Abstract
This study reports the performance analysis of an organic dye-sensitized solar cell (DSSC), introducing MnO2 as an electron transport layer in TiO2/MnO2 bilayer assembly. The DSSCs have been fabricated using TiO2 and TiO2/MnO2 layer-by-layer architecture films onto fluorine-doped tin oxide (FTO) glass and sensitized with natural dye extracted from Malvaviscus penduliflorus flower in ethanol medium. The counter electrode was prepared to layer copper powder containing paste onto FTO's conductive side by the doctor's blade method. The optical, morphological, and structural properties of photoanodes were explored via ultraviolet–visible, field emission scanning electron microscopy, and X-ray diffraction analyses. Moreover, dye complexity and thermostability of dyes were characterized via Fourier-transform infrared spectroscopy and thermogravimetric analyses. The iodide/triiodide (i.e., I−/I3−) redox couple of electrolyte solution was employed as a charge transport medium between the electrodes. Finally, photoanode and counter electrode sandwiches were assembled to envisage the photovoltaic performance potential under simulated AM 1.5G solar illumination using 100 mW cm–2 light intensity. The as-fabricated DSSC comprising TiO2/MnO2 bilayer assembly exhibited 6.02 mA cm–2 short circuit current density (Jsc), 0.38 V open-circuit voltage (Voc), 40.38% fill factor, and 0.92% conversion efficiency, which is about 200% higher compared to the assembly devoid of MnO2 layer.
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Introduction
Nowadays, clean, near-zero-emission and sustainable renewable energy production are vital concerns for policymakers worldwide. The energy consumption demand is expected to be doubled in 2050 [1, 2]. Notably, a significant percentage of energy demand is backed by fossil fuel-based resources, implying an adverse impact on global warming, environment, and ecosystem. For circumventing the problems related to the limited amount of fossil fuel and adverse environmental concerns, present researchers are focused on renewable energy sources, i.e., solar energy, which is abundant and cost-effective.
Of variable third-generation solar cells, DSSC is low cost and easy to fabricate. The DSSC module works as a photoelectrochemical device in which electron–hole pair is generated via light-induced exciton [3]. The dye-anchored metal oxide semiconductor, i.e., TiO2, works as an electron transport layer, and electrolyte functions as a charge transport media and electron recombination suppression media between photoanode and cathode [4, 5].
The sensitizer mostly influences the performance potential of DSSC. The absorption of a wider range of light spectrum and a high molar absorption coefficient elevate the light-harvesting ability of TiO2 film. The natural color pigments of plant leaves, fruits, and flowers can be used as a sensitizer for DSSC application(s). Though DSSC has impressive performance under indoor lighting, the long-term stability and outdoor performance under high-temperature ambient conditions are yet to be achieved to date [6]. Moreover, the DSSC conversion efficiency is much lower than that of the commercially available silicon-based solar cells. The chlorophyll extract from various leaves has been used as a natural sensitizer in DSSC.
Moreover, in DSSC, red/purple pigment in various leaves/flowers has been used as a sensitizer [7]. Notably, an abundantly available organic dye is easily extracted from flowers and leaves, mainly responsible for light absorption in DSSC. It is expected that the dye should absorb ultraviolet–visible (UV–Vis) and near-infrared (NIR) regions of the light spectrum. The hydrophobic organic dye is selected for long-term stability. Hydrophobic dye reduces the possibility of direct contact among photoanode and liquid electrolyte, retarding water-induced dye degradation for the cell's long-term stability [8, 9]. The natural color pigments originated from organic dyes impart an anthocyanins group present in the different parts (e.g., flower, leaves) of the plant [10,11,12]. Red pigment-containing flower Hibiscus rosa-sinensis possessing a higher concentration of anthocyanins group is used for a natural dye-sensitized solar cell [13, 14]. In fact, Malvaviscus penduliflorus flower is closely related to the Hibiscus family. However, potential research based on M. penduliflorus flower -extracted dye in DSSC is still lacking. The broader absorption of Hibiscus-extracted dye within 400–500 nm can further be enhanced using either concentrated dye solution or operating the sensitization process at elevated temperature [15,16,17]. The absorption defect of the M. penduliflorus flower-extracted dye starts from 550 nm onward [18]. The performance of the DSSC can be compensated introducing a scattering layer or interfacial modification in the photoanode and concomitantly improves the broader spectrum wavelength range of light absorption to make it suitable for outdoor application(s) [19, 20]. The front side and back side illumination for photovoltaic devices originate from the cost-effective perspective, as the higher percentage of the incident solar spectrum can be harvested without altering the cell area. The light-harvesting property, along with the back side illumination, of the device can be enhanced by integrating porous scattering sensitized film, i.e., mesoporous TiO2, with a semi-transparent counter electrode. TiO2 has a wide bandgap of around 3.2 eV and is used widely in DSSC photoanode fabrication [21]. The tuning of optical and electrical properties and device performance enhancement is possible via suitable semiconductor material doping in the layered architecture [22, 23]. In this regard, semiconductor and bilayer assembly with MnO2/TiO2 can be employed for DSSC application(s).
Moreover, the bandgap of MnO2 around 2.57 eV makes it an ideal material for MnO2/TiO2 bilayer photoanode fabrication [24]. In DSSC fabrication, most of the research works use expensive platinum as a counter electrode, limiting the employability toward large-scale production. Thus, less expensive copper as a counter electrode is expected to facilitate the large-scale industrial application(s). This research's main objective is to elevate the output performance of cost-friendly DSSC by incorporating bilayer TiO2/MnO2 in the working electrode. Moreover, the present work aims to draw attractive attention toward cost effective DSSC fabrication. Accordingly, an attempt was made to extract the dye, i.e., sensitizer, from natural origin, i.e., Malvaviscus penduliflorus flower layer-by-layer architecture of TiO2/MnO2 toward the fabrication of photoelectrode for cost-friendly DSSC fabrication/ application.
Experimental details
Materials and chemicals
All the chemicals were purchased from commercial sources and used without purification. Natural dye was extracted from Malvaviscus penduliflorus flower using ethanol. Fluorine-doped tin oxide (FTO) glass substrate of 12–15 Ω sq–1 surface resistivity and 2.3 mm thickness purchased from Pilkington (India) was used as a conductive surface in the working and counter electrodes. Scotch tape (25 μm mm thick, Solaronix) was used in the doctor's blade method to control the film's thickness. TiO2 nanoparticle paste (Solaronix, 18 wt%) was used for thin film deposition on the working electrode. The polyvinyl alcohol dhesive was used as a binder for preparing MnO2 powder paste and copper powder paste. MnO2 powder (Fisher Scientific, India) was used for bilayer assembly preparation in photoanode. Copper powder (Loba Chemie, India) was used to prepare a counter electrode with copper paste. Potassium iodide and iodine were used to prepare the iodide/ triiodide electrolyte solution and acted as a charge transport media between the two electrodes. Paraffin spacer (50 μm thick, Merck, Germany) was used as a sealant and separation layer between the two electrodes during device assembling.
Cleaning of glass substrates
FTO glass substrates were appropriately cleaned with distilled water, followed by ethanol in an ultrasonic bath for 10 min before the material deposition.
Fabrication of working electrode
A scotch tape of 25 μm thickness was used to cover the cleaned FTO glass substrate's edges for making bottom contact. The thickness of TiO2 and TiO2/MnO2 bilayer photoanodes was controlled to approximately 25 μm and 50 μm, respectively. A transparent TiO2 nanoparticle paste was layered on the FTO glass substrate's conductive side by the doctor blade method. The as-prepared TiO2 film was dried in a hot air oven dryer at 70 °C for approximately 15 min before MnO2 layer deposition. After that, 0.1 g MnO2 powder was mixed with 1 g adhesive to prepare a uniformly dispersed MnO2 powder paste. MnO2 paste was similarly deposited onto the TiO2 layer, followed by drying at around 70 °C for 15 min. The layer-by-layer architecture deposition method was employed for TiO2/MnO2 bilayer assembly preparation. The thickness of the TiO2 and TiO2/MnO2 bilayer photoanodes was maintained at 25 μm and 50 μm, respectively. Finally, TiO2 and TiO2/MnO2 bilayer structure samples were annealed in a furnace at 450 °C for 45 min to improve the deposited surface morphology and crystallinity material. The samples were cooled down slowly to avoid any surface defects or cracks before dipping the samples in a natural dye solution. These samples were immersed in a dye solution for 36 h and kept in a dark place at room temperature. The electrode samples were gently washed with distilled water to remove any unadsorbed excess dye and dried in a hot oven air dryer at 40 °C for 5 min.
Fabrication of the counter electrode
Here, a cleaned FTO glass substrate was used for counter electrode fabrication. Scotch tape was used to cover the edges of the FTO glass, similar to working electrode preparation. 0.12 g copper powder was mixed with 1 g adhesive to prepare a uniformly dispersed copper powder paste. The as-prepared copper powder paste was deposited on the precleaned FTO glass's conductive side by the doctor blade method. Finally, the sample was placed in a furnace at around 200 °C for 1 h. Before removing the furnace sample, the copper-coated FTO counter electrode was cooled slowly to avoid any surface cracks on the thin film.
Preparation of natural dye solution
Herein, 5 g of fresh Malvaviscus penduliflorus flower (Fig. 1a) was washed with distilled water and cleaned flower petals were cut into small pieces. After that, the flower petals in 100 ml ethanol were poured in a mixer and ground for 3 min. The process was repeated thrice for preparing a thick solution. Furthermore, the solution was stirred continuously in a magnetic stirrer for 2 h to get a uniformly dispersed solution (Fig. 1b). The solution was kept in a cold and dark place for 36 h before filtration. Finally, the filtrate dye solution was collected and the residue was filtered out. The as-prepared dye solution, i.e., sensitizer, was safely stored in a cold and dark place.
Preparation of electrolyte
Herein, 80 mg potassium iodide and 13 mg iodine were mixed with ethanol in a culture tube and placed under continuous stirring for 5 min. The electrolyte solution containing a culture tube was stored in a dark place.
DSSC device assembling
The photoanodes and the copper-coated counter electrode were separated by a paraffin spacer and clamped together, keeping both the conducting surface facing each other (Fig. 1c). An electrolyte solution containing I−/I3− was injected in the hollow spacer area between the working electrode and counter electrode before assembling. As the electrolyte solution spread over and covered the whole active area via capillary action, two binder clips were used to hold the sandwich-like assembly for further electrical characterization.
Measurement and characterization
The light absorption property of the dye solution, dye-adsorbed TiO2, and TiO2/MnO2 bilayer assembly of photoanode was analyzed and recorded using a UV–Vis spectrophotometer (Hitachi Spectrophotometer, Japan). In dye solutions, functionalities and complex molecular bindings were studied within 500–4000 cm–1 using Fourier transform infrared spectroscopy (PerkinElmer, USA). The nanostructure's surface topography on photoanode was investigated by field emission scanning electron microscopy (JEOL, Japan). The diffractogram was studied via XRD diffractometer (XPert PRO, USA) using a CuKα source (1.54 Å). 40 kV and 30 mA sources were used to measure 2θ within 10°–80° using nickel-filtered CuKα radiation. The temperature-induced degradation of the natural dye material was characterized by TGA (PerkinElmer, USA). The fabricated DSSC performance was analyzed using an AM 1.5 G sun simulator exhibiting irradiation of 100 mW cm–2 intensity of light (Compact 150WSolar Simulator, Zolix Instruments, China) using source meter (model: 2450, Keithley, USA).
Results and discussion
UV–Vis analysis
Figure 2 envisages the absorption spectra of thin both films of natural dy-coated TiO2/MnO2 bilayer assembly, dye-coated TiO2, anatase TiO2, and dye solution. Though absorption band edges of TiO2 thin film and dye solution were observed at 300 nm and 375 nm, respectively, no significant peak was found for TiO2/MnO2 bilayer assembly and dye-coated TiO2. Interestingly, TiO2/MnO2 bilayer assembly and dye-coated TiO2 envisaged higher absorbance and long UV–Vis spectrum than the rest of the samples. From the Tauc plot, anatase TiO2 envisaged a high bandgap of 3.74 eV, whereas dye-coated TiO2 and TiO2/MnO2 bilayer assembly presented 2.31 and 1.99 eV bandgaps, respectively. Thus, the photoanode fabricated with dye-coated TiO2/MnO2 bilayer assembly elevated the absorption property throughout the longer UV–Vis spectrum via layer-by-layer photoanode architecture fabrication, suitable for solar cell application [25].
FTIR analysis
The Fourier-transform infrared spectroscopy (FTIR) peak at 3418 cm–1 was ascribed to the O–H str. of dye [26]. Moreover, peaks at 2925 and 2864 cm–1 were related to the C–H str. of –CH2– and –CH3 functionalities, respectively [27]. The –C≡N, C–N and N–H str. of amide, –CH3, and –O–C≡N functionalities in dye were confirmed from peaks at 2088, 1633, 1385, and 1085 cm−1, respectively [28, 29]. In ETOH, the change in C–O str' intensity was substantiated via slight displacement of the peak from 1094 to 1085 cm–1 in ethanol–dye solution (see Fig. 3).
FESEM analysis
Field emission scanning electron microscopy (FESEM) images envisaged uniform particle size distribution of TiO2 within 20–40 nm and resembled a distributed porous nanostructure network. TiO2/MnO2 bilayer nanostructure was more compact than TiO2. The surface morphology altered from the granular porous network of TiO2 to a more compact and relatively larger grain size of MnO2 in the TiO2/MnO2 bilayer assembly. The incorporation of MnO2 in a bilayer assembly significantly reduced the void fractions in the photoanode sample. The larger surface area of layer-by-layer architecture of TiO2/MnO2 bilayer assembly compared to other photoanode counterparts resulted in higher dye loading capability in the nanostructure [30]. The surface roughness and void fractions on the photoanode samples should substantially impact the electrical performances of the photoanode [31]. In this regard, the nanomaterials' electrical performance is significantly influenced via surface morphology linked directly with the specific surface area interaction with electrolyte [32] (see Fig. 4).
Structural analysis
The extent of orderliness, i.e., crystalline nature, and phase formation of the dye-adsorbed TiO2/MnO2 bilayer photoanode and TiO2 film were characterized by thin film XRD analysis (Fig. 5) in which the characteristic diffraction peaks recorded at 2θ = 25.78°, 37.6°, 38.18°, 48.38°, 54.37°, 63.22°, and 69.21° corresponding to crystallographic planes (101), (103), (004), (200), (105), (204), and (541) of the anatase phase of TiO2, respectively [33]. The complexation among TiO2 and MnO2 was substantiated by the presence of MnTiO3 in bilayer structure photoanode [34], confirmed by the diffraction peaks of MnTiO3 at 2θ = 31.64°, 35.34°, 51.8°, and 60.47° for (104), (110), (116), and (124) crystallographic planes, respectively. Moreover, the peaks at 2θ = 28.35°, 37.55°, 60.59°, and 65.86° for (310), (211),(521), and (002) planes confirmed the presence of MnO2 [35]. The additional characteristic peaks were correlated to the prevalent FTO and Ti [36]. In the TiO2/MnO2 bilayer assembly, a slight change in the main peak position of TiO2 from 25.32° to 25.78° was ascribed to the change in TiO2 crystal lattice due to the diffusion of Mn2+ ion in the TiO2 crystal.
TG analysis
Figure 6 shows the differential thermal analysis (DTA), derivative thermogravimetry (DTG) and TG curves of the natural dye extracts of Malvaviscus penduliflorus flower. From the dye's TG curve (Fig. 6), the weight losses within 50–100 °C corresponded to the loss of unbound water in the dye. Notably, the DTA curve was devoid of exothermic decomposition peak(s) or the endothermic dehydration peak(s) within 50–100 °C. Thus, this dye was suitable for DSSC solar cell application(s), confirming the dye's suitability in extreme climate conditions [6].
Photovoltaic study
The photovoltaic characteristics of the natural dye-sensitized DSSCs were tested via current density–voltage (J–V) and power–voltage (P–V) measurements. TiO2 and TiO2/MnO2 bilayer-assembled DSSCs were tested under simulated AM 1.5G solar illumination having 100 mW cm–2 light intensity. The performance was measured using a Keithley source meter at 27 °C. The output result of photovoltaic performance and different parameters of DSSCs, i.e., open-circuit voltage (Voc), short circuit current density (Jsc), fill factor (FF), efficiency (η), and maximum power output (Pmax), are given in Table 1. Because of the higher dye loading in TiO2/MnO2 bilayer nanostructure, the dye-adsorbed TiO2/MnO2 bilayer assembly showed more conversion efficiency compared to that of TiO2 in the photoanode (Fig. 7) [37]. Indeed, the bilayer assembly imparted an additional surface area for a higher amount of dye loading [38]. The decrease in open-circuit voltage (Voc) in the bilayer assembly could be attributed to the nanoparticles' elevated interfacial resistance. The Jsc improved significantly in the bilayer assembly due to increased spectral response with a longer wavelength. Interestingly, for both the photoanode samples, an increase in Voc and a decrease in Jsc were noted in the back side illumination. The rise in Voc was ascribed to the slow electron recombination, whereas the decrease in Jsc was related to reducing light penetration intensity in the back side illumination direction [39]. Notably, both light scattering effects and light reabsorbing ability of dye molecule reduced in the back side illumination.
The recombination kinetics of dye-coated TiO2, and TiO2/MnO2 bilayer-assembled DSSC devices were analyzed using open-circuit voltage decay (OCVD) studies. From the as-obtained OCVD curve (Fig. 8), the lifetime of Voc prevailed in the region between steady state and dark equilibrium. Moreover, the devices' OCVD profiles presented a slow decay rate for dye-coated TiO2/MnO2 bilayer devices compared to the device devoid of bilayer assembly, confirming a slow recombination rate in the bilayer structure of the device. Herein, the lifetime of the charge carrier is influenced by photoanode hierarchical architecture [40]. Notably, the lifetime of the charge carrier and Voc decay were correlated by the following reported equation [41]:
Here, k, T, and e represent Boltzmann constant, absolute temperature, and charge of electron, respectively. The bilayer structure photoanode envisaged a slower slope than the device without bilayer, supporting a slower recombination rate and longer lifetime of charge carrier (see Table 2).
Conclusions
Natural dye extract from Malvaviscus penduliflorus flower has been used for the fabrication of low-cost and eco-friendly DSSCs. The dye molecule's adsorption in the TiO2 matrix facilitates the charge transfer from the dye molecule to the TiO2 conduction band, elevating the efficiency. MnO2 in the TiO2/MnO2 bilayer structure reduces the bandgap, improving DSSC performance. The FTIR result indicates the interaction of dye molecule with alcohol. The change in intensity and shift of the peaks have revealed a charge-transfer complex between the dye molecule and alcohol. The hydroxyl anchored group's presence in the dye solution improves the light absorption coefficient in the visible spectrum. FESEM images of bilayer structure photoanode comprise the maximum surface coverage with the minimum agglomeration and void portion. Incorporating the MnO2 layer works as an interface between the TiO2 and electrolyte layer, which improves the surface passivation and electron transport. The deposition of the MnO2 layer on the TiO2 photoanode has no significant impact on the phase change of the TiO2 material. Thus, the interaction between TiO2 and MnO2 layer has effects only on the surroundings optoelectronic change. It was evident that the minor shift of the main TiO2 peak position at a higher diffraction angle can be attributed to incorporating Mn2+ ion into the TiO2 lattice. TG analysis confirmed the thermostability of dye up to 100 °C. Combining an electron transport layer like MnO2 on TiO2 material significantly improves the optoelectronic property of the photoanode. It is also concluded that incorporating an electron transport layer like MnO2 on TiO2 material significantly improves the optoelectronic property of the photoanode due to a combination of several factors including the increase of dye absorption. The significant improvement of quality charge extraction increases the diffusional length of charge carriers and reduces surface recombination enhanced the performance of the DSSC.
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Acknowledgements
This work was supported by Science and Engineering Research Board (SERB) grants funded by Department of Science and Technology (DST) Central, Government of India through Teachers Associateship for Research Excellence (TAR/2018/000195) [S. Roy]. The authors would like to acknowledge Dr. Achintya Singha, Associate Professor, Department of Physics Main Campus Bose Institute Kolkata for his valuable comments and ideas which helped to improve the manuscript.
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Datta, S., Dey, A., Singha, N.R. et al. Enhanced performance of dye-sensitized solar cell with thermally stable natural dye-assisted TiO2/MnO2 bilayer-assembled photoanode. Mater Renew Sustain Energy 9, 25 (2020). https://doi.org/10.1007/s40243-020-00185-3
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DOI: https://doi.org/10.1007/s40243-020-00185-3