Skip to main content

Advertisement

Log in

Metal oxide–grafted graphene nanocomposites for energy storage applications

  • Review
  • Published:
Emergent Materials Aims and scope Submit manuscript

Abstract

The graphene oxide and metal oxide–grafted graphene composites are studied on their promising electrochemical properties for high-performance supercapacitor applications. The identical decoration of metal oxide nanomaterials over the graphene structure reveals enhanced structural, thermal, and electrochemical stability to fabricate stable electrode materials. In the study, we review our recent studies on the utilization of graphene oxide and metal oxide–graphene grafted nanocomposites for energy storing applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23
Fig. 24
Fig. 25

Similar content being viewed by others

References

  1. K. Satheesh, R. Jayavel, Synthesis and electrochemical properties of reduced graphene oxide via chemical reduction using thiourea as a reducing agent. Mater. Lett. 113, 5–8 (2013)

    Article  CAS  Google Scholar 

  2. V. Thirumal, A. Pandurangan, R. Jayavel, K.S. Venkatesh, N.S. Palani, R. Ragavan, R. Ilangovan, Single pot electrochemical synthesis of functionalized and phosphorus doped graphene nanosheets for supercapacitor applications. J. Mater. Sci. Mater. Electron. 26, 6319–6328 (2015)

    Article  CAS  Google Scholar 

  3. V. Thirumal, A. Pandurangan, R. Jayavel, R. Ilangovan, Synthesis and characterization of boron doped graphene nanosheets for supercapacitor applications. Synth. Met. 220, 524–532 (2016)

    Article  CAS  Google Scholar 

  4. S. Dorothy, T. Lavanya, K. Punithamurthy, R. Jayavel, K. Satheesh, Optical characterization and electrochemical properties of Cd(1− x )Cu( x )S/rGO Composites synthesized through reflux method. J. Nanosci. Nanotechnol. 16, 9716–9721 (2016)

    Article  CAS  Google Scholar 

  5. T. Saravanan, M. Shanmugam, P. Anandan, M. Azhagurajan, K. Pazhanivel, M. Arivanandhan, Y. Hayakawa, R. Jayavel, Facile synthesis of graphene-CeO2 nanocomposites with enhanced electrochemical properties for supercapacitors. Dalton Trans. 44, 9901–9908 (2015)

    Article  CAS  Google Scholar 

  6. M. Murugan, R.M. Kumar, A. Alsalme, A. Alghamdi, R. Jayavel, Facile hydrothermal preparation of niobium pentaoxide decorated reduced graphene oxide nanocomposites for supercapacitor applications. Chem. Phys. Lett. 650, 35–40 (2016)

    Article  CAS  Google Scholar 

  7. V. Rajeswari, R. Jayavel, A. Clara Dhanemozhi, Synthesis and characterization of graphene-zinc oxide nanocomposite electrode material for supercapacitor applications. Mater. Today Proc. 4(2), 645–652 (2017). https://doi.org/10.1016/j.matpr.2017.01.068

  8. R. Thangappan, S. Kalaiselvam, A. Elayaperumal, R. Jayavel, M. Arivanandhan, R. Karthikeyan, Y. Hayakawa, Graphene decorated with MoS2 nanosheets: a synergetic energy storage composite electrode for supercapacitor applications. Dalton Trans. 45, 2637–2646 (2016)

    Article  CAS  Google Scholar 

  9. P. Nagaraju, A. Alsalme, A. Alswieleh, R. Jayavel, Facile in-situ microwave irradiation synthesis of TiO2/graphene nanocomposite for high-performance supercapacitor applications. J. Electroanal. Chem. 808, 90–100 (2018)

    Article  CAS  Google Scholar 

  10. P. Nagaraju, A. Alsalme, A.M. Alkathiri, R. Jayavel, Rapid synthesis of WO3/graphene nanocomposite via in-situ microwave method with improved electrochemical properties. J. Phys. Chem. Solids 120, 250–260 (2018)

    Article  CAS  Google Scholar 

  11. N.A. Kalam, C. Sengottaiyan, R. Jayavel, K. Ariga, R.G. Shrestha, T. Subramani, S. Sankar, L.K. Shrestha, Vanadium sulfide/reduced graphene oxide composite with enhanced supercapacitance performance. J. Taiwan Inst. Chem. Eng. 92, 72–79 (2018)

    Article  Google Scholar 

  12. R. Thangappan, M. Arivanandhan, R. Dhinesh Kumar, R. Jayavel, Facile synthesis of RuO2 nanoparticles anchored on graphene nanosheets for high performance composite electrode for supercapacitor applications. J. Phys. Chem. Solids 121, 339–349 (2018)

    Article  CAS  Google Scholar 

  13. T. Saravanan, P. Anandan, M. Shanmugam, T. Jayakumari, M. Arivanandhan, M. Azhagurajan, Y. Hayakawa, R. Jayavel, Impact of graphene on the enhancement of electrochemical and photocatalytic performance of Gd2O3 - graphene nanocomposites. Solid State Sci. 83, 171–180 (2018)

    Article  CAS  Google Scholar 

  14. C. Sengottaiyan, N.A. Kalam, R. Jayavel, R.G. Shrestha, T. Subramani, S. Sankar, J.P. Hill, L.K. Shrestha, K. Ariga, BiVO4/RGO hybrid nanostructure for high performance electrochemical supercapacitor. J. Solid State Chem. 269, 409–418 (2019)

    Article  CAS  Google Scholar 

  15. P. Nagaraju, R. Vasudevan, M. Arivanandhan, A. Alsalme, R. Jayavel, High-performance electrochemical capacitor based on cuprous oxide/graphene nanocomposite electrode material synthesized by microwave irradiation method. Emergent Mater. 2, 495–504 (2019)

    Article  CAS  Google Scholar 

  16. M.M. Ismail, S. Hemaanandhan, D. Mani, M. Arivanandhan, G. Anbalagan, R. Jayavel, Facile preparation of Mn3O4/rGO hybrid nanocomposite by sol gel in situ reduction method with enhanced energy storage performance for supercapacitor applications. J. Sol-Gel Sci. Technol. 93, 703–713 (2019)

    Article  Google Scholar 

  17. T. Saravanan, P. Anandan, M. Shanmugam, M. Azhagurajan, M.M. Ismail, M. Arivanandhan, Y. Hayakawa, R. Jayavel, Facile synthesis of Yb2OS graphene nanocomposites for enhanced energy and environmental applications. Polym. Bull. 77, 3891–3906 (2019)

    Article  Google Scholar 

  18. R. Selvarajan, S. Vadivel, M. Arivanandhan, R. Jayavel, Facile synthesis of pervoskite type BiYO3 embedded reduced graphene oxide (RGO) composite for supercapacitor applications. Ceram. Int. 46, 3471–3478 (2020)

    Article  CAS  Google Scholar 

  19. V. Venkatachalam, R. Jayavel, 1D/2D Co3O4/Graphene composite electrodes for high-performance supercapacitor applications. J. Electron. Mater. 49, 3174–3181 (2020)

    Article  CAS  Google Scholar 

  20. R. Thangappan, R. Dhinesh Kumar, R. Jayavel, Synthesis, structural and electrochemical properties of Mn-MoO4/graphene nanocomposite electrode material with improved performance for supercapacitor application. J. Energy Storage 27, 101069 (2020)

    Article  Google Scholar 

  21. P. Nagaraju, M. Arivanandhan, A. Alsalme, A. Alghamdi, R. Jayavel, Enhanced electrochemical performance of α-MoO3/graphene nanocomposites prepared by an in situ microwave irradiation technique for energy storage applications. RSC Adv. 10, 22836–22847 (2020)

    Article  CAS  Google Scholar 

  22. P. Nagaraju, R. Vasudevan, A. Alsalme, A. Alghamdi, M. Arivanandhan, R. Jayavel, Surfactant-free synthesis of Nb2O5 nanoparticles anchored graphene nanocomposites with enhanced electrochemical performance for supercapacitor electrodes. Nanomaterials 10, 160 (2020)

    Article  CAS  Google Scholar 

  23. R. Thangappan, S. Kalaiselvam, A. Elayaperumal, R. Jayavel, Synthesis of graphene oxide/vanadium pentoxide composite nanofibers by electrospinning for supercapacitor applications. Solid State Ionics 268, 321–325 (2014)

    Article  CAS  Google Scholar 

  24. J. Jayachandiran, M. Arivanandhan, O. Padmaraj, R. Jayavel, D. Nedumaran, Investigation on ozone-sensing characteristics of surface sensitive hybrid rGO/WO3 nanocomposite films at ambient temperature. Adv. Compos. Mater. 3, 16–30 (2020)

    Article  CAS  Google Scholar 

  25. P. Sivasamy, S. Harikrishnan, R. Jayavel, S.I. Hussain, S. Kalaiselvam, L. Lu, Preparation and thermal characteristics of caprylic acid based composite as phase change material for thermal energy storage. Mater. Res. Express. 6, 105051 (2019)

    Article  CAS  Google Scholar 

  26. R. Rajendran, L.K. Shrestha, K. Minami, M. Subramanian, R. Jayavel, K. Ariga, Dimensionally integrated nanoarchitectonics for a novel composite from 0D, 1D, and 2D nanomaterials: RGO/CNT/CeO2 ternary nanocomposites with electrochemical performance. J. Mater. Chem. A 2, 18480–18487 (2014)

    Article  CAS  Google Scholar 

  27. R. Rajendran, L.K. Shrestha, R.M. Kumar, R. Jayavel, J.P. Hill, K. Ariga, Composite nanoarchitectonics for ternary systems of reduced graphene oxide/carbon nanotubes/nickel oxide with enhanced electrochemical capacitor performance. J. Inorg. Organomet. Polym. Mater. 25, 267–274 (2015)

    Article  CAS  Google Scholar 

  28. C. Sengottaiyan, R. Jayavel, R.G. Shrestha, J.P. Hill, K. Ariga, L.K. Shrestha, Electrochemical supercapacitance properties of reduced graphene oxide/Mn2O3:Co3O4 nanocomposite. J. Inorg. Organomet. Polym. Mater. 27, 576–585 (2017)

    Article  CAS  Google Scholar 

  29. C. Sengottaiyan, R. Jayavel, R.G. Shrestha, T. Subramani, S. Maji, J.H. Kim, J.P. Hill, K. Ariga, L.K. Shrestha, Indium oxide/carbon nanotube/reduced graphene oxide ternary nanocomposite with enhanced electrochemical supercapacitance. Bull. Chem. Soc. Jpn. 92, 521–528 (2019)

    Article  CAS  Google Scholar 

  30. D. Selvakumar, H. Sivaram, A. Alsalme, A. Alghamdi, R. Jayavel, Facile synthesize of free standing highly conducting flexible reduced graphene oxide paper. J. Mater. Sci. Mater. Electron. 27, 6232–6241 (2016)

    Article  CAS  Google Scholar 

  31. M. Murugan, R.M. Kumar, A. Alsalme, A. Alghamdi, R. Jayavell, In situ hydrothermal synthesis of graphene-CuO nanocomposites for lithium battery applications. J. Nanosci. Nanotechnol. 16, 317–320 (2016)

    Article  CAS  Google Scholar 

  32. D. Selvakumar, A. Alsalme, A. Alghamdi, R. Jayavel, Reduced graphene oxide paper as bimorphic electrical actuators. Mater. Lett. 191, 182–185 (2017)

    Article  CAS  Google Scholar 

  33. D. Selvakumar, A. Alsalme, A. Alswieleh, R. Jayavel, Freestanding flexible nitrogen doped-reduced graphene oxide film as an efficient electrode material for solid-state supercapacitors. J. Alloys Compd. 723, 995–1000 (2017)

    Article  CAS  Google Scholar 

  34. D. Selvakumar, G. Murugadoss, A. Alsalme, A.M. Alkathiri, R. Jayavel, Heteroatom doped reduced graphene oxide paper for large area perovskite solar cells. Sol. Energy 163, 564–569 (2018)

    Article  CAS  Google Scholar 

  35. D. Selvakumar, H. Sivaram, A. Alsalme, A. Alghamdi, R. Jayavel, Freestanding flexible, pure and composite form of reduced graphene oxide paper for ammonia vapor sensing. Sci. Rep. 9, 8749 (2019)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Jayavel.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Selvakumar, D., Nagaraju, P., Arivanandhan, M. et al. Metal oxide–grafted graphene nanocomposites for energy storage applications. emergent mater. 4, 1143–1165 (2021). https://doi.org/10.1007/s42247-021-00215-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42247-021-00215-4

Keywords

Navigation