Abstract
Platinum particles dispersed in a polyaniline film (PAni/Pt) provide a better catalyst than smooth Pt for the electrooxidation of β-d(+)glucose in perchloric acid aqueous solutions. The Pt particles are less sensitive to poison formation than smooth platinum. Their catalytic activity is influenced by modification with underpotential deposition (u.p.d.) of thallium, lead or bismuth. Up to 0.4V vs RHE the Pt particles show a better activity than u.p.d.- modified platinum particles. However, above 0.4V the u.p.d.-modified particles are more active than bare Pt particles. Underpotential deposition of cadmium inhibits the electrooxidation of β- d(+)glucose. The morphology and the nature of the metallic dispersion were examined by transmission electron microscopy.
Similar content being viewed by others
References
S. K. Wolfson, Jr., S. L. Goldberg, P. Prusiner and L. Navies, Trans. Am. Soc. Artif. Intern. Organs 14 (1968) 839.
S. J. Yao, A. J. Appleby, A. Geisel, H. R. Cash and S. Wolfson, Nature (UK) 224 (1969) 421.
K. W. Chang, S. Aisenberg, J. S. Soeldner and J. M. Hie-bert, Trans. Am. Soc. Artif. Intern. Organs 19 (1973) 352.
J. R. Rao, G. J. Richter, F. Von Sturm and E. Weidlich, Bioelectrochem. Bioenerg. 3 (1976) 139.
V. Gebhardt, G. Luft, G. Richter and F. Von Sturm, ibid. 5 (1978) 607.
M. L. B. Rao and R. F. Drake, J. Electrochem. Soc. 116 (1969) 334.
S. J. Yao, A. J. Appleby and S. Wolfson, Jr., Z. Phys. Chem. NF 82 (1972) 225.
E. Skou, Electrochim. Acta 22 (1977) 313.
S. Ernst, J. Heitbaum and C. H. Hamann, J. Electroanal. Chem. 100 (1979) 173.
H. Lerner, J. Giner, J. S. Soeldner and C. Colton, J. Elec-trochem. Soc. 126 (1979) 237.
S. Ernst, J. Heitbaum and C. H. Hamann, Ber. Bunsenges. Phys. Chem. 84 (1980) 50.
M. F. L. Mele, H. A. Videla and A. J. Arvia, Bioelectro-chem. Bioenerg. 9 (1982) 469.
Idem, ibid. 10 (1983) 239.
Yu. B. Vassiliev, O. A. Khazova and N. N. Nikolaeva, J. Electroanal. Chem. 196 (1985) 105.
A. E. Bolzan, T. Iwasita and W. Vielstich, J. Electrochem. Soc. 134 (1987) 3052.
A. M. Castro Luna, A. Bolzan, M. F. L. Mele and A. J. Arvia, Z. Phys. Chem. 160 (1988) 25.
K. Popovic, A. Tripkovic, N. Markovic and R. R. Adzic, J. Electroanal. Chem. 295 (1990) 79.
A. M. Castro Luna, A. Bolzan, M. F. L. Mele and A. J. Arvia, J. Pure Appl. Chem. 63 (1991) 1599.
F. Largeaud, K. B. Kokoh, B. Beden and C. Lamy, J. Electroanal. Chem. 397 (1995) 261.
B. Beden, F. Largeaud, K. B. Kokoh and C. Lamy, Elec-trochim. Acta 41 (1996) 701.
Yu. B. Vassiliev, O. A. Khazova and N. N. Nikolaeva, J. Electroanal. Chem. 196 (1985) 127.
M. F. L. Mele, H. A. Videla and A. J. Arvia, Bioelectro-chem. Bioenerg. 16 (1986) 213.
R. R. Adzic, M. W. Hsiao and E. B. Yeager, J. Electroanal. Chem. 260 (1989) 475.
M. Castro Luna, M. F. L. Mele and A. J. Arvia, J. Elec-troanal. Chem. 323 (1992) 149.
N. Xonoglou, I. Moumtzis and G. Kokkinidis, ibid. 237 (1987) 93.
K. B. Kokoh, J.-M. Leger, B. Beden and C. Lamy, Elec-trochim. Acta 37 (1992) 133
J. Giner and P. Malachesky, Proceedings of the Artifical Heart Program Conference, US Department of Health, Education and Welfare, Washington DC (1969), p. 839.
I. T. Bae, X. Xing, C. C. Liu and E. Yeager, J. Electroanal. Chem. 284 (1990) 335.
I. T. Bae and E. Yeager, J. Electroanal. Chem. 309 (1991) 131.
M. Sakamoto and K. Takamura, Bioelectrochem. Bioenerg. 9 (1982) 571.
N. Xonoglou and G. Kokkinidis, Bioelectrochem. Bioenerg 12 (1984) 485; ibid 14 (1985) 375.
G. Kokkinidis, J.-M. Léger and C. Lamy, J. Electroanal. Chem. 242 (1988) 221.
G. Tourillon and F. Garnier, J. Phys. Chem. 88 (1984) 5281.
W.-H. Kao and T. Kuwana, J. Am. Chem. Soc. 106 (1984) 473.
D. E. Bartak, B. Kazee, K. Shimazu and T. Kuwana, Anal. Chem. 58 (1986) 2756.
L. Coche and J.-C. Moutet, J. Am. Chem. Soc. 109 (1987) 6887.
K. M. Kost, D. E. Bartak, B. Kazee and T. Kuwana, Anal. Chem. 60 (1988) 2379.
S. Holdcroft and B. L. Funt, J. Electroanal. Chem. 240 (1988) 89.
P. O. Esteban, J.-M. Léger, C. Lamy and E. Genies, J. Appl. Electrochem. 19 (1989) 462.
M. Gholamian and A. Q. Contractor, J. Electroanal. Chem. 289 (1990) 69.
D. J. Strike, N. F. Rooij, M. Koudelka-Hep, M. Ulmann and J. Augustynski, J. Appl. Electrochem. 22 (1992) 922.
M. Ulmann, R. Kostecki, J. Augustynski, D. J. Strike and M. Koudelka-Hep, Chimia 46 (1992) 138.
A. Leone, W. Marino and B. R. Scharifker, J. Electrochem. Soc. 139 (1992) 438.
C. S. C. Bose and K. Rajeshwar, J. Electroanal. Chem. 333 (1992) 235.
C. C. Chen, C. S. C. Bose and K. Rajeshwar, J. Electroanal. Chem. 350 (1993) 161.
H. Laborde, J.-M. Léger and C. Lamy, J. Appl. Electro-chem. 24 (1994) 219.
W. T. Napporn, H. Laborde, J.-M. Léger and C. Lamy, J. Electroanal. Chem. 404 (1996) 153.
W. T. Napporn, J.-M. Léger and C. Lamy, J. Electroanal. Chem. 408 (1996) 141.
S. Ye, A. K. Vijh and L. H. Dao, J. Electroanal. Chem. 415 (1996) 115.
C. T. Hable and M. S. Wrighton, Langmuir 9 (1993) 3284.
R. Schrebler, M. A. del Valle, H. Gomez, C. Veas and R. Cordova, J. Electroanal. Chem. 380 (1995) 219.
Y. Takasu, N. Ohashi, X.-C. Zhang, Y. Murakami, H. Minagawa, S. Sato and K. Yahikozawa, Electrochim. Acta 41 (1996) 2595.
A. Kelaidopoulou, E. Abelidou, A. Papoutsis, E. K. Poly-chroniadis and G. Kokkinidis, J. Appl. Electrochem. (1998), in press.
J.-C. LaCroix and A. F. Diaz, J. Electrochem. Soc. 135 (1988) 1457.
D. E. Stilwell and S.-M. Park, J. Electrochem. Soc. 135 (1988) 2491.
J. V. Smith (Ed.), ‘X-ray Powder Data File’, American Society for Testing Materials, (1960) card 4-802.
R. R. Adzic, in H. Gerischer and C. W. Tobias (Eds), ‘Advances in Eletrochemistry and Electrochemical En-gineering’, Vol. 13 (Wiley, New York, 1984), p. 159.
G. Kokkinidis, J. Electroanal. Chem. 201 (1986) 206.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kelaidopoulou, A., Papoutsis, A., Kokkinidis, G. et al. Electrooxidation of β-D(+)glucose on bare and u.p.d. modified platinum particles dispersed in polyaniline. Journal of Applied Electrochemistry 29, 101–107 (1999). https://doi.org/10.1023/A:1003433206439
Issue Date:
DOI: https://doi.org/10.1023/A:1003433206439