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Quantitative EPR Investigation of Binary Mixed Oxides Containing V2O5 Prepared by Mechanochemical Activation

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Abstract

Seven binary mixed oxides of V2O5, MoO3, TiO2, B2O3, Bi2O3, In2O3, and Tm2O3, in which V2O5 is a permanent component, were prepared by the method of mechanochemical activation (MCA). All composites have been investigated using EPR spectroscopy, X-ray diffraction, BET analysis and EPR spectra calculations. The results obtained were compared with those for individual V2O5 powder. The kinetic of structural transformations occurring in these binary mixtures under MCA were quantitatively characterized using a developed program of EPR spectra analysis. These structural rearrangements are fitted well by the first-order rate constants. Influence of the oxide nature mixed with vanadium pentoxide, the ratio of the components and time of milling on these transformations are discussed.

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Acknowledgements

This work was supported by the State assignment of RF No AAAA-A20-120021390044-2 and partially by Russian Foundation for Basic Research (Grant No. 19-03-00358-a). We are thankful to Prof. A. Kh. Vorob’ev (Department of Chemistry, M. V. Lomonosov Moscow State University) provided us his computer Program package and to Dr. Y. N. Kozlov (N. Semenov Federal Research Center for Chemical Physics RAS) for helpful discussions.

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Authors and Affiliations

  1. N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

    A. I. Kokorin, S. O. Travin, I. V. Kolbanev, E. N. Degtyarev, A. B. Borunova, G. A. Vorobieva, A. A. Dubinsky & A. N. Streletskii

  2. Plekhanov Russian University of Economics, Moscow, Russian Federation

    A. I. Kokorin

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  1. A. I. Kokorin
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  2. S. O. Travin
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  3. I. V. Kolbanev
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  4. E. N. Degtyarev
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  5. A. B. Borunova
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  6. G. A. Vorobieva
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  8. A. N. Streletskii
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Correspondence to A. I. Kokorin.

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Kokorin, A.I., Travin, S.O., Kolbanev, I.V. et al. Quantitative EPR Investigation of Binary Mixed Oxides Containing V2O5 Prepared by Mechanochemical Activation. Appl Magn Reson 52, 927–944 (2021). https://doi.org/10.1007/s00723-021-01314-5

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