Journal of Nanostructure in Chemistry

, Volume 7, Issue 3, pp 273–281 | Cite as

Synthesis, characterization, and application of nickel oxide/CNT nanocomposites to remove Pb2+ from aqueous solution

Open Access
Original Research

Abstract

In this study, the efficiency of nickel oxide/carbon nanotube (NiO/CNT) nanocomposite to remove Pb2+ from aqueous solution is investigated. NiO/CNT nanocomposite was prepared using the direct coprecipitation method in an aqueous media in the presence of CNTs. Samples were characterized using simultaneous thermal analysis (STA), X-ray diffraction (XRD), filed emission scanning electron microscopy (FESEM), and Brunauer–Emmett–Teller (BET). To optimize the adsorption of Pb2+ ions on NiO/CNT nanocomposite, the effects of different parameters including pH, contact time, initial concentration of Pb2+, and adsorbent mass—were also investigated. The optimum Pb2+ removal efficiency on NiO/CNT nanocomposite is achieved under experimental conditions of pH 7, contact time of 10 min, initial Pb2+ concentration of 20 ppm, and adsorbent mass of 0.1 g. The experimental data showed that the Pb2+ ions adsorption of NiO/CNT nanocomposite was through a Freundlich isotherm model rather than a Langmuir model. The kinetic data of adsorption of Pb2+ ions on the adsorbent was perfectly shown by a pseudo-second-order equation, to indicate their chemical adsorption. Thermodynamic parameters such as ΔG°, ΔH°, and ΔS° were also measured; the obtained values showed that the adsorption was basically spontaneous and endothermic.

Keywords

Removal Adsorption Carbon nanotubes Composite Heavy metals 

Introduction

Water, which is one of the main elements in the environment, is highly exposed to contamination. Among water pollutants, heavy metal cations, including Pb2+, Cd2+, Cr3+, Cr6+, Co2+, Cu2+, Fe3+, Ni2+ and Zn2+, are extremely toxic and non-biodegradable. These are commonly discharged into water sources and environment via either natural or industrial wastes. Today, elimination of water sources from such cations is among the main challenges faced by researchers and environmentalists. The accumulation of these metal cations in living organisms causes many physiological disorders [1]. The permitted level of Pb2+ in drinking water is 0.01 mg L−1 [2]. The exposure of human body organs to high concentrations of Pb2+ can result in anaemia, mental disorder, and renal and liver diseases.

Several different methods have been introduced and used for heavy metal removal [3], i.e. chemical precipitation, ion exchange, reverse osmosis, membrane-based processes, evaporation, solvent extraction, and adsorption. The efficiency of some of these methods is reduced due to major drawbacks including low removal efficiency and causing side effects that lead to new environmental issues.

In recent years, metal oxide nanoparticles especially metal oxide/CNT nanocomposites have attracted a good deal of persistent interest because of their unique chemical, physical, electrical, and thermal properties [4, 5, 6]. These materials are widely used in several areas, including chemistry, physics, material science, biology, medicine, and environment [7, 8].

Metal oxide nanoparticle and metal oxide/CNT nanocomposite adsorbents have been applied for the removal of heavy metals from aqueous solutions. These adsorbents are economically more affordable and also more environment-friendly [9, 10, 11, 12].

The amount of heavy metal uptake is directly associated with the total amount of active sites available on the adsorbent; a decrease in metallic nanoparticle dimensions increases their surface-to-volume ratio and consequently increases the active surface area for adsorption. In this regard, the utilization of appropriate substrate material in the synthesis procedure of metal oxide nanoparticles can prevent agglomeration, decrease the diameter of nanoparticles, and change the cluster-like morphology of nanoparticles to a powdered morphology. Therefore, the obtained nanocomposite with larger specific surface area and higher adsorption capacity can be employed as a suitable adsorbent for heavy metal removal.

Due to high surface-to-volume ratio, CNTs are considered as great substrates for the nucleation and growth of nanoparticles with control over diameter distribution [13, 14, 15, 16]. One of the main challenges encountered when CNTs are used as the support material for nanoparticle synthesis is the hydrophobicity of their surface. In this regard, surface functionalization of CNTs for the generation of covalent bonds and further attachment of oxide nanoparticles seems to be of great significance [17, 18, 19]. The functionalization of CNTs is commonly performed using the chemical oxidation process introducing functional groups such as –COOH, C–O, C=O, and –OH on the surface of CNTs; such groups act as active surface sites for metal attachment [20, 21]. NiO nanostructure can be synthesized through various methods such as co-precipitation [22], sol gel [23], hydrothermal [24], spray pyrolysis method [25], and chemical precipitation [26]. In this study, NiO/CNT nanocomposite was synthesized by chemical precipitation method, which was simple and cost efficient.

NiO/CNT nanocomposite was applied as an adsorbent to remove Pb2+ from aqueous solution. However, pH, contact time, adsorbent dosage, and initial concentration of Pb2+ were the parameters, the effects of which on adsorption uptake have been investigated.

Experiment

Materials

Lead nitrate [Pb(NO3)2, 99.5%], nickel chloride hexa-hydrate (NiCl2·6H2O, 98%), sodium hydroxide (NaOH, 99%), CNTs (MWCNTs, US4309, 20 < d < 30 nm, SSA = 264 m2 g−1, 95%), and sulphuric (95–97%), nitric (60%), and hydrochloric (37%) acids were applied without further purification.

To synthesize NiO/CNT nanocomposite, the surface of CNTs was functionalized as follows: initially, the desired amount of CNTs was added to the mixture of sulphuric/nitric/hydrochloric acids (6 M) and ultrasonicated for 30 min. The obtained mixture was stirred for 2 h at temperature of 80 °C and was then filtered and washed with deionized water until the pH reached 7. Finally, the functionalized CNTs were dried in an oven at 120 °C.

For NiO/CNT nanocomposite preparation with 1:1 weight ratio, 3.2 g of NiCl2·6H2O was dissolved in 50 ml of deionized water containing 1 g of functionalized CNTs. This was then ultrasonicated for 10 min and magnetically stirred for 15 min at 80 °C. The addition of 1.1 g of NaOH to the mixture and stirring for 30 min completed the precipitation of Ni(OH)2/CNTs nanocomposite. The obtained black mixture was filtered, washed with absolute ethanol and deionized water, dried at 120 °C for 24 h, and finally calcinated at 300 °C for 2 h in static air.

Methods of analysis

To determine the optimum calcination temperature of NiO/CNT nanocomposite powder, simultaneous thermal analysis (STA 1500) was applied in a static air atmospheric (10 °C min−1). The residual concentration of Pb2+ ions in aqueous media was analysed with the aid of Buck Scientifics 210 VGP flame atomic adsorption spectroscopy. The crystallinity of samples was determined using Xpertpr Pananalytical X-ray diffraction apparatus (Holland) with Cu(Kα) source and wavelength of λ = 1.5405 Å. The morphology of powders was recorded using Field Emission Scanning Electron Microscopy on a Mira3-XMU system. The BET specific surface area and porosity were determined using nitrogen adsorption–desorption porosimetry (77 K) by a porosimeter (Bel Japan, Inc.).

Adsorption studies

In this section, 1000 ppm of Pb2+ stock solution was initially provided through dissolving the desired volume of (Pb(NO3)2) in deionized water; the corresponding concentrations were then obtained from the dilution of the stock solution. For batch adsorption experiments, 0.1 g of NiO/CNT was added to 50 ml of 20 ppm solution of Pb2+ and then stirred. After adsorption, the nanocomposite was taken from the solution and the residual Pb2+ concentration was measured using flame atomic adsorption spectroscopy. The effects of the different parameters namely pH, initial Pb2+ concentration, adsorbent dosage, and contact time on the amount of adsorption were investigated through the removal percentage (R) of Pb2+ by the equation mentioned below:
$$\% R = \frac{{C_{0} - C_{\text{e}} }}{{C_{0} }} \times 100,$$
here, C0 and Ce are the initial and equilibrium concentrations of Pb2+ (mg L−1).

Result and discussion

NiO/CNT characterization

To study the temperature-dependent behaviour of nanocomposite, STA was performed on Ni(OH)2/CNT synthesized precursor in static air. According to the obtained spectra (Fig. 1), in the temperature range of 40–800 °C, three endothermic reactions occur in Ni(OH)2/CNT. In the range of 40–400 °C, two stages of weight loss in the sample are observed. These can be attributed to two reactions in the initial stage at 40–200 °C, attributing to surface moisture evaporation and the second one at 200–400 °C is the result of water release and the formation of NiO chemical structure with the following reactions:
$${\text{Ni(OH)}}_{2} \cdot 6{\text{H}}_{2} {\text{O}} \to {\text{Ni(OH)}}_{2} + 6{\text{H}}_{2} {\text{O,}}$$
$${\text{Ni(OH)}}_{2} \to {\text{NiO}} + {\text{H}}_{2} {\text{O}} .$$
Fig. 1

STA curves of Ni(OH)2/CNT in air

The slow decrease in weight at a temperature above 300 °C is related to the removal of small amounts of hydroxyl-groups remaining during the development of the NiO phase [27].

The weight percentage of the sample at 400 °C was 86%, which is related to the NiO/CNT nanocomposite. At 800 °C, the weight percentage of the sample reached 43%, due to the oxidation of CNTs into CO2 [28]. Following the specifications of STA, 300 °C was considered as the reaction temperature in the study.

The morphologies of NiO/CNT and pure NiO were analysed using FESEM images, as shown in Fig. 2. It can be seen in Fig. 2a that NiO nano-crystallites are aggregated, forming clusters with larger grains. The formation of this agglomerated structure has unfavourable impacts on the physical and chemical features of nanoparticles. The utilization of CNTs as the support material for the growth of nanoparticles reduces the agglomeration and changes the powder morphology from a cluster-like to a filamentous structure (Fig. 2b). It is observed that the nanoparticles on the surface of CNTs possess smaller dimensions in comparison with pure NiO nanoparticles [27].
Fig. 2

FESEM of a pure NiO and b NiO/CNT nanocomposite

Figure 3 indicates the X-ray diffraction pattern of Ni(OH)2/CNT and NiO/CNT nanocomposites. Characteristic peaks at 2θ = 37.3°, 43.4°, 62.9° and 75.4° are assigned to (111), (200), (220), and (311) crystallographic orientations in NiO nanoparticles, respectively (Fig. 3a), the strong diffraction peak at 2θ = 26° reflected from (002) lattice plane in CNTs [29]. The peaks of Ni(OH)2/CNT cannot be seen at NiO/CNT, which is due to the crystallization and change in the structure of crystal. The size of NiO/CNT nanoparticles was calculated using the Scherrer equation \(D = \frac{k\lambda}{\beta \cos \theta }\). The main reflection peak of the XRD pattern at 2θ = 43° can be attributed to (200) plane. The size of NiO/CNT nano-crystallites was 18.5 nm.
Fig. 3

XRD pattern of a Ni(OH)2/CNT and b NiO/CNT nanocomposite

N2 adsorption–desorption isotherms was utilized to assess the specific surface area, mean pore diameter and the total volume of NiO/CNT nanocomposite. The specific surface area of NiO/CNT nanocomposite was measured by the Brunauer–Emmett–Teller (BET) method (Fig. 4). The specific surface area, mean pore diameter and the total pore volume of NiO/CNT nanocomposite were determined to be 90 m2 g−1, 4.16 nm and 9.26 × 10−2 cm3 g−1, respectively.
Fig. 4

BET plot of NiO/CNT nanocomposite

Effect of pH

The pH is among the most remarkable parameters that should be controlled in metal ions adsorption process of aqueous solutions. To evaluate the effect of pH, the initial pH varied from 3 to 8 in the solution. It was observed (Fig. 5a) that the rate of removal of Pb2+ increased rapidly, from about 9–94% as pH increased from 3 to 6, and then remained constant following the increase of pH value from 7 to 8. Based on the authors’ best knowledge, lead species are available in Pb2+ and Pb(OH)+ forms at pH 3–8 [30]. When the pH value is low (<6), the predominant lead specie is Pb2+ and Pb2+ is removed by sorption reaction. Therefore, the lower adsorption percentage of Pb2+ on NiO/CNT at lower pH values partly depends on the competition between H+ and Pb2+ on the surface sites Pb2+ removal rate, which is maximized in pH values 6 to 8 and then remains constant. In this range, the main species are Pb2+ and Pb(OH)+; hence, Pb2+ removal is regulated by the sorption of Pb2+ and Pb(OH)+. According to the results of the current study, to eliminate Pb2+ from the solution by NiO/CNT, pH 7 is the most optimum value for the employed system.
Fig. 5

a Effect of pH, b contact time, c adsorbent mass and d initial concentration on Pb2+ removal by NiO/CNT nanocomposite

Effect of contact time

The contact time and its effect on Pb2+ elimination rate using NiO/CNT is depicted in Fig. 5b. The highest amount of adsorption approximately 100%, was achieved after 10 min of adsorption at pH 7. Therefore, a period of 10 min was considered as the optimum contact time for Pb2+ adsorption on the NiO/CNT nanocomposite.

Effect of adsorbent mass

Figure 5c illustrates the effect of adsorbent mass on the removal rate for a 20 ppm solution of Pb2+ by NiO/CNT nanocomposite and CNTs. In both adsorbents, the percentage of adsorbed lead increased as the mass of adsorbent was increased over the range of 0.02–0.1 g. A removal rate of approximately 100% was obtained when 0.1 g of NiO/CNT nanocomposite was drowned in 50 mL of the 20 ppm Pb2+ solution, compared to 43% removal when 0.1 g of CNTs was used. Based on the given results, it is obvious that the mechanism of nanocomposite adsorption towards Pb2+ may be attributed to three factors: the van der Waals interaction between the hexagonally arrayed carbon atoms in the graphite sheets of the CNTs and the positively charged lead ions, the electrostatic attraction between the negatively charged adsorbent surface of the CNT and Pb2+ cations, and the electrostatic attraction between Pb2+ and the electron pairs on the oxygen atoms of nickel oxide [30].

Effect of Pb2+ initial concentration

Figure 5d indicates the variation in removal rate in the initial concentration of Pb2+. It is evident that the initial concentration increase of Pb2+ from 20 to 100 ppm reduces the removal efficiency from almost 100–10%. At lower initial concentrations of Pb2+, an adequate number of active sites are available for adsorption, leading to a higher adsorption capacity. It is also noteworthy that at higher initial concentrations, the number of metal ions is higher compared with active adsorption sites; therefore, the removal efficiency decreases [31].

Adsorption isotherms

Adsorption isotherms represent the amount of adsorbed metal ion per unit mass of the adsorbent. Among all the isotherm models, the Langmuir and Freundlich models are the most popular ones describing adsorption in these systems [32, 33, 34]. The equilibrium adsorption capacity (qe) is calculated using:
$$q_{\text{e}} = \frac{{C_{0} - C_{\text{e}} }}{m}V,$$
here qe is the adsorbed Pb2+ amount (mg g−1), m is the composite mass (g), and V is the solution volume (L).
Figure 6a, b, respectively, illustrate Langmuir and Freundlich isotherms for Pb2+ adsorption on NiO/CNT nanocomposite with the obtained parameters summarized in Table 1. According to the data shown in Table 1, both the Langmuir and Freundlich models are appropriate for interpreting the obtained experimental data; however, the Freundlich model, with a higher correlation coefficient (R2), showed higher compatibility with the data, compared with the Langmuir model.
Fig. 6

a Langmuir, b Freundlich adsorption isotherm, c pseudo-first-order, d pseudo-second-order kinetic models and e Van’t Hoff plot for Pb2+ removal on NiO/CNT nanocomposite

Table 1

Langmuir, Freunlich parameters and correlation coefficients of Pb2+ adsorption onto NiO/CNT

Langmuir

\(\frac{1 }{{q_{\text{e}} }} = \left( {\frac{1 }{{q_{\text{m}} K_{L} }}} \right) + \left( {\frac{1 }{{C_{\text{e}} }}} \right) + \frac{1 }{{q_{\text{m}} }}\)

Freundlich

\({ \log }q_{\text{e}} = \log K_{\text{F}} + \frac{1 }{n}{ \log }C_{\text{e}}\)

qm (mg g−1)

KL (L mg−1)

R2

KF (L mg−1)

1/n

R2

24.63

1.14

0.9279

11.39

0.3493

0.9502

To get the synthesized absorbent efficiency approved, its maximum amount of absorption was compared with other adsorbents. As shown in Table 2, the maximum absorption capacity obtained in this study is significant compared to other adsorbents [35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46], which indicates the efficiency of the synthetic adsorbent.
Table 2

The equilibrium capacities of Pb(II) on various adsorbents

Adsorbents

qmax (mg g−1)

References

MWCNTs

1

[35]

MWCNTs

4

[36]

Activated carbon

13.05

[37]

MWCNTs

15.6

[35]

Oxidized MWCNTs

2.06

[38]

Oxidized N-doped MWCNTs

29

[39]

MWCNT-f

14.56

[40]

Tiol/CNT

65.52

[41]

SiO2/MWCNT

13

[42]

Iron oxid/MWCNT

12

[43]

Al2O3/CNTs

67.5

[44]

PAAM/MWCNTs

29.71

[45]

Zeolites: chabazite

6

[46]

NiO/CNTs

24.63

This study

Adsorption kinetics

One of the most important features of designing an adsorption system is the prediction of the adsorption rate, i.e., how fast the adsorption is taking place, which is controlled by adsorption kinetics. The adsorption kinetics depends on the adsorbent physical and chemical properties; it also affects the adsorption mechanism. To evaluate the adsorption mechanism, adsorption kinetic constants, Lagergren pseudo first-order and Ho, pseudo second-order rate equations can be used [47].

The obtained results are summarized in Fig. 6c, d, and Table 3. According to Table 3, the pseudo second-order model, with higher values of correlation coefficient (R2) and closer values of calculated adsorption capacity (qe,cal) to experimental one (qe,exp) is a better model to describe the adsorption capacity of ions on NiO/CNT nanocomposite. This indicates that the adsorption of Pb2+ onto NiO/CNT may be the chemisorption involving valence forces through the exchange or sharing of electrons between adsorbate and adsorbent [48].
Table 3

Adsorption kinetic parameters of Pb2+ adsorption onto NiO/CNT

Psedo-first-order Ln(qe − qt) = Lnqe − k1t

Psedo-second-order \(\frac{t}{{q_{\text{t}} }} = \frac{1}{{k_{2_{}} q_{\text{e}}^{2} }} + \frac{1}{{q_{\text{e}} }}t\)

Experimental data

k1 (min−1)

qe,cal (g mg−1 min−1)

R2

k2 (g mg−1 min−1)

qe,cal (mg g−1)

R2

qe,exp (mg g−1)

0.46

16.54

0.9787

0.189

10.55

0.9997

10

Adsorption thermodynamics

Another feature of any adsorption process with high significance is the determination of thermodynamic parameters, including changes in Gibbs free energy (ΔG°, KJ mol−1), enthalpy (ΔH°, KJ mol−1), and entropy (ΔS°, J mol−1 K−1). Adsorption thermodynamics were evaluated at different temperatures (288, 298, 308, and 318 K). The results are depicted in Fig. 6e. To measure the thermodynamic parameters and Kd values, Van’t Hoff equation was applied [49].

The results of calculation are shown in Table 4. The negative values of ΔG° indicate that the adsorption was a spontaneous reaction. The ΔH° and ΔS° positive values are attributed to the endothermic nature of adsorption and the increase in the randomness at the solid/liquid interface during the adsorption of Pb2+ on NiO/CNT nanocomposite, respectively.
Table 4

Values of thermodynamic parameters of adsorption of Pb2+ onto NiO/CNT

\({\text{Ln}}K_{\text{d}} = \frac{\Delta S^\circ }{R} - \frac{\Delta H^\circ }{RT}\)

ΔG° (temperature, K)

ΔS°

ΔH°

\(\Delta G^\circ = - RT\ln K_{\text{d}}\)

 

\(K_{\text{d}} = \frac{{q_{\text{e}} }}{{C_{\text{e}} }}\)

224.26

61.55

2.80 (288)

−5.52 (298)

−7.89 (308)

−9.57 (318)

Conclusion

In this study, NiO/CNT nanocomposite was utilized as an adsorbent to remove Pb2+ from an aqueous solution. The NiO/CNT nanocomposite powder was prepared using direct coprecipitation process in the aqueous media. The results indicate that the optimum efficiency for Pb2+ removal is achieved under experimental conditions of pH 7, contact time of 10 min, and the initial Pb2+ concentration of 20 ppm. Moreover, increasing the initial concentration of Pb2+ and reducing the adsorbent dosage diminishes the removal efficiency. Therefore, NiO/CNT nanocomposite can be considered as a useful adsorbent for the elimination of aqueous solutions from Pb2+. In addition, results obtained from Pb2+ adsorption on NiO/CNT nanocomposite follow the pseudo second-order rate equation and Freundlich isotherm.

References

  1. 1.
    Bedelean, H., Maicaneanu, A., Burca, S., Stanca, M.: Removal of heavy metal ions from wastewaters using natural clays. J. Clay Miner. 44, 487–495 (2009)CrossRefGoogle Scholar
  2. 2.
    Chand, P., Pakade, Y.B.: Synthesis and characterization of hydroxyapatite nanoparticles impregnated on apple pomace to enhanced adsorption of Pb(II), Cd(II) and Ni(II) ions from aqueous solution. Environ. Sci. Pollut. Res. 22, 10919–10929 (2015)CrossRefGoogle Scholar
  3. 3.
    Shafaei, A., Ashtiani, F.Z., Kaghazchi, T.: Equilibrium studies of the sorption of Hg(II) ions onto chitosan. Chem. Eng. J. 133(1–3), 311–316 (2007)CrossRefGoogle Scholar
  4. 4.
    Kumar, R., Singh, R.K., Dubey, P.K., Singh, D.P., Yadav, R.M., Tiwari, R.S.: Freestanding 3D graphene–nickel encapsulated nitrogen-rich aligned bamboo like carbon nanotubes for high-performance supercapacitors with robust cycle stability. Adv. Mater. Interfaces 2, 1500191 (2015)CrossRefGoogle Scholar
  5. 5.
    Kumar, R., Singh, R.K., Singh, D.P., Vaz, A.R., Yadav, R.R., Rout, C.S., Moshkalev, S.A.: Synthesis of self-assembled and hierarchical palladium-CNTs-reduced graphene oxide composites for enhanced field emission properties. Mater. Des. 122, 110–117 (2017)CrossRefGoogle Scholar
  6. 6.
    Kumar, R., Singh, R.K., Dubey, P.K., Singh, D.P., Yadav, R.M.: Self-assembled Hierarchical formation of conjugated 3D cobalt oxide nanobeads–CNTs–graphene nanostructure using microwave for high performance supercapacitor electrode. ACS Appl. Mater. Interfaces 7, 15042–15051 (2015)CrossRefGoogle Scholar
  7. 7.
    Zare, K., Gupta, V.K., Moradi, O., Makhlouf, A.S.H., Sillanpää, M., Nadagouda, M.N., Sadegh, H., Shahryari-ghoshekandi, R., Pal, A., Wang, Z., Tyagi, T., Kazemi, M.: A comparative study on the basis of adsorption capacity between CNTs and activated carbon as adsorbents for removal of noxious synthetic dyes: a review. J. Nanostruct. Chem. 5(2), 227–236 (2015)CrossRefGoogle Scholar
  8. 8.
    Moradi, O., Fakhri, A., Adami, S., Adami, S.: Isotherm, thermodynamic, kinetics, and adsorption mechanism studies of Ethidium bromide by single-walled carbon nanotube and carboxylate group functionalized single-walled carbon nanotube. J. Colloid Interface Sci. 395, 224–229 (2013)CrossRefGoogle Scholar
  9. 9.
    Abd El Fatah, Ossman, M.E.: Removal of heavy metal by nickel oxide nano powder. Int. J. Environ. Res. 8(3), 741–750 (2014)Google Scholar
  10. 10.
    Coston, J.A., Fuller, C.C., Davis, J.A.: Pb2+ and Zn2+ adsorption by a natural aluminum-and iron-bearing surface coating on an aquifer sand. Geochim. Cosmochim. Acta 59, 3535–3547 (1995)CrossRefGoogle Scholar
  11. 11.
    Agrawal, A., Sahu, K.K.: Kinetic and isotherm studies of cadmium adsorption on manganese nodule residue. J. Hazard. Mater. 137, 915–924 (2006)CrossRefGoogle Scholar
  12. 12.
    Srivastava, N.K., Jha, M.K., Sreekrishnan, T.R.: Removal of Cr(VI) from waste water using NiO nanoparticles. Int. Sci. Environ. Technol. 3(2), 395–402 (2014)Google Scholar
  13. 13.
    Awasthi, S., Awasthi, K., Kumar, R., Srivastava, O.N.: Functionalization effects on the electrical properties of multi-walled carbon nanotube-polyacrylamide composites. J. Nanosci. Nanotechnol. 9, 5455–5460 (2009)CrossRefGoogle Scholar
  14. 14.
    Kumar, R., Singh, R.K., Ghosh, A.K., Sen, R., Srivastava, S.K., Tiwari, R.S., Srivastava, O.N.: Synthesis of coal-derived single-walled carbon nanotube from coal by varying the ratio of Zr/Ni as bimetallic catalyst. J. Nanopart. Res. 15, 1406 (2013)CrossRefGoogle Scholar
  15. 15.
    Kumar, R., Singh, R.K., Singh, D.P.: Natural and waste hydrocarbon precursors for the synthesis of carbon based nanomaterials: graphene and CNTs. Renew. Sustain. Energy Rev. 58, 976–1006 (2016)CrossRefGoogle Scholar
  16. 16.
    Li, Y.H., Di, Z., Ding, J., Wu, D., Luan, Z., Zhu, Y.: Adsorption thermodynamic, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Res. 39, 605–609 (2005)CrossRefGoogle Scholar
  17. 17.
    Taleshi, F., Hosseini, A.A.: Synthesis of uniform MgO/CNT nanorods by precipitation method. J. Nanostruct. Chem. 3(1), 1–5 (2012)CrossRefGoogle Scholar
  18. 18.
    Jiang, S., Storr Handberg, E., Liu, F., Liao, Y., Wang, H., Li, Z., Song, S.: Effect of doping the nitrogen into carbon nanotubes on the activity of NiO catalysts for the oxidation removal of toluene. Appl. Catal. B 160–161, 716–721 (2014)CrossRefGoogle Scholar
  19. 19.
    Songa, S., Meng, A., Jiang, S., Cheng, B., Jiang, C.: Construction of Z-scheme Ag2CO3/N-doped graphene photocatalysts with enhanced visible-light photocatalytic activity by tuning the nitrogen species. Appl. Surf. Sci. 396, 1368–1374 (2017)CrossRefGoogle Scholar
  20. 20.
    Taleshi, F., Porkia, M., Shakeri Chenari, I., Pahlavan, A., Ahmadi Tarsi, M., Zabihi, F., Dehghan-niarostami, N.: Morphology of CuFe2O4/CNT composites prepared by precipitation, plastics, rubber and composites. Macromol. Eng. 43, 240–244 (2014)Google Scholar
  21. 21.
    Han, W.Q., Zettl, A.: Coating single-walled carbon nanotubes with tin oxide. Nano Lett. 3, 681–683 (2003)CrossRefGoogle Scholar
  22. 22.
    Mallick, P., Chandanarath Biswal, R., Mishra, N.C.: Structural and magnetic properties of Fe doped NiO. Indian J. Phys. 83, 517–523 (2009)CrossRefGoogle Scholar
  23. 23.
    Mallick, P., Sahoo, C.S., Mishra, N.C.: Structural and optical characterization of NiO nanoparticles synthesized by sol-gel route. AIP Conf. Proc. 1461, 229–232 (2012)CrossRefGoogle Scholar
  24. 24.
    Takami, S., Hayakawa, R., Wakayama, Y., Chikyow, T.: Continuous hydrothermal synthesis of nickel oxide nanoplates and their use as nanoinks for p-type channel material in a bottom-gate field-effect transistor. Nanotechnology 21, 134009 (2010)CrossRefGoogle Scholar
  25. 25.
    Yudin, A., Shatrova, N., Khaydarov, B., Kuznetsov, D., Dzidziguri, E., Issi, J.P.: Synthesis of hollow nanostructured nickel oxide microspheres by ultrasonic spray atomization. J. Aerosol Sci. 98, 30–40 (2016)CrossRefGoogle Scholar
  26. 26.
    Chakrabarty, S., Chatterjee, K.: Synthesis and characterization of nanodimensional NiO semiconductor. J. Phys. Sci. 13, 245–250 (2008)Google Scholar
  27. 27.
    Lin, P., She, Q., Hong, B., Liu, X., Shi, Y., Shi, Z., Zheng, M., Donga, Q.: The nickel oxide/CNT composites with high capacitance for supercapacitor. J. Electrochem. Soc. 157(7), A818–A823 (2010)CrossRefGoogle Scholar
  28. 28.
    Kumar, R., Singh, R.K., Vaz, A.R., Savu, R., Moshkalev, S.A.: Self-assembled and one-step synthesis of interconnected 3D network of Fe3O4/reduced graphene oxide nanosheets hybrid for high-performance supercapacitor electrode. Appl. Mater. Interfaces 9, 8880–8890 (2017)CrossRefGoogle Scholar
  29. 29.
    Taleshi, F.: A new strategy for increasing the yield of carbon nanotubes by the CVD method. Fuller. Nanotubes Carbon Nanostruct. 22, 921–927 (2014)CrossRefGoogle Scholar
  30. 30.
    Gupta, V.K., Agarwal, S., Saleh, T.A.: Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J. Hazard. Mater. 185, 17–23 (2011)CrossRefGoogle Scholar
  31. 31.
    Rao, M.M., Ramesh, A., Rao, G.P.C., Seshaiah, K.: Removal of copper and cadmium from the aqueous solutions by activated carbon derived from Ceiba pentandra hulls. J. Hazard. Mater. B 129, 123–129 (2006)CrossRefGoogle Scholar
  32. 32.
    Tahermansouri, H., Dehghan, Z., Kiani, F.: Phenol adsorption from aqueous solutions by functionalized multiwalled carbon nanotubes with a pyrazoline derivative in the presence of ultrasound. RSC Adv. 5, 44263–44273 (2015)CrossRefGoogle Scholar
  33. 33.
    Langmuir, I.: The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40, 1361–1403 (1918)CrossRefGoogle Scholar
  34. 34.
    Freundlich, H.: Over the adsorption in solution. J. Phys. Chem. 57, 385–470 (1906)Google Scholar
  35. 35.
    Li, Y.H., Wang, S., Wei, J., Zhang, X., Xu, C., Luan, Z., Wei, B.: Lead adsorption on carbon nanotubes. Chem. Phys. Lett. 357, 263–266 (2002)CrossRefGoogle Scholar
  36. 36.
    Chen, Y., Haddon, R.C., Fang, S., Rao, A.M., Eklund, P.C., Lee, W.H., Smalley, R.E.: Chemical attachment of organic functional groups to single-walled carbon nanotube material. J. Mater. Res. 13, 2423–2431 (1998)CrossRefGoogle Scholar
  37. 37.
    Imamoglu, M., Tekir, O.: Removal of copper(II) and lead(II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228, 108–113 (2008)CrossRefGoogle Scholar
  38. 38.
    Xu, D., Tan, X., Chen, C., Wang, X.: Removal of Pb(II) from aqueous solution by oxidized multiwalled carbon nanotubes. J. Hazard. Mater. 154, 407–416 (2008)CrossRefGoogle Scholar
  39. 39.
    Perez-Aguilar, N., Muñoz-Sandoval, E., Diaz-Flores, P., Rangel- Mendez, J.: Adsorption of cadmium and lead onto oxidized nitrogendoped multiwall carbon nanotubes in aqueous solution: equilibrium and kinetics. J. Nanopart. Res. 12, 467–480 (2010)CrossRefGoogle Scholar
  40. 40.
    Jahangiri, M., Kiani, F., Tahermansouri, H., Rajabalinezhad, A.: The removal of lead ions from aqueous solutions by modified multi-walled carbon nanotubes with 1-isatin-3-thiosemicarbazone. J. Mol. Liq. 212, 219–226 (2015)CrossRefGoogle Scholar
  41. 41.
    Zhang, C., Sui, J., Li, J., Tang, Y., Cai, W.: Efficient removal of heavy metal ions by thiol functionalized superparamagnetic carbon nanotubes. Chem. Eng. J. 210, 45–52 (2012)CrossRefGoogle Scholar
  42. 42.
    Saleh, T.A.: Nanocomposite of carbon nanotubes/silica nanoparticles and their use for adsorption of Pb(II): from surface properties to sorption mechanism. Desalin. Water Treat. 57, 10730–10744 (2016)CrossRefGoogle Scholar
  43. 43.
    Hu, J., Shao, D., Chen, C., Sheng, G., Li, J., Wang, X., Nagatsu, M.: Plasma-induced grafting of cyclodextrin onto multiwall carbon nanotube/iron oxides for adsorbent application. J. Phys. Chem. B 114, 6779–6785 (2010)CrossRefGoogle Scholar
  44. 44.
    Hsieh, S.H., Horng, J.J.: Adsorption behavior of heavy metal ions by carbon nanotubes grown on microsized Al2O3 particles. J. Univ. Sci. Technol. 14, 77–84 (2007)CrossRefGoogle Scholar
  45. 45.
    Yang, S., Hu, J., Chen, C., Shao, D., Wang, X.: Mutual effects of Pb(II) and humic acid adsorption on multiwalled carbon nanotubes/polyacrylamide composites from aqueous solutions. Environ. Sci. Technol. 45, 3621–3627 (2011)CrossRefGoogle Scholar
  46. 46.
    Ouki, S.K., Kavannagh, M.: Performance of natural zeolites for the treatment of mixed metal-contaminated effluents. Waste Manag. Res. 15, 383–394 (1997)CrossRefGoogle Scholar
  47. 47.
    Benguell, B., Benaissa, H.: Cadmium removal from aqueous solutions by chitin: kinetic and equilibrium studies. Water Res. 36, 2463–2474 (2002)CrossRefGoogle Scholar
  48. 48.
    Gu, H., Lou, H., Tian, J., Liu, S., Tang, Y.: Reproducible magnetic carbon nanocomposites derived from polystyrene with superior tetrabromobisphenol A adsorption performance. J. Mater. Chem. A 4, 10174–10185 (2016)CrossRefGoogle Scholar
  49. 49.
    Gu, H., Lou, H., Ling, D., Xiang, B., Guo, Z.: Polystyrene controlled growth of zerovalent nanoiron/magnetite on a sponge-like carbon matrix towards effective Cr(VI) removal from polluted water. RSC Adv. 6, 110134–110145 (2016)CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.Department of Chemistry, Science and Research BranchIslamic Azad UniversityTehranIran
  2. 2.Department of Physics, Qaemshahr BranchIslamic Azad UniversityQaemshahrIran

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