Abstract
The graphene oxide and metal oxide–grafted graphene composites are studied on their promising electrochemical properties for high-performance supercapacitor applications. The identical decoration of metal oxide nanomaterials over the graphene structure reveals enhanced structural, thermal, and electrochemical stability to fabricate stable electrode materials. In the study, we review our recent studies on the utilization of graphene oxide and metal oxide–graphene grafted nanocomposites for energy storing applications.
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References
K. Satheesh, R. Jayavel, Synthesis and electrochemical properties of reduced graphene oxide via chemical reduction using thiourea as a reducing agent. Mater. Lett. 113, 5–8 (2013)
V. Thirumal, A. Pandurangan, R. Jayavel, K.S. Venkatesh, N.S. Palani, R. Ragavan, R. Ilangovan, Single pot electrochemical synthesis of functionalized and phosphorus doped graphene nanosheets for supercapacitor applications. J. Mater. Sci. Mater. Electron. 26, 6319–6328 (2015)
V. Thirumal, A. Pandurangan, R. Jayavel, R. Ilangovan, Synthesis and characterization of boron doped graphene nanosheets for supercapacitor applications. Synth. Met. 220, 524–532 (2016)
S. Dorothy, T. Lavanya, K. Punithamurthy, R. Jayavel, K. Satheesh, Optical characterization and electrochemical properties of Cd(1− x )Cu( x )S/rGO Composites synthesized through reflux method. J. Nanosci. Nanotechnol. 16, 9716–9721 (2016)
T. Saravanan, M. Shanmugam, P. Anandan, M. Azhagurajan, K. Pazhanivel, M. Arivanandhan, Y. Hayakawa, R. Jayavel, Facile synthesis of graphene-CeO2 nanocomposites with enhanced electrochemical properties for supercapacitors. Dalton Trans. 44, 9901–9908 (2015)
M. Murugan, R.M. Kumar, A. Alsalme, A. Alghamdi, R. Jayavel, Facile hydrothermal preparation of niobium pentaoxide decorated reduced graphene oxide nanocomposites for supercapacitor applications. Chem. Phys. Lett. 650, 35–40 (2016)
V. Rajeswari, R. Jayavel, A. Clara Dhanemozhi, Synthesis and characterization of graphene-zinc oxide nanocomposite electrode material for supercapacitor applications. Mater. Today Proc. 4(2), 645–652 (2017). https://doi.org/10.1016/j.matpr.2017.01.068
R. Thangappan, S. Kalaiselvam, A. Elayaperumal, R. Jayavel, M. Arivanandhan, R. Karthikeyan, Y. Hayakawa, Graphene decorated with MoS2 nanosheets: a synergetic energy storage composite electrode for supercapacitor applications. Dalton Trans. 45, 2637–2646 (2016)
P. Nagaraju, A. Alsalme, A. Alswieleh, R. Jayavel, Facile in-situ microwave irradiation synthesis of TiO2/graphene nanocomposite for high-performance supercapacitor applications. J. Electroanal. Chem. 808, 90–100 (2018)
P. Nagaraju, A. Alsalme, A.M. Alkathiri, R. Jayavel, Rapid synthesis of WO3/graphene nanocomposite via in-situ microwave method with improved electrochemical properties. J. Phys. Chem. Solids 120, 250–260 (2018)
N.A. Kalam, C. Sengottaiyan, R. Jayavel, K. Ariga, R.G. Shrestha, T. Subramani, S. Sankar, L.K. Shrestha, Vanadium sulfide/reduced graphene oxide composite with enhanced supercapacitance performance. J. Taiwan Inst. Chem. Eng. 92, 72–79 (2018)
R. Thangappan, M. Arivanandhan, R. Dhinesh Kumar, R. Jayavel, Facile synthesis of RuO2 nanoparticles anchored on graphene nanosheets for high performance composite electrode for supercapacitor applications. J. Phys. Chem. Solids 121, 339–349 (2018)
T. Saravanan, P. Anandan, M. Shanmugam, T. Jayakumari, M. Arivanandhan, M. Azhagurajan, Y. Hayakawa, R. Jayavel, Impact of graphene on the enhancement of electrochemical and photocatalytic performance of Gd2O3 - graphene nanocomposites. Solid State Sci. 83, 171–180 (2018)
C. Sengottaiyan, N.A. Kalam, R. Jayavel, R.G. Shrestha, T. Subramani, S. Sankar, J.P. Hill, L.K. Shrestha, K. Ariga, BiVO4/RGO hybrid nanostructure for high performance electrochemical supercapacitor. J. Solid State Chem. 269, 409–418 (2019)
P. Nagaraju, R. Vasudevan, M. Arivanandhan, A. Alsalme, R. Jayavel, High-performance electrochemical capacitor based on cuprous oxide/graphene nanocomposite electrode material synthesized by microwave irradiation method. Emergent Mater. 2, 495–504 (2019)
M.M. Ismail, S. Hemaanandhan, D. Mani, M. Arivanandhan, G. Anbalagan, R. Jayavel, Facile preparation of Mn3O4/rGO hybrid nanocomposite by sol gel in situ reduction method with enhanced energy storage performance for supercapacitor applications. J. Sol-Gel Sci. Technol. 93, 703–713 (2019)
T. Saravanan, P. Anandan, M. Shanmugam, M. Azhagurajan, M.M. Ismail, M. Arivanandhan, Y. Hayakawa, R. Jayavel, Facile synthesis of Yb2OS graphene nanocomposites for enhanced energy and environmental applications. Polym. Bull. 77, 3891–3906 (2019)
R. Selvarajan, S. Vadivel, M. Arivanandhan, R. Jayavel, Facile synthesis of pervoskite type BiYO3 embedded reduced graphene oxide (RGO) composite for supercapacitor applications. Ceram. Int. 46, 3471–3478 (2020)
V. Venkatachalam, R. Jayavel, 1D/2D Co3O4/Graphene composite electrodes for high-performance supercapacitor applications. J. Electron. Mater. 49, 3174–3181 (2020)
R. Thangappan, R. Dhinesh Kumar, R. Jayavel, Synthesis, structural and electrochemical properties of Mn-MoO4/graphene nanocomposite electrode material with improved performance for supercapacitor application. J. Energy Storage 27, 101069 (2020)
P. Nagaraju, M. Arivanandhan, A. Alsalme, A. Alghamdi, R. Jayavel, Enhanced electrochemical performance of α-MoO3/graphene nanocomposites prepared by an in situ microwave irradiation technique for energy storage applications. RSC Adv. 10, 22836–22847 (2020)
P. Nagaraju, R. Vasudevan, A. Alsalme, A. Alghamdi, M. Arivanandhan, R. Jayavel, Surfactant-free synthesis of Nb2O5 nanoparticles anchored graphene nanocomposites with enhanced electrochemical performance for supercapacitor electrodes. Nanomaterials 10, 160 (2020)
R. Thangappan, S. Kalaiselvam, A. Elayaperumal, R. Jayavel, Synthesis of graphene oxide/vanadium pentoxide composite nanofibers by electrospinning for supercapacitor applications. Solid State Ionics 268, 321–325 (2014)
J. Jayachandiran, M. Arivanandhan, O. Padmaraj, R. Jayavel, D. Nedumaran, Investigation on ozone-sensing characteristics of surface sensitive hybrid rGO/WO3 nanocomposite films at ambient temperature. Adv. Compos. Mater. 3, 16–30 (2020)
P. Sivasamy, S. Harikrishnan, R. Jayavel, S.I. Hussain, S. Kalaiselvam, L. Lu, Preparation and thermal characteristics of caprylic acid based composite as phase change material for thermal energy storage. Mater. Res. Express. 6, 105051 (2019)
R. Rajendran, L.K. Shrestha, K. Minami, M. Subramanian, R. Jayavel, K. Ariga, Dimensionally integrated nanoarchitectonics for a novel composite from 0D, 1D, and 2D nanomaterials: RGO/CNT/CeO2 ternary nanocomposites with electrochemical performance. J. Mater. Chem. A 2, 18480–18487 (2014)
R. Rajendran, L.K. Shrestha, R.M. Kumar, R. Jayavel, J.P. Hill, K. Ariga, Composite nanoarchitectonics for ternary systems of reduced graphene oxide/carbon nanotubes/nickel oxide with enhanced electrochemical capacitor performance. J. Inorg. Organomet. Polym. Mater. 25, 267–274 (2015)
C. Sengottaiyan, R. Jayavel, R.G. Shrestha, J.P. Hill, K. Ariga, L.K. Shrestha, Electrochemical supercapacitance properties of reduced graphene oxide/Mn2O3:Co3O4 nanocomposite. J. Inorg. Organomet. Polym. Mater. 27, 576–585 (2017)
C. Sengottaiyan, R. Jayavel, R.G. Shrestha, T. Subramani, S. Maji, J.H. Kim, J.P. Hill, K. Ariga, L.K. Shrestha, Indium oxide/carbon nanotube/reduced graphene oxide ternary nanocomposite with enhanced electrochemical supercapacitance. Bull. Chem. Soc. Jpn. 92, 521–528 (2019)
D. Selvakumar, H. Sivaram, A. Alsalme, A. Alghamdi, R. Jayavel, Facile synthesize of free standing highly conducting flexible reduced graphene oxide paper. J. Mater. Sci. Mater. Electron. 27, 6232–6241 (2016)
M. Murugan, R.M. Kumar, A. Alsalme, A. Alghamdi, R. Jayavell, In situ hydrothermal synthesis of graphene-CuO nanocomposites for lithium battery applications. J. Nanosci. Nanotechnol. 16, 317–320 (2016)
D. Selvakumar, A. Alsalme, A. Alghamdi, R. Jayavel, Reduced graphene oxide paper as bimorphic electrical actuators. Mater. Lett. 191, 182–185 (2017)
D. Selvakumar, A. Alsalme, A. Alswieleh, R. Jayavel, Freestanding flexible nitrogen doped-reduced graphene oxide film as an efficient electrode material for solid-state supercapacitors. J. Alloys Compd. 723, 995–1000 (2017)
D. Selvakumar, G. Murugadoss, A. Alsalme, A.M. Alkathiri, R. Jayavel, Heteroatom doped reduced graphene oxide paper for large area perovskite solar cells. Sol. Energy 163, 564–569 (2018)
D. Selvakumar, H. Sivaram, A. Alsalme, A. Alghamdi, R. Jayavel, Freestanding flexible, pure and composite form of reduced graphene oxide paper for ammonia vapor sensing. Sci. Rep. 9, 8749 (2019)
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Selvakumar, D., Nagaraju, P., Arivanandhan, M. et al. Metal oxide–grafted graphene nanocomposites for energy storage applications. emergent mater. 4, 1143–1165 (2021). https://doi.org/10.1007/s42247-021-00215-4
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DOI: https://doi.org/10.1007/s42247-021-00215-4