Abstract
The distribution of inclusions at the bottom of a Ce-treated heavy steel ingot was detected and calculated. The three-dimensional morphology and spatial distribution of CeAlO3 clusters were characterized using the electrolytic extraction and Micro-CT detection. A model of inclusion collision to predict the aggregation of CeAlO3 inclusions in the ingot was established and validated by measured results. Inclusions were mainly CeAlO3 and a small amount of Ce2O2S in the tundish after cerium treatment. The collision and aggregation of inclusions led to the formation of large clusters in the ingot during the solidification process. Large slag entrainment inclusions, large CeAlO3 clusters and small CeAlO3 particles were observed from the center to the edge of the ingot bottom. Large inclusions were mainly concentrated at the center. The number density of inclusions larger than 200 μm was 0.21 mm−3. The maximum diameter of CeAlO3 clusters was 1340 μm. From the edge to the radial center and from the bottom to the top, the average diameter of inclusions gradually increased due to the longer solidification time of the ingot.
Similar content being viewed by others
References
E.J. Pickering, C. Chesman, S. Al-Bermani, M. Holland, P. Davies, J. Talamantes-Silva, Metall. Mater. Trans. B 46 (2015) 1860–1874.
J. Li, X. Xu, N. Ren, M. Xia, J. Li, J. Iron Steel Res. Int. 29 (2022) 1901–1914.
M. Bitterlin, A. Loucif, N. Charbonnier, M. Jahazi, L.P. Lapierre-Boire, J.B. Morin, Eng. Fail. Anal. 68 (2016) 122–131.
W. Yang, X. Wang, L. Zhang, W. Wang, Steel Res. Int. 84 (2013) 878–891.
W. Yang, H. Duan, L. Zhang, Y. Ren, JOM 65 (2013) 1173–1180.
W. Mu, N. Dogan, K.S. Coley, J. Mater. Sci. 53 (2018) 13203–13215.
L. Zhang, Nonmetallic inclusions in steels, Metallurgical Industry Press, Beijing, China, 2019.
Q. Ren, L. Zhang, Metall. Mater. Trans. B 51 (2020) 589–600.
C. Wu, X. Yang, G. Cheng, Adv. Mater. Res. 311–313 (2011) 1032–1035.
Y. Huang, G. Cheng, S. Li, W. Dai, Steel Res. Int. 89 (2018) 1800371.
H. Li, Y. Yu, X. Ren, S. Zhang, S. Wang, J. Iron Steel Res. Int. 24 (2017) 925–934.
S. Gao, M. Wang, J. Guo, H. Wang, J. Zhi, Y. Bao, Steel Res. Int. 90 (2019) 1900194.
F. Huang, J. Li, R. Zang, Ironmak. Steelmak. 50 (2023) 744–756.
S. Luo, Z. Shen, Z. Yu, W. Wang, M. Zhu, Steel Res. Int. 92 (2021) 2000394.
R. Geng, J. Li, C. Shi, J. Iron Steel Res. Int. 29 (2022) 1659–1668.
W. Zheng, X. Yan, S. Xiong, G. Wang, G. Li, J. Rare Earths 39 (2021) 348–356.
G. Cai, Y. Pang, Y. Huang, R.D.K. Misra, ISIJ Int. 59 (2019) 2302–2310.
W. Mu, N. Dogan, K.S. Coley, Metall. Mater. Trans. B 48 (2017) 2092–2103.
Y. Wang, C. Liu, Metall. Mater. Trans. B 51 (2020) 2585–2595.
J. Wang, L. Zhang, Y. Zhang, Q. Ren, H. Duan, Metall. Mater. Trans. B 52 (2021) 2831–2836.
O. Haida, T. Emi, K. Sanbongi, T. Shiraishi, A. Fujiwara, Tetsu-to-Hagane 64 (1978) 1538–1547.
C. Yang, Y. Luan, D. Li, Y. Li, J. Mater. Sci. Technol. 35 (2019) 1298–1308.
C. Zhang, F. Hu, J. Zhou, G. Zhang, W. Zhou, D. Zhang, K. Wu, Steel Res. Int. 94 (2023) 2200946.
W. Chen, L. Zhang, Q. Ren, Q. Wang, X. Cai, Y. Ren, W. Yang, Metall. Mater. Trans. B 52 (2021) 3497–3514.
W. Chen, L. Zhang, Y. Wang, Y. Ren, Q. Ren, W. Yang, Int. J. Heat Mass Transf. 190 (2022) 122789.
L. Zhang, B. Rietow, B.G. Thomas, K. Eakin, ISIJ Int. 46 (2006) 670–679.
D.A. Skobir, M. Godec, M. Balcar, M. Jenko, Vacuum 84 (2009) 205–208.
Q. Zhou, J. Ba, W. Chen, L. Zhang, Metall. Mater. Trans. B 54 (2023) 1565–1581.
W. Liu, X. Zhu, J. Su, Y. Ding, J. Zhou, M. Jiang, X. Wu, Cast Met. 5 (1992) 217–220.
J. Liu, Y. Yang, C. Zhuang, X. Cui, Y. Li, J. Univ. Sci. Technol. Beijing 33 (2011) No. S1, 179–184.
W. Li, H. Shen, X. Zhang, B. Liu, Metall. Mater. Trans. B 45 (2014) 464–471.
Y. Wang, Inclusion evolution in molten and solidifying steel, Carnegie Mellon University, Pittsburgh, USA, 2003.
Y. Wang, M. Valdez, S. Sridhar, Int. J. Mater. Res. 93 (2002) 12–20.
H. Shibata, H. Yin, S. Yoshinaga, T. Emi, M. Suzuki, ISIJ Int. 38 (1998) 149–156.
E. Zinngrebe, C. Van Hoek, H. Visser, A. Westendorp, I.H. Jung, ISIJ Int. 52 (2012) 52–61.
S. Taniguchi, A. Kikuchi, Tetsu-to-Hagane 78 (1992) 527–535.
U. Lindborg, Trans. Metall. Soc. AIME 242 (1968) 94.
P.G. Saffman, J.S. Turner, J. Fluid Mech. 1 (1956) 16.
H. Ling, L. Zhang, H. Li, Metall. Mater. Trans. B 47 (2016) 2991–3012.
S. Taniguchi, A. Kikuchi, T. Ise, N. Shoji, ISIJ Int. 36 (1996) S117–S120.
L. Zhang, Q. Zhou, W. Chen, Y. Wang, L. Zhang, Foundry Technol. 43 (2022) 1051–1057.
Acknowledgements
The authors are grateful for the support from National Key R&D Program (No. 2023YFB3709900), the National Natural Science Foundation of China (Grant Nos. U22A20171 and 52104343), the Natural Science Foundation of Hebei Province (Grant No. E2021203222) and the High Steel Center (HSC) at Yanshan University and North China University of Technology, China.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare no conflict of interest.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zhou, Qy., Ba, Jt., Zhang, L. et al. Aggregation of CeAlO3 inclusions in heavy ingot of a steel containing 0.007% aluminum. J. Iron Steel Res. Int. (2024). https://doi.org/10.1007/s42243-023-01154-6
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s42243-023-01154-6