1 Introduction

In recent decades, as the level of mining mechanization has continuously increased, coal dust concentration in underground mines has similarly grown, and the associated exposure time of high concentrations of coal dust to workers has increased (Xu et al. 2018; Shi et al. 2019). The increasing cases of pneumoconiosis (CWP) and coal dust explosion accidents in recent years have forced enterprises and governments worldwide to focus their attention on coal dust suppression (Hall et al. 2019). For instance, the permissible exposure limit (PEL) of respiratory coal dust in the US was reduced from 2.0 to 1.5 mg/m3 in 2016 (Xu et al. 2018). In China, the Air Pollutant Discharge Standard (GB16297—1996) was revised by China’s Ministry of Environmental Protection in 2017, and the requirements for fugitive emission control measures in mining processes were enhanced (Zhou G et al. 2018; Zhou L et al. 2018; Zhou Q et al. 2018).

There has been considerable research to efficiently control coal dust in underground mines by studying its generation mechanism, diffusion process, and suppressant technologies. To date, the most common approach to control coal dust is hydraulic methods, such as water spray, coal seam water injection, and chemical dust suppression. In these cases, wetting fluids (mainly water or water solutions) are used to wet the coal dust particles, increase their mass, and facilitate their settling (Kollipara et al. 2014; Zhou et al. 2020; Jin et al. 2019; Liu et al. 2019a). Therefore, the wetting ability of fluids on coal dust is significant to achieve high dust suppressant efficiencies.

It is widely accepted that studying the influence of the physicochemical properties of dust on its wettability is important (Xu et al. 2017; Wang et al. 2017, 2019; Liu et al. 2019b). In addition, decreasing the surface tension of wetting fluids is another effective approach to improve the wettability of coal dust (Xu et al. 2018; Shi et al. 2019; Meng et al. 2019). Consequently, numerous studies have focused on developing chemical dust suppressants. Adding surfactants is the most common method to reduce the surface tension of water, and the effects of the concentration and species (including cationic, anionic, and non-ionic) of surfactants on the solution surface tension have been intensely investigated (Meng et al. 2019; Shi et al. 2019; Xi et al. 2019). In addition, the synergistic effects of different surfactant species (Xi et al. 2017; Bao et al. 2020; Zhou et al. 2020), the compatibility of surfactants with various kinds of chlorine salts (e.g., NaCl, CaCl2) (Jin et al. 1999; Ni et al. 2019), and surfactant-magnetized water (Zhou G et al. 2018; Zhou L et al. 2018; Zhou Q et al. 2018) have been investigated. Nevertheless, few chemical dust inhibitors have been widely applied in the field due to their low dust suppression efficiency, high cost, and other factors (Xu et al. 2018). Therefore, developing a chemical coal dust suppressant that has good dust inhibition efficiency and is convenient for field applications is required to control coal dust in underground mines.

In this study, a novel composite chemical suppressant, called NCZ, was prepared using calcium chloride (CaCl2), magnesium chloride (MgCl2), and nonionic surfactants using a thermal synthesis method for the hydrophobicity of coal dust. The water-staining properties of NCZ powder and its solutions were then characterized using water absorption and anti-evaporation tests, respectively. Next, the wettability of the NCZ solutions with different concentrations on coal dust were evaluated by measuring the sink rate (SR) and initial contact angles (ICA) on a coal dust platelet. Finally, the effects of the solution surface tension on the wettability of coal dust were discussed, and their quantitative relationship was fit using the least squares method.

2 Materials and experiments

2.1 Coal dust sample

The experimental coal dust was collected using a hang plate from a return airway in Yongcheng coalfield in Henan Province and sieved with a 200 mesh (≤ 74 μm) in a laboratory. The proximate and ultimate analyses of the coal dust were conducted following the GB/T 212—2008 and GB/T 31391—2015 standards, respectively. The results are listed in Table 1. The dynamic contact angles between the coal dust and deionized water were measured at 7.5 Hz for 10 s using a Theta Lite TL101 apparatus (Finland). As shown in Fig. 1, the contact angles at 0 and 10 s were 141.9° and 109.6°, respectively. Therefore, the coal dust is almost considered a super-hydrophobic material (contact angle > 150°) (Notsu et al. 2005).

Table 1 Proximate and ultimate analyses of the experimental coal dust
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Fig. 1
figure 1

Dynamic contact angles of the experimental coal dust on deionized water within 10 s

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2.2 Preparation of NCZ dust suppressant

A thermal synthesis method was utilized to prepare the NCZ dust suppressant to ensure all the components were fully mixed. As shown in Fig. 2, 100 g of a CaCl2 and MgCl2 mixture (4:1 mass ratio; both materials have a relatively large water-absorbing capacity (Jin et al. 1999; Ni et al. 2019) and can prevent settled dust from flying again) was dissolved in water. The solution was heated, and when the temperature reached 120–140 °C, 5 g of a non-ionic surfactant mixture, i.e., primary alcohol ethoxylate (JFC) and Triton X-100 at a 1:1 mass ratio, was added to the solution. The solution was then poured into a stainless-steel mold, which was cooled in a water bath to room temperature before being unloaded. The NCZ infiltration sticks were obtained, which were placed directly into water injection holes on a coal seam to enhance the wettability of the coal body.

Fig. 2
figure 2

Preparation process of the NCZ infiltration sticks

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Finally, the NCZ infiltration sticks were pulverized to form a mesh powder (≤ 1.70 mm) to test its enhancement effect on the wettability of coal dust. The NCZ infiltration sticks before (a) and after (b) pulverizing are shown in Fig. 3.

Fig. 3
figure 3

Photographs of NCZ infiltration sticks before (a) and after (b) pulverizing

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2.3 Surface tension test

The pendant drop method (Berry et al. 2015) was used to measure the dynamic surface tension of clean water and the NCZ solutions at 7.5 Hz over 30 s using a Theta Lite TL101 apparatus (Fig. 4). The average values were used for further calculations.

Fig. 4
figure 4

Photographs of the Theta Lite TL101 apparatus

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2.4 Water-retaining test

The water-retaining ability of the dust suppressant significantly affects its dust suppression efficiency because it can decrease the probability of settled dust flying again through absorption and anti-evaporating water (Zhang et al. 2018).

2.4.1 Water-absorption test

Approximately 1 g of the NCZ powder (Fig. 3b) was placed in a culture dish (φ = 58 mm) and kept in a laboratory environment at 17 ± 1 °C and (25 ± 5)% humidity for 26 h. Next, the powder mass was examined every ~ 2 h using an analytical balance (sensitivity of 0.0001 g), and the water absorption rate (WAR) was calculated using Eq. (1).

$$WAR = \frac{{m_{t} - m_{0} }}{{m_{0} t}}$$
(1)

where, m0 and mt are the masses of the NCZ powder at time 0 (initial mass) and t, respectively.

2.4.2 Anti-evaporation test

Approximately 20 mL of NCZ solutions with concentrations of 0% (clean water), 0.1%, 0.5%, 1.0%, 5.0%, 10.0%, and 20.0% were poured into culture dishes (φ = 80 mm) and placed in a laboratory environment (the same conditions used for the water-absorption test) for 24 h. Their masses were measured and recorded every 2 h, and the evaporation rate (ER) was calculated using Eq. (2).

$$ER = \frac{{m_{0} - m_{t} }}{t}.$$
(2)

The averages were considered for further calculations.

2.5 Wettability test

  1. (1)

    Contact angle test

    The dynamic contact angles between the coal dust and NCZ solutions at various concentrations were measured per the discussion in Sect. 2.1, and the ICA value was selected for further analysis (Li et al. 2013).

  2. (2)

    Sink test

    Compared with other laboratory static tests, the sink test is the most reliable method to quantify the wettability of coal dust (Chen et al. 2019). In this study, 0.1–0.5 g of experimental coal dust was placed on the surface of the NCZ solutions, and the time (sink time) taken for all coal dust to disappear from the surface was recorded (Shi et al. 2019; Chen et al. 2019). The sink rate (SR) is calculated using Eq. (3):

    $$SR = \frac{m}{t}$$
    (3)

    where, m is the mass of coal dust. The sink tests were repeated three times, and the average value was taken.

3 Results and discussion

3.1 Changes in surface tension of NCZ solutions

The variability of the surface tension for the NCZ solutions (0.0 wt%, 0.1 wt%, 0.5 wt%, 1.0 wt%, 5.0 wt%, 10.0 wt%, and 20.0 wt%) is shown in Fig. 5. It is noted that the solution surface tension reduced sharply from 73.02 to 32.95 mN/m with the addition of 0.5 wt% NCZ. With further increases in the NCZ concentration, the solution surface tension reduced more slowly and reduced only by 3.53 mN/m as the NCZ concentration increased from 0.5 wt% to 20.0 wt%. The critical micelle concentration (CMC) (Xu et al. 2018) of the NCZ solution is thus 0.5 wt%. The surfactant molecules form a unimolecular layer at the CMC on the solution surface, which results in a reduced surface tension. Multiple layers of surfactant molecules are then formed on the surface when the concentration is > CMC, but this has little effect on the solution surface tension (Xu et al. 2018). Therefore, the surface tension of the NCZ solution is reduced sharply at concentrations less than 0.5 wt%, and when the NCZ concentration is greater than 0.5 wt%, the solution surface tension is reduced at a relatively slow rate.

Fig. 5
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Curve of the surface tension for the NCZ solution at different concentrations

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3.2 Water-retaining property of NCZ powder and solutions

3.2.1 Water absorption process of NCZ powder

Changes in the NCZ powder mass and its WAR with time are shown in Fig. 6, where three distinct stages are observed. In stage 1, the physical adsorption of water dominated from 0–130 min as the NCZ powder is much drier than air, and the WAR decreased linearly from 1.98 to 1.29 mg/g h. The WAR then began to fluctuate steadily between 1.3 and 1.4 mg/g h from 130–400 min (stage 2). Here, the chemical absorption dominates, which is attributed to the hygroscopic properties of CaCl2 and MgCl2. In stage 3 (> 400 min), the mass of the NCZ powder increased slowly, and the water adsorption process stopped when the equilibrium point was reached. That is, the WAR of the NCZ powder was equal to the ER of water. At the equilibrium point, the mass of the NCZ powder does not change, and the WAR becomes 0.

Fig. 6
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Variations in the mass and WAR of NCZ powder with time

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3.2.2 Evaporation properties of NCZ solutions

The evaporation rate of the dust suppressant solution is directly related to the possibility of the settled dust flying again. Therefore, investigating the evaporation properties of the NCZ solution is important to understand its dust suppressed performance. It is widely accepted that the ER of a solution increases as its surface tension decreases because the intermolecular forces inside the solution are reduced. The dust suppressant efficiency is improved by adding surfactant into water, but this accelerates the evaporation of moisture in coal dust and lets the settled dust become airborne. To induce anti-evaporation of the dust inhibitor solutions, stronger water-absorbent salts, i.e., CaCl2 and MgCl2, were added into the NCZ suppressant. Figure 7 shows the ER curve of the NCZ solutions at differing concentrations. The ER rapidly decreased first before slowly decreasing with an increasing NCZ concentration with a transition point of 0.5 wt%. This is consistent with the trend of the surface tension (Fig. 5), which illustrates that the NCZ dust suppressant can not only effectively reduce the solution surface tension but can also enhance the anti-evaporation properties of the solutions. The ER of the 20 wt% NCZ solution decreased by 11.7% compared with that of clean water.

Fig. 7
figure 7

Evaporation rate of NCZ solutions at different concentrations

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3.3 Enhancement in wettability of coal dust by NCZ solutions

3.3.1 Contact angle

Figure 8 shows several images of contact angles at various times. As the ICA is an effective method to evaluate the wettability of coal dust (Li et al. 2013), it was selected to evaluate the wettability of NCZ.

Fig. 8
figure 8

Images of water solution drops on compressed coal dust pellets

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As shown in Fig. 9, the ICA decreased gradually for greater NCZ concentrations following a power function trend (R2 = 0.97). However, unlike changes in the surface tension, when the NCZ concentration was > 0.5 wt% (CMC), the ICA reduced significantly with concentration. That is, the ICA decreased by 54.0% when the NCZ concentration increased from 0.5 wt% to 10.0 wt%. The optimal wetting concentration was 20 wt% with a minimum contact angle of 29.3°. This indicates that increasing the NCZ concentration beyond 0.5 wt% can significantly enhance the wettability of coal dust although this has little effect on the solution surface tension. Thus, the solution at the CMC point is far from its strongest wetting performance on coal dust. This is significant when selecting the best concentration of dust suppressants. In addition, decreasing the surface tension of the solution can improve its wettability for coal dust, but their relationship is non-linear.

Fig. 9
figure 9

Initial contact angle of NCZ solutions on the coal dust surface

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3.3.2 Sink rate

The sink test is one of the most accurate laboratory tests to evaluate the wettability of coal dust (Chen et al. 2019). As shown in Fig. 10, the coal dust does not settle in clean water or a 0.1 wt% NCZ solution, but it begins to sink in NCZ solutions with concentrations above 0.5%. As seen, the settling rate gradually increased with the NCZ concentration. The sink rate was improved by 45.0% when the NCZ concentration varied from 10.0 wt% to 20.0 wt%, which differs greatly from the changes in the surface tension that only reduced by 1.0 mN/m over the same concentration range. This demonstrates that the solution surface tension changes a little after the CMC, but its wettability of coal dust does not reach its maximum there. Thus, the wettability of the solution for coal dust can still be improved considerably by increasing the NCZ concentration beyond its CMC.

Fig. 10
figure 10

Sink rate curve of coal dust in the NCZ solutions

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3.4 Effect of solution surface tension on the wettability of coal dust

Numerous studies have shown that the wettability of a suppressant solution to coal dust increases with a lower surface tension (Xu et al. 2018; Zhou G et al. 2018; Zhou L et al. 2018; Zhou Q et al. 2018; Shi et al. 2019; Xi et al. 2019). However, a quantitative analysis of this phenomenon has not yet been thoroughly conducted, which is significant to guide field applications of chemical dust suppressants and improve their efficiencies. The relationship between the solution surface tension and the wettability of coal dust (including SR and ICA) is fit using the least squares method based on the obtained test data. Figure 11a illustrates the relationship between the solution surface tension and the SR of coal dust. An exponential function is obtained with a goodness of fit (R2) of 0.827. This indicates that the SR of coal dust exponentially increases with decreases in the solution surface tension. The SR of coal dust increased by 5.79 times when the solution surface tension decreased from 32.95 to 29.42 mN/m.

As shown in Fig. 11b, a negative exponential function is established between the solution surface tension and the ICA of coal dust. Without considering cost, a smaller surface tension for the solution gives a better wetting performance on coal dust. This indicates that the wettability of solutions to coal dust is exponentially related (i.e., non-linear) with its surface tension. Therefore, this is the most effective method to improve the dust suppression efficiency through continual reductions in the solution surface tension.

Fig. 11
figure 11

Relationship between the solution surface tension and the SR (a) and ICA (b) of coal dust

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4 Conclusions

A novel composite dust suppressant NCZ was prepared that utilized CaCl2, MgCl2, and nonionic surfactants for hydrophobic coal dust. Its water-retaining properties and wettability of coal dust were comprehensively tested in a laboratory environment. The following conclusions are drawn:

  1. (1)

    The critical micelle concentration (CMC) and the corresponding surface tension of the NCZ solution were 0.5 wt% and 32.95 mN/m, respectively. The surface tension of the NCZ solution was reduced to 29.42 mN/m when its concentration increased to 20.0 wt%.

  2. (2)

    The water-absorbing process of the NCZ powder involved three stages: physical adsorption stage (0–130 min), chemical adsorption stage (130–400 min), and equilibrium adsorption and evaporation stage (> 400 min). Additionally, the ER of the 20.0 wt% NCZ solution was reduced by 11.7% relative to clean water.

  3. (3)

    The NCZ solution had a remarkable enhancement effect on the wettability of coal dust. The ICA and SR for clean water and the NCZ solution (20.0 wt%) were 141.9° and 0 mg/s, and 29.3° and 1.46 mg/s, respectively.

  4. (4)

    The solution surface tension was exponentially related to the SR and ICA. Thus, the wettability of coal dust can be rapidly improved by continually decreasing the solution surface tension when it is below 32 mN/m. Without considering costs, a smaller solution surface tension gives a better wetting performance on coal dust.

Finally, the limitations of this study are that the mechanism of the exponential relationship between the surface tension and SR and ICA has not been analyzed or developed theoretically or experimentally, which we intend to achieve in future work.