Abstract
Saturated vapor pressure, critical evaporation temperature and evaporation loss rate of Fe-Ga alloy were calculated under different conditions of Ga and Fe contents with activity coefficients. The relationship between the change of Ga content and melting time was determined. The results demonstrated that saturated vapor pressure of Ga was higher than that of Fe under the same conditions. The difference value of critical evaporation temperature of Ga with and without Ar was nearly 800 K. The critical evaporation temperature of Fe was higher than that of Ga under vacuum, indicating that Ga was more volatile than Fe. At 1 800 K, the evaporation rate of Ga was 84 times higher than that of Fe in the melt of Fe81Ga19 alloy. Under this condition, the change of Ga content and smelting time kept a linear relationship. The higher the temperature was, the faster the Ga content decreased, which was consistent with theoretical calculations.
Similar content being viewed by others
References
R. A. Kellogg, A. B. Flatau, A. E. Clark, J. Appl. Phys. 91 (2002) 7821–7823.
J. Boisse, H. Zapolsky, A. G. Khachaturyan, Acta. Mater. 59 (2011) 2656–2668.
S. M. Na, A.B. Flatau, J. Mater. Sci. 49 (2014) 7697–7706.
I. S. Golovin, V. V. Palacheva, V. Y. Zadorozhnyy, J. Zhu, H. Jiang, J. Cifre, T. A. Lograsso, Acta Mater. 78 (2014) 93–102.
C. Yuan, J. H. Li, X. Q. Bao, X. X. Gao, J. Magn. Magn. Mater. 362 (2014) 154–158.
M. V. Petrik, O. I. Gorbatov; Y. N. Gornostyrev, JETP Lett. 98 (2014) 809–812.
I. S. Golovin, J. Cifre, J. Alloys Comp. 584 (2014) 322–326.
P. Gong, L. P. Jiang, Z. Q. Zhao, S. X. Wu, Rare Metal Mat. Eng. 42 (2013) 2139–2143.
M. Ramanathan, B. Saha, C. Ren, S. Guruswamy, M. K. McCarter, Mater. Sci. Eng. A. 578 (2013) 54–61.
D. Iselt, U. Gaitzsch, S. Oswald, S. Faehler, L. Schultz, H. Schloerb, Electrochim. Acta 56 (2011) 5178–5183.
A. G. Olabi, A. Grunwald, Mater. Des. 29 (2008) 469–483.
Q. Xing, T. A. Lograsso, Scripta Mater. 65 (2011) 359–362.
H. Basumatary, M. Palit, J. A. Chelvane, Scripta Mater. 59 (2008) 878–881.
J. K. Zhou, J. G. Li, Physica B 403 (2008) 3932–3936.
H. Wang, Z. D. Zhang, R. Q .Wu, L. Z. Sun, Acta Mater. 61 (2013) 2919–2925.
Q. Xing, T. A. Lograsso, Scripta Mater. 65 (2011) 359–362.
S. M. Na, S. J. Suh, A. B. Flatau, J. Magn. Magn. Mater. 310 (2007) 2630–2632.
H. Y. Yasuda, T. Maruyama, Mater. Trans. 54 (2013) 36–42.
C. Li, J. H. Liu, C. B. Jiang, Metall. Mater. Trans. A 43 (2012) 4514–4519.
J. H. Li, X. X. Gao, J. X. Xie, J. Zhu, X. Q. Bao, R. B. Yu, Physica B 407 (2012) 1186–1190.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation Item: Item Sponsored by National Natural Science Foundation of China (51161019); Project of Department of Science and Technology of Jiangxi Province of China (20133BBE50011); Project of Department of Science & Technology of Jiangxi Province of China (20141BDH80025)
Rights and permissions
About this article
Cite this article
Yan, Jw., Luo, L., Peng, Af. et al. Behavior of Element Vaporization and Composition Control of Fe-Ga alloy during Vacuum Smelting. J. Iron Steel Res. Int. 22, 983–989 (2015). https://doi.org/10.1016/S1006-706X(15)30100-X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1016/S1006-706X(15)30100-X