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One-pot synthesis of acrylate resin and ZnO nanowires composite for enhancing oil absorption capacity and oil-water separation

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Abstract

Inspired by the fast separation of oils, we synthesized a multi-functional oil-absorbable material, ZnO nanowires/acrylic ester composite resin, via a facile and cost-effective suspension polymerization method. Especially, the ZnO nanowires were fabricated by hydrothermal method and the surface of superhydrophobic and superoleophilic ZnO nanowires was modified by A151. Various technologies such as FT-IR, XRD, SEM, and DSC-TG have been used to investigate the properties of the as-synthesized materials. The corresponding oil absorption results showed that the composite resins could effectively separate organics from wastewater. Moreover, the composite resins were proved to have an excellent reusability after 10 cycles and the antibacterial activity of the synthesized composite resins mixed with ZnO nanowires were confirmed against E. coli and S. aureus, which could play an important role in water purification. Herein, the as-synthesized multi-functional oil-absorbable resins possess a far-reaching application prospect in the field of environmental treatment.

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References

  1. Li J-J, Zhu L-T, Luo Z-H (2016) Electrospun fibrous membrane with enhanced swithchable oil/water wettability for oily water separation. Chem Eng J 287:474–481

    Article  CAS  Google Scholar 

  2. Lü X, Cui Z, Wei W, Xie J, Jiang L, Huang J, Liu J (2016) Constructing polyurethane sponge modified with silica/graphene oxide nanohybrids as a ternary sorbent. Chem Eng J 284:478–486

    Article  Google Scholar 

  3. Nikkhah AA, Zilouei H, Asadinezhad A, Keshavarz A (2015) Removal of oil from water using polyurethane foam modified with nanoclay. Chem Eng J 262:278–285

    Article  CAS  Google Scholar 

  4. Zang D, Liu F, Zhang M, Niu X, Gao Z, Wang C (2015) Superhydrophobic coating on fiberglass cloth for selective removal of oil from water. Chem Eng J 262:210–216

    Article  CAS  Google Scholar 

  5. Zhou C, Cheng J, Hou K, Zhao A, Pi P, Wen X, Xu S (2016) Superhydrophilic and underwater superoleophobic titania nanowires surface for oil repellency and oil/water separation. Chem Eng J 301:249–256

    Article  CAS  Google Scholar 

  6. Lee JH, Kim DH, Han SW, Kim BR, Park EJ, Jeong M-G, Kim JH, Kim YD (2016) Fabrication of superhydrophobic fibre and its application to selective oil spill removal. Chem Eng J 289:1–6

    Article  CAS  Google Scholar 

  7. Page CA, Bonner JS, McDonald TJ, Autenrieth RL (2002) Behavior of a chemically dispersed oil in a wetland environment. Water Res 36:3821–3833

    Article  CAS  Google Scholar 

  8. Broje V, Keller AA (2006) Improved mechanical oil spill recovery using an optimized geometry for the skimmer surface. Environ Sci Technol 40:7914–7918

    Article  CAS  Google Scholar 

  9. Feng J, Nguyen ST, Fan Z, Duong HM (2015) Advanced fabrication and oil absorption properties of super-hydrophobic recycled cellulose aerogels. Chem Eng J 270:168–175

    Article  CAS  Google Scholar 

  10. Zhang WY, Qiu-Rong LI, Xie YN, Pei YR (2011) Synthesis of high oil-absorption resins modified by organic bentonite with microwave irradiation. Finn Chem 28:24–28

    Google Scholar 

  11. Syed S, Alhazzaa MI, Asif M (2011) Treatment of oily water using hydrophobic nano-silica. Chem Eng J 167:99–103

    Article  CAS  Google Scholar 

  12. Ibrahim S, Haming A, Wang SB (2009) Removal of emulsified food and mineral oils from wastewater using surfactant modified barley straw. Bioresour Technol 100:5744–5749

    Article  CAS  Google Scholar 

  13. Atanub B, Sajilata MG, Sudhar T, Rekhas S (2008) Regeneration of thermally polymerized frying oils with adsorbents. Food Chem 110:562–570

    Article  Google Scholar 

  14. Ahmad AL, Sumathi S, Hameed BH (2005) Residual oil and suspended solid removal using natural adsorbents chitosan, bentonite and activated carbon: a comparative study. Chem Eng J 108:179–185

    Article  CAS  Google Scholar 

  15. Mysore D, Viraraghavan T, Jin YC (2005) Treatment of oily waters using vermiculite. Water Res 39:2643–2653

    Article  CAS  Google Scholar 

  16. Arbatan T, Fang X, Shen W (2011) Superhydrophobic and oleophilic calcium carbonate powder as a selective oil sorbent with potential use in oil spill clean-ups. Chem Eng J 166:787–791

    Article  CAS  Google Scholar 

  17. Cho E-C, Hsiao Y-S, Lee K-C, Huang J-H (2015) Few-layer graphene based sponge as a highly efficient, recyclable and selective sorbent for organic solvents and oils. RSC Adv 5:53741–53748

    Article  CAS  Google Scholar 

  18. Ge X, Yang W, Wang J, Long D, Ling L, Qiao W (2015) Flexible carbon nanofiber sponges for highly efficient and recyclable oil absorption. RSC Adv 5:70025–70031

    Article  CAS  Google Scholar 

  19. Gupta S, Tai N-H (2016) Carbon materials as oil sorbents: a review on the synthesis and performance. J Mater Chem A 4:1550–1565

    Article  CAS  Google Scholar 

  20. Wang Y, Liu X, Lian M, Zheng G, Dai K, Liu C, Shen C (2017) Continuous fabrication of polymer microfiber bundles with interconnected microchannels for oil/water separation. Appl Mater Today 9:77–81

    Article  Google Scholar 

  21. Ying Y, Ying W, Li Q, Meng D, Ren G, Yan R, Peng X (2017) Recent advances of nanomaterial-based membrane for water purification. Appl Mater Today 7:144–158

    Article  Google Scholar 

  22. Pawar M, Kadam A, Yemul O, Thamke V, Kodam K (2016) Biodegradable bioepoxy resins based on epoxidized natural oil (cottonseed & algae) cured with citric and tartaric acids through solution polymerization: a renewable approach. Ind Crop Prod 89:434–447

    Article  CAS  Google Scholar 

  23. Zheng Y, Cao E, Zhu Y, Wang A, Hu H (2016) Perfluorosilane treated Calotropis gigantea fiber: instant hydrophobic–oleophilic surface with efficient oil-absorbing performance. Chem Eng J 295:477–483

    Article  CAS  Google Scholar 

  24. Qu JY, Han Q, Gao F, Qiu JS (2017) Carbon foams produced from lignin-phenol-formaldehyde resin for oil/water separation. New Carbon Materials 32:86–91

    Article  Google Scholar 

  25. Zhang C, Yang D, Zhang T, Qiu F, Dai Y, Xu J, Jing Z (2017) Synthesis of MnO2/poly(n-butylacrylate-co-butyl methacrylate-co-methyl methacrylate) hybrid resins for efficient oils and organic solvents absorption. J Clean Prod 148:398–406

    Article  CAS  Google Scholar 

  26. Chu Y, Fan C, Zhang Q, Zan C, Ma D, Jiang H, Wang Y, Wei F (2014) The oxidation of heavy oil to enhance oil recovery: the numerical model and the criteria to describe the low and high temperature oxidation. Chem Eng J 248:422–429

    Article  CAS  Google Scholar 

  27. Rong J, Qiu F, Zhang T, Zhang X, Zhu Y, Xu J, Yang D, Dai Y (2017) A facile strategy toward 3D hydrophobic composite resin network decorated with biological ellipsoidal structure rapeseed flower carbon for enhanced oils and organic solvents selective absorption. Chem Eng J 322:397–407

    Article  CAS  Google Scholar 

  28. Yue X, Zhang T, Yang D, Qiu F, Rong J, Xu J, Fang J (2017) The synthesis of hierarchical porous Al2O3/acrylic resin composites as durable, efficient and recyclable absorbents for oil/water separation. Chem Eng J 309:522–531

    Article  CAS  Google Scholar 

  29. Wang Y, Li Q, Bo L, Wang X, Zhang T, Li S, Ren P, Wei G (2016) Synthesis and oil absorption of biomorphic MgAl layered double oxide/acrylic ester resin by suspension polymerization. Chem Eng J 284:989–994

    Article  CAS  Google Scholar 

  30. Yan L, Li Q, Wang X, Song H, Chi H, Qiao Y, Zhai Y, Liu D (2017) Synthesis and absorption performance of acrylic ester and hollow fiber MgO nanoparticles resin composite. Polym-Plast Technol Eng 56:1–9

    Article  Google Scholar 

  31. Amanullah M, Javed Q-u-A, Rizwan S (2016) Surfactant-assisted carbon doping in ZnO nanowires using poly ethylene glycol (PEG). Mater Chem Phys 180:128–134

    Article  CAS  Google Scholar 

  32. Marimuthu T, Anandhan N, Thangamuthu R, Mummoorthi M, Ravi G (2016) Synthesis of ZnO nanowire arrays on ZnO TiO2 mixed oxide seed layer for dye sensitized solar cell applications. J Alloys Compd 677:211–218

    Article  CAS  Google Scholar 

  33. Marimuthu T, Anandhan N, Thangamuthu R, Surya S (2017) Facile growth of ZnO nanowire arrays and nanoneedle arrays with flower structure on ZnO-TiO2 seed layer for DSSC applications. J Alloys Compd 693:1011–1019

    Article  CAS  Google Scholar 

  34. Butanovs E, Kuzmin A, Butikova J, Vlassov S, Polyakov B (2017) Synthesis and characterization of ZnO/ZnS/MoS2 core-shell nanowires. J Cryst Growth 459:100–104

    Article  CAS  Google Scholar 

  35. Wiese H (2010) A. W. Adamson: “Physical Chemistry of Surfaces”, 5. Auflage, John Wiley & Sons Inc., New York, Chichester, Brisbane, Toronto, Singapore 1990. 777 Seiten, Preis: £ 47.50. Zeitschrift Fã¼r Elektrochemie Berichte Der Bunsengesellschaft Fã¼r Physikalische Chemie 95:-

  36. Wang Y, Zhang D, Lv D, Sun Y (2015) Mg–Al mixed metal oxide film derived from layered double hydroxide precursor film: fabrication and antibacterial properties. J Taiwan Inst Chem Eng 57:160–166

    Article  CAS  Google Scholar 

  37. Bakhsheshi-Rad HR, Hamzah E, Low HT, Kasiri-Asgarani M, Farahany S, Akbari E, Cho MH (2017) Fabrication of biodegradable Zn-Al-Mg alloy: mechanical properties, corrosion behavior, cytotoxicity and antibacterial activities. Mater Sci Eng C 73:215–219

    Article  CAS  Google Scholar 

  38. Dhanalakshmi A, Palanimurugan A, Natarajan B (2017) Enhanced antibacterial effect using carbohydrates biotemplate of ZnO nano thin films. Carbohydr Polym 168:191–200

    Article  CAS  Google Scholar 

  39. Ryu S-J, Jung H, Oh J-M, Lee J-K, Choy J-H (2010) Layered double hydroxide as novel antibacterial drug delivery system. J Phys Chem Solids 71:685–688

    Article  CAS  Google Scholar 

  40. Rasouli N, Movahedi M, Doudi M (2017) Synthesis and characterization of inorganic mixed metal oxide nanoparticles derived from Zn–Al layered double hydroxide and their antibacterial activity. Surf Interfaces 6:110–115

    Article  CAS  Google Scholar 

  41. Kiro A, Bajpai J, Bajpai AK (2017) Designing of silk and ZnO based antibacterial and noncytotoxic bionanocomposite films and study of their mechanical and UV absorption behavior. J Mech Behav Biomed Mater 65:281–294

    Article  CAS  Google Scholar 

  42. Saravanan M, Gopinath V, Chaurasia MK, Syed A, Ameen F, Purushothaman N (2018) Green synthesis of anisotropic zinc oxide nanoparticles with antibacterial and cytofriendly properties. Microb Pathog 115:57–63

    Article  CAS  Google Scholar 

  43. Joe A, Park S-H, Shim K-D, Kim D-J, Jhee K-H, Lee H-W, Heo C-H, Kim H-M, Jang E-S (2017) Antibacterial mechanism of ZnO nanoparticles under dark conditions. J Ind Eng Chem 45:430–439

    Article  CAS  Google Scholar 

  44. Raghupathi KR, Koodali RT, Manna AC (2011) Size-dependent bacterial growth inhibition and mechanism of antibacterial activity of zinc oxide nanoparticles. Langmuir 27:4020

    Article  CAS  Google Scholar 

  45. Bondarenko O, Juganson K, Ivask A, Kasemets K, Mortimer M, Kahru A (2013) Toxicity of Ag, CuO and ZnO nanoparticles to selected environmentally relevant test organisms and mammalian cells in vitro: a critical review. Arch Toxicol 87:1181

    Article  CAS  Google Scholar 

  46. Alswat AA, Ahmad MB, Saleh TA, Hussein MZ, Ibrahim NA (2016) Effect of zinc oxide amounts on the properties and antibacterial activities of zeolite/zinc oxide nanocomposite. Mater Sci Eng C 68:505–511

    Article  CAS  Google Scholar 

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Funding

This work was financially supported by the National Nature Science Foundation of China (21706100 and U1507115); Natural Science Foundation of Jiangsu Province (BK20160500, BK20161362, and BK20160491); the Natural Science Foundation of Hebei Province (B2018203393); “Qinhuangdao Science and Technology Research and Development Plan,” China, No. 201701B044; and Hebei Province key research and development projects, No.17272402D.

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Correspondence to Qiurong Li or Tao Zhang.

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Yan, L., Li, Q., Chi, H. et al. One-pot synthesis of acrylate resin and ZnO nanowires composite for enhancing oil absorption capacity and oil-water separation. Adv Compos Hybrid Mater 1, 567–576 (2018). https://doi.org/10.1007/s42114-018-0043-4

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