Skip to main content
Log in

Innovative continuous polypropylene fiber composite filament for material extrusion

  • Full Research Article
  • Published:
Progress in Additive Manufacturing Aims and scope Submit manuscript

Abstract

Material extrusion is a common additive manufacturing technique used in various fields, including engineering and medicine. Continuous development of innovative feedstock materials for the material-extrusion process is indispensable to broaden the use of this additive manufacturing technique. This work is focused on the development and characterization of a continuous fiber-reinforced thermoplastic composite filament for the material-extrusion process. Continuous polypropylene (PP) fiber is used to reinforce poly(ε-caprolactone) (PCL), a tissue-scaffolding material commonly used in the medical field. Filaments with different fiber contents are produced through a hot melt impregnation process. Thermal analysis is conducted to evaluate the thermal properties of the filament. The mechanical properties of the filaments are evaluated through tensile testing, and the effect of the fiber content on tensile strength and Young’s modulus is determined. It was found that the strength and modulus of PCL increased significantly with continuous PP fibers added. The addition of 9 vol% PP fibers can improve the tensile strength of PCL by more than 600% and its tensile modulus by more than 200%. The printability of the continuous PP fiber-reinforced PCL composite filament was also demonstrated. This study demonstrates the effectiveness of improving the mechanical property of PCL by adding fibers, which offers a promising avenue for the advancement of biocompatible material-extrusion printing materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. Parandoush P, Lin D (2017) A review on additive manufacturing of polymer-fiber composites. Compos Struct 182:36–53. https://doi.org/10.1016/j.compstruct.2017.08.088

    Article  Google Scholar 

  2. Huang B et al (2019) Study of processing parameters in fused deposition modeling based on mechanical properties of acrylonitrile-butadiene-styrene filament. Polym Eng Sci 59(1):120–128. https://doi.org/10.1002/pen.24875

    Article  Google Scholar 

  3. Li Y, Shimizu H (2009) Improvement in toughness of poly(l-lactide) (PLLA) through reactive blending with acrylonitrile–butadiene–styrene copolymer (ABS): morphology and properties. Eur Polymer J 45(3):738–746. https://doi.org/10.1016/j.eurpolymj.2008.12.010

    Article  Google Scholar 

  4. Kuznetsov VE et al (2018) Strength of PLA components fabricated with fused deposition technology using a desktop 3D printer as a function of geometrical parameters of the process. Polymers 10(3):313. https://doi.org/10.3390/polym10030313

    Article  MathSciNet  Google Scholar 

  5. Das A et al (2023) Melt-based additive manufacturing of polyolefins using material extrusion and powder bed fusion. Polym Rev 63(4):895–960. https://doi.org/10.1080/15583724.2023.2220024

    Article  Google Scholar 

  6. Rocha DP et al (2023) Sensing materials: electrochemical sensors enabled by 3D printing. In: Narayan R (ed) Encyclopedia of sensors and biosensors, 1st edn. Elsevier, Oxford, pp 73–88

    Chapter  Google Scholar 

  7. Lay M et al (2019) Comparison of physical and mechanical properties of PLA, ABS and nylon 6 fabricated using fused deposition modeling and injection molding. Compos B Eng 176:107341. https://doi.org/10.1016/j.compositesb.2019.107341

    Article  Google Scholar 

  8. Celestine A-DN, Agrawal V, Runnels B (2020) Experimental and numerical investigation into mechanical degradation of polymers. Compos B Eng 201:108369. https://doi.org/10.1016/j.compositesb.2020.108369

    Article  Google Scholar 

  9. Wu W et al (2015) Influence of layer thickness and raster angle on the mechanical properties of 3D-printed PEEK and a comparative mechanical study between PEEK and ABS. Materials 8:5834–5846. https://doi.org/10.3390/ma8095271

    Article  Google Scholar 

  10. Winarso R et al (2022) Application of fused deposition modeling (FDM) on bone scaffold manufacturing process: a review. Heliyon 8(11):e11701. https://doi.org/10.1016/j.heliyon.2022.e11701

    Article  Google Scholar 

  11. Deshmukh K et al (2017) 3 - Biopolymer composites with high dielectric performance: interface engineering. In: Sadasivuni KK et al (eds) Biopolymer composites in electronics. Elsevier, pp 27–128

    Chapter  Google Scholar 

  12. Jiao Z et al (2019) 3D printing of HA / PCL composite tissue engineering scaffolds. Adv Ind Eng Polym Res 2(4):196–202. https://doi.org/10.1016/j.aiepr.2019.09.003

    Article  Google Scholar 

  13. Shofner ML et al (2003) Nanofiber-reinforced polymers prepared by fused deposition modeling. J Appl Polym Sci 89(11):3081–3090. https://doi.org/10.1002/app.12496

    Article  Google Scholar 

  14. Ning F et al (2015) Additive manufacturing of carbon fiber reinforced thermoplastic composites using fused deposition modeling. Compos B Eng 80:369–378. https://doi.org/10.1016/j.compositesb.2015.06.013

    Article  Google Scholar 

  15. Zhong W et al (2001) Short fiber reinforced composites for fused deposition modeling. Mater Sci Eng, A 301(2):125–130. https://doi.org/10.1016/S0921-5093(00)01810-4

    Article  Google Scholar 

  16. Tian X et al (2022) 3D printing of continuous fiber reinforced polymer composites: development, application, and prospective. Chin J Mech Eng Addit Manuf Front 1(1):100016. https://doi.org/10.1016/j.cjmeam.2022.100016

    Article  Google Scholar 

  17. Heidari-Rarani M, Rafiee-Afarani M, Zahedi AM (2019) Mechanical characterization of FDM 3D printing of continuous carbon fiber reinforced PLA composites. Compos B Eng 175:107147. https://doi.org/10.1016/j.compositesb.2019.107147

    Article  Google Scholar 

  18. Klift FVD et al (2016) 3D Printing of continuous carbon fibre reinforced thermo-plastic (CFRTP) tensile test specimens. Open J Compos Mater. https://doi.org/10.4236/ojcm.2016.61003

    Article  Google Scholar 

  19. Li N, Li Y, Liu S (2016) Rapid prototyping of continuous carbon fiber reinforced polylactic acid composites by 3D printing. J Mater Process Technol 238:218–225. https://doi.org/10.1016/j.jmatprotec.2016.07.025

    Article  Google Scholar 

  20. Melenka GW et al (2016) Evaluation and prediction of the tensile properties of continuous fiber-reinforced 3D printed structures. Compos Struct 153:866–875. https://doi.org/10.1016/j.compstruct.2016.07.018

    Article  Google Scholar 

  21. Matsuzaki R et al (2016) Three-dimensional printing of continuous-fiber composites by in-nozzle impregnation. Sci Rep 6(1):23058. https://doi.org/10.1038/srep23058

    Article  Google Scholar 

  22. Maddah H (2016) Polypropylene as a promising plastic: a review. Am J Polym Sci 6:2163-1352. https://doi.org/10.5923/j.ajps.20160601.01

    Article  Google Scholar 

  23. Schmidt A, Taylor D (2021) Erosion of soft tissue by polypropylene mesh products. J Mech Behav Biomed Mater 115:104281. https://doi.org/10.1016/j.jmbbm.2020.104281

    Article  Google Scholar 

  24. Kraft CT, Molina BJ, Skoracki RJ (2020) Polypropylene mesh complications in the sublay position after abdominally based breast reconstruction: les complications des treillis de polypropylène en sous-couche après une reconstruction mammaire par voie abdominale. Plast Surg 29(1):16–20. https://doi.org/10.1177/2292550320936683

    Article  Google Scholar 

  25. Arcana IM et al (2007) Study on properties of polymer blends from polypropylene with polycaprolactone and their biodegradability. Polym J 39(12):1337–1344. https://doi.org/10.1295/polymj.PJ2006250

    Article  Google Scholar 

  26. INNEGRA. Corporate Presentation (2021). Available from: https://static1.squarespace.com/static/5dfd2483cf94db2cc7127d0f/t/5e1a822ce07fd33951ddc73d/1578795572287/Corporate+Presentation.pdf. Accessed 27 Apr 2023

  27. Stewart R (2010) Automotive composites offer lighter solutions. Reinf Plast 54(2):22–28. https://doi.org/10.1016/S0034-3617(10)70061-8

    Article  Google Scholar 

  28. Bhudolia SK et al (2021) Enhanced impact energy absorption and failure characteristics of novel fully thermoplastic and hybrid composite bicycle helmet shells. Mater Des 209:110003. https://doi.org/10.1016/j.matdes.2021.110003

    Article  Google Scholar 

  29. Bhudolia SK et al (2022) On the Mode II fracture toughness, failure, and toughening mechanisms of wholly thermoplastic composites with ultra-lightweight thermoplastic fabrics and innovative Elium® resin. Compos A Appl Sci Manuf 161:107115. https://doi.org/10.1016/j.compositesa.2022.107115

    Article  Google Scholar 

  30. Hu Y et al (2021) Carbon fibre damage during 3D printing of polymer matrix laminates using the FDM process. Mater Des 205:109679. https://doi.org/10.1016/j.matdes.2021.109679

    Article  Google Scholar 

  31. Parker M et al (2022) 3D printing of continuous carbon fiber reinforced polyphenylene sulfide: exploring printability and importance of fiber volume fraction. Addit Manuf 54:102763. https://doi.org/10.1016/j.addma.2022.102763

    Article  Google Scholar 

  32. Reddy MM et al (2013) Biobased plastics and bionanocomposites: Current status and future opportunities. Prog Polym Sci 38(10):1653–1689. https://doi.org/10.1016/j.progpolymsci.2013.05.006

    Article  Google Scholar 

  33. Jung S-H et al (2010) Pyrolysis of a fraction of waste polypropylene and polyethylene for the recovery of BTX aromatics using a fluidized bed reactor. Fuel Process Technol 91(3):277–284. https://doi.org/10.1016/j.fuproc.2009.10.009

    Article  Google Scholar 

  34. Kim YC, Ahn W, Kim CY (1997) A study on multiple melting of isotactic polypropylene. Polym Eng Sci 37(6):1003–1011. https://doi.org/10.1002/pen.11745

    Article  Google Scholar 

  35. Tam T, Bhatnagar A (2016) 1 - High-performance ballistic fibers and tapes. In: Bhatnagar A (ed) Lightweight ballistic composites, 2nd edn. Woodhead Publishing, Cham, pp 1–39

    Google Scholar 

  36. Patrício T, Bártolo P (2013) Thermal stability of PCL/PLA blends produced by physical blending process. Procedia Eng 59:292–297. https://doi.org/10.1016/j.proeng.2013.05.124

    Article  Google Scholar 

  37. Chan C-M et al (2002) Polypropylene/calcium carbonate nanocomposites. Polymer 43(10):2981–2992. https://doi.org/10.1016/S0032-3861(02)00120-9

    Article  Google Scholar 

  38. Lanyi FJ et al (2020) On the determination of the enthalpy of fusion of α-crystalline isotactic polypropylene using differential scanning calorimetry, X-ray diffraction, and fourier-transform infrared spectroscopy: an old story revisited. Adv Eng Mater 22(9):1900796. https://doi.org/10.1002/adem.201900796

    Article  Google Scholar 

  39. Wang W et al (2015) The effect of high temperature annealing process on crystallization process of polypropylene, mechanical properties, and surface quality of plastic parts. J Appl Polym Sci. https://doi.org/10.1002/app.42773

    Article  Google Scholar 

  40. Frontini PM, Fave A (1995) The effect of annealing temperature on the fracture performance of isotactic polypropylene. J Mater Sci 30(9):2446–2454. https://doi.org/10.1007/BF01184599

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Haibin Ning.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yan, Y., Pillay, S. & Ning, H. Innovative continuous polypropylene fiber composite filament for material extrusion. Prog Addit Manuf (2024). https://doi.org/10.1007/s40964-024-00605-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40964-024-00605-0

Keywords

Navigation