Zyryanov, V.V. and Lapina, O.B., Mechanochemical Synthesis and Structure of New Phases in the Pb-V-O System, Neorg. Mater., 2001, vol. 37, no. 3, pp. 331–337 [Inorg. Mater. (Engl. Transl.), vol. 37, no. 3, pp. 264-270].

    Google Scholar 

  11. Zyryanov, V.V., Mechanically Induced Phase Transformations in PbO, Neorg. Mater., 1997, vol. 33, no. 10, pp. 1228–1234 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 10, pp. 1039-1045].

    Google Scholar 

  12. Avvakumov, E.G., Kosova, N.V., and Aleksandrov, V.V., Effect of Mechanical Activation on the Decomposition of Lead Dioxide, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk., 1983, vol. 3, no. 7, pp. 25–30.

    Google Scholar 

  13. Avvakumov, E.G., Mekhanicheskie metody aktivatsii khimicheskikh protsessov (Mechanical Methods for Activating Chemical Processes), Novosibirsk: Nauka, 1979.

    Google Scholar 

  14. Zyryanov, V.V., Lyakhov, N.Z., and Boldyrev, V.V., ESR Study of Titania Mechanolysis, Dokl. Akad. Nauk SSSR, 1981, vol. 258, no. 2, pp. 394–397.

    Google Scholar 

  15. Zyryanov, V.V., Mechanochemical Synthesis of MM'O4 Oxides with the Scheelite Structure, Neorg. Mater., 2000, vol. 36, no. 1, pp. 63–69 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 1, pp. 54-59].

    Google Scholar 

  16. Zyryanov, V.V., Mechanochemical Synthesis of Lead Titanate, Neorg. Mater., 1999, vol. 35, no. 9, pp. 1101–1107 [Inorg. Mater. (Engl. Transl.), vol. 35, no. 9, pp. 935-940].

    Google Scholar 

  17. Zyryanov, V.V., Mechanochemical Effects in Oxide Systems, Extended Abstract of Doctoral (Chem.) Dissertation, Novosibirsk, 2000.

  18. Bokhonov, B.B., Konstanchuk, I.G., and Boldyrev, V.V., Structural and Morphological Changes during the Mechanical Activation of Nano-Size Particles, Mater. Res. Bull., 1995, vol. 30, no. 10, pp. 1277–1284.

    Google Scholar 

  19. Heinike, G., Tribochemistry, Berlin: Akademie, 1984. Translated under the title Tribokhimiya, Moscow: Mir, 1987.

    Google Scholar 

  20. Zyryanov, V.V., Mechanochemical Equilibrium in Pb2MoO5 Synthesis, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk., 1990, vol. 2, pp. 101–106.

    Google Scholar 

  21. Gol'dberg, E.L. and Shapkin, V.L., Vibrational Instability of Mechanochemical Equilibrium, Sib. Khim. Zh., 1991, vol. 6, pp. 120–127.

    Google Scholar 

  22. Wells, A.F., Structural Inorganic Chemistry, Oxford: Clarendon, 1986, vol. 3, 5th ed.

    Google Scholar 

  23. Urusov, V.S., Teoreticheskaya kristallokhimiya (Theoretical Crystal Chemistry), Moscow: Mosk. Gos. Univ., 1987.

    Google Scholar 

  24. Venevtsev, Yu.N., Politova, E.D., and Ivanov, S.A., Segneto-i antisegnetoelektriki semeistva titanata bariya (Ferro-and Antiferroelectrics of the Barium Titanate Family), Moscow: Khimiya, 1985.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Mechano- and Solid-State Chemistry, Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    V. V. Zyryanov & A. A. Gusev

Authors
  1. V. V. Zyryanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zyryanov, V.V., Gusev, A.A. Mechanochemical Reactions in Mixtures of Lead Oxides. Inorganic Materials 37, 257–263 (2001). https://doi.org/10.1023/A:1004117414763

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1004117414763

Keywords

Search

Navigation