Abstract
One main source of nickel besides nickel sulfide ore is laterite nickel ore. Laterite ore is more sustainable and has abundant reserves. Nowadays, nickel demands are increasingly needed either for the manufacture of stainless steel or nickel-based batteries. This study aims to study the smelting process of limonitic laterite nickel ore. The smelting process was performed using a Mini Blast Furnace pilot plant with a capacity of ten tons of ore per day or 350 kg per batch. In the interest of modifying the properties of slag and enhance selective reduction, limestone and coal were used. The smelting process was performed by feeding raw material bearing nickel (ore and sinter) as much as 480 kg. The ratio of nickel:sintered:coal:limestone was 1:2.3:2.73:(1.14–1.44). The blast air used was 26 m3/min. Then, the crude ferronickel or nickel pig iron products and the resulting slag were characterized using EDX and XRD. As a result, the resulting crude ferronickel products had relatively high nickel and sulfur contents, namely 24.30% and 1.15%, respectively. In addition, the nickel recovery produced was 64.3%. Selective reduction proved can be enhanced by amount of limestone fed into Mini Blast Furnace.
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F. Knobloch, S.V. Hanssen, A. Lam et al., Net emission reductions from electric cars and heat pumps in 59 world regions over time. Nature Sustain. 3(6), 437–447 (2020). https://doi.org/10.1038/s41893-020-0488-7
C. Xu, Q. Dai, L. Gaines et al., Future material demand for automotive lithium-based batteries. Commun. Mater. 1, 1–10 (2020). https://doi.org/10.1038/s43246-020-00095-x
A. Accardo, G. Dotelli, M.L. Musa, E. Spessa, Life cycle assessment of an NMC battery for application to electric light-duty commercial vehicles and comparison with a sodium-nickel-chloride battery. Appl. Sci. 11, 1160 (2021). https://doi.org/10.3390/APP11031160
D. Kinch, B. Kilbey, Greater nickel usage, vertical integration, now major trends in EV batterymaking: Roskill | S&P Global Platts (2021). https://www.spglobal.com/platts/en/market-insights/latest-news/metals/012021-greater-nickel-usage-vertical-integration-now-major-trends-in-ev-batterymaking-roskill. Accessed 11 Aug 2021
Statista Research Department, • Worldwide—demand for nickel in EV batteries 2025 | Statista (2021). https://www.statista.com/statistics/967700/global-demand-for-nickel-in-ev-batteries/. Accessed 11 Aug 2021
British Geological Survey, Battery raw materials briefing note on raw materials for batteries in electric vehicles background (2018). https://www2.bgs.ac.uk/mineralsuk/download/briefing_papers/batteryRawMaterial.pdf
M.L.C.M. Henckens, E. Worrell, Reviewing the availability of copper and nickel for future generations. The balance between production growth, sustainability and recycling rates. J. Clean. Prod. 264, 121460 (2020). https://doi.org/10.1016/J.JCLEPRO.2020.121460
R. Ferreira, F. Pinto, INSG insight comment on the effect of the COVID-19 pandemic on the global nickel market (2020). https://insg.org/wp-content/uploads/2020/10/INSG_Insight_32-Comment-on-the-effect-of-the-Covid-19-pandemic-on-the-global-nickel-market.pdf
T.E. Norgate, S. Jahanshahi, W.J. Rankin, Alternative routes to stainless steel-a life cycle approach. in: 10th International Ferroalloys Congress, 1–4 Feb 2004 (South African Institute of Mining and Metallurgy, Cape Town, South Africa, Marshalltown, SA, 2004), pp. 693–704. http://hdl.handle.net/102.100.100/188402?index=1
S. Pintowantoro, F. Abdul, Selective reduction of laterite nickel ore. Mater. Trans. 60, 2245–2254 (2019). https://doi.org/10.2320/MATERTRANS.MT-M2019101
B. Widyartha, Y. Setiyorini, F. Abdul et al., Effective beneficiation of low content nickel ferrous laterite using fluxing agent through Na2SO4 selective reduction. Materialwiss. Werkstofftech. 51, 750–757 (2020). https://doi.org/10.1002/MAWE.202000007
A.D. Dalvi, W. Gordon Bacon, M. Robert, C. Osborne, The past and the future of nickel laterites. in: PDAC 2004 International Convention, Trade Show & Investors Exchange. The prospectors and Developers Association of Canada Toronto, (2004), pp. 1–27
J.K.I.J.H. Seo, A study on classification of limonite and saprolite from nickel laterite ores. Resour. Recycl. 25, 40–47 (2016). https://doi.org/10.7844/KIRR.2016.25.1.40
F. Rodrigues, C.A. Pickles, J. Peacey et al., Factors affecting the upgrading of a nickeliferous limonitic laterite ore by reduction roasting, thermal growth and magnetic separation. Minerals 7, 176 (2017). https://doi.org/10.3390/MIN7090176
F. Abdul, S. Pintowantoro, A. Purnamasari, Direct reduction of nickel laterite limonitic ore using a coal-dolomite mixture bed and Na2SO4 as a selective agent. J. Chem. Technol. Metall. 55, 103–110 (2020)
Y.C. Zhai, W.N. Mu, Y. Liu, Q. Xu, A green process for recovering nickel from nickeliferous laterite ores. Trans. Nonferrous Met. Soc. China 20, s65–s70 (2010). https://doi.org/10.1016/S1003-6326(10)60014-3
F. Abdul, S. Pintowantoro, A. Kawigraha, A. Nursidiq, Effects of reduction temperature to Ni and Fe content and the morphology of agglomerate of reduced laterite limonitic nickel ore by coal-bed method. AIP Conf. Proc. 1945, 020034 (2018). https://doi.org/10.1063/1.5030256
F. Abdul, S. Pintowantoro, R.B. Yuwandono, Analysis of holding time variations to Ni and Fe content and morphology in nickel laterite limonitic reduction process by using coal-dolomite bed. AIP Conf. Proc. 1945, 020033 (2018). https://doi.org/10.1063/1.5030255
T. Ogura, K. Kuwayama, A. Ono, Y. Yamada, Production of Fe–Ni by the rotary kiln-electric furnace process at Hyuga Smelter. Int. J. Miner. Process. 19, 189–198 (1987). https://doi.org/10.1016/0301-7516(87)90040-8
D. Zhao, B. Ma, B. Shi et al., Mineralogical characterization of limonitic laterite from Africa and its proposed processing route. J. Sustain. Metall. 6(3), 491–503 (2020). https://doi.org/10.1007/S40831-020-00290-7
L.B. Tsymbulov, M.V. Knyazev, L.S. Tsemekhman, Oxide nickel ores smelting of ferronickel in two-zone Vaniukov Furnace. Canadian Metallurgical Quarterly 50(2), 135–144 (2013). https://doi.org/10.1179/000844311X12949291727772
E. Keskinkilic, Nickel laterite smelting processes and some examples of recent possible modifications to the conventional route. Metals 9, 974 (2019). https://doi.org/10.3390/MET9090974
S. Pintowantoro, R.A.M. Pasha, F. Abdul, Gypsum utilization on selective reduction of limonitic laterite nickel. Results Eng. 12, 100296 (2021). https://doi.org/10.1016/j.rineng.2021.100296
S. Yuan, ZHOU W tao, LI Y jun, HAN Y xin, Efficient enrichment of nickel and iron in laterite nickel ore by deep reduction and magnetic separation. Trans. Nonferrous Met. Soc. China 30, 812–822 (2020). https://doi.org/10.1016/S1003-6326(20)65256-6
J. Xiao, W. Xiong, K. Zou et al., Extraction of nickel from magnesia–nickel silicate ore. J. Sustain. Metall. 7(2), 642–652 (2021). https://doi.org/10.1007/S40831-021-00364-0
W. Astuti, R. Andika, F. Nurjaman, Effect of basicity and reductant amount in the nickel pig iron (NPI) production from Indonesian limonite ore in submerged electric arc furnace (SAF). IOP Conf. Ser. Mater. Sci. Eng. 285, 012023 (2018). https://doi.org/10.1088/1757-899X/285/1/012023
M. Liu, X. Lv, E. Guo et al., Novel process of ferronickel nugget production from nickel laterite by semi-molten state reduction. ISIJ Int. 54, 1749–1754 (2014). https://doi.org/10.2355/ISIJINTERNATIONAL.54.1749
M. Rao, G. Li, T. Jiang et al., Carbothermic reduction of nickeliferous laterite ores for nickel pig iron production in China: a review. JOM 65(11), 1573–1583 (2013). https://doi.org/10.1007/S11837-013-0760-7
S. Pintowantoro, A.B. Widyartha, Y. Setiyorini, F. Abdul, Sodium thiosulfate and natural sulfur: novel potential additives for selective reduction of limonitic laterite ore. J. Sustain. Metall. 7(2), 481–494 (2021). https://doi.org/10.1007/S40831-021-00352-4
M. Haziq Uddin, L. Tafaghodi Khajavi, The effect of sulfur in rotary kiln fuels on nickel laterite calcination. Miner. Eng. 157, 106563 (2020). https://doi.org/10.1016/J.MINENG.2020.106563
F. Abdul, S. Pintowantoro, A. Maulidani, Analysis the effect of charcoal mass variation to Ni content, sinter strength and yield on sintering process of limonitic laterite nickel ore. Key Eng. Mater. 867, 25–31 (2020). https://doi.org/10.4028/WWW.SCIENTIFIC.NET/KEM.867.25
D. Fernández-González, I. Ruiz-Bustinza, J. Mochón et al., Iron ore sintering: process, Mineral Processing and Extractive. Metall. Rev. 38(4), 215–227 (2017). https://doi.org/10.1080/08827508.2017.1288115
S. Pintowantoro, F. Abdul, P.I. Nindhita, A.B. Widyartha, Analysis of flux type variations in the sintering process of limonitic laterite nickel ore. AIP Conf. Proc. 2262, 070002 (2020). https://doi.org/10.1063/5.0016067
F. Abdul, S. Pintowantoro, A. Yurisman, The effect of air flow rate on sinter yield, sinter strength and Ni content in sintering laterite nickel ore. Mater. Res. Commun. 1, 26–33 (2020)
R. Elliott, F. Rodrigues, C.A. Pickles, J. Peacey, A two-stage thermal upgrading process for nickeliferous limonitic laterite ores. Canad. Metall. Quarter. 54(4), 395–405 (2016). https://doi.org/10.1179/1879139515Y.0000000009
J. Yang, G. Zhang, O. Ostrovski, S. Jahanshahi, Selective reduction of an Australian garnieritic laterite ore. Miner. Eng. 131, 79–89 (2019). https://doi.org/10.1016/J.MINENG.2018.10.018
G. Hang, Z. Xue, Y. Wu, Preparation of high-grade ferronickel from low-grade nickel laterite by self-reduction and selective oxidation with CO2-CO gas. Miner. Eng. 151, 106318 (2020). https://doi.org/10.1016/J.MINENG.2020.106318
S. Pournaderi, E. Keskinkiliç, A. Geveci, Y.A. Topkaya, Laboratory-scale smelting of limonitic laterite ore from Central Anatolia. J. South. Afr. Inst. Min. Metall. 117, 695–703 (2017). https://doi.org/10.17159/2411-9717/2017/V117N7A11
D. Wang, Q. Wang, S. Zhuang, J. Yang, Evaluation of alkali-activated blast furnace ferronickel slag as a cementitious material: reaction mechanism, engineering properties and leaching behaviors. Constr. Build. Mater. 188, 860–873 (2018)
Y. Wang, R. Zhu, Q. Chen et al., Recovery of Fe, Ni Co, and Cu from nickel converter slag through oxidation and reduction. ISIJ Int. 58, 2191–2199 (2018). https://doi.org/10.2355/ISIJINTERNATIONAL.ISIJINT-2018-533
G. Sun, B. Li, H. Guo et al., Thermodynamic study on reduction of iron oxides by H2 + CO + CH4 + N2 mixture at 900 °C. Energies 13, 5053 (2020). https://doi.org/10.3390/EN13195053
S. Ilyas, R.R. Srivastava, H. Kim et al., Extraction of nickel and cobalt from a laterite ore using the carbothermic reduction roasting-ammoniacal leaching process. Sep. Purif. Technol. 232, 115971 (2020). https://doi.org/10.1016/J.SEPPUR.2019.115971
J. Chen, P.C. Hayes, Mechanisms and kinetics of reduction of solid NiO in CO/CO2 and CO/Ar gas mixtures. Metall. Mater. Trans. B 50(6), 2623–2635 (2019). https://doi.org/10.1007/S11663-019-01662-5
A.E.M. Warner, C.M. Díaz, A.D. Dalvi et al., JOM world nonferrous smelter survey, part III: nickel: laterite. JOM 58(4), 11–20 (2006). https://doi.org/10.1007/S11837-006-0209-3
M. Solar, I. Candi, B. Wasmund, Selection of optimum ferronickel grade for smelting nickel laterites (2008). https://store.cim.org/en/selection-of-optimum-ferronickel-grade-for-smelting-nickel-laterites. Accessed 11 Aug 2021
D.R. Swinbourne, Understanding ferronickel smelting from laterites through computational thermodynamics modelling. Miner. Process. Extr. Metall. 123(3), 127–140 (2014). https://doi.org/10.1179/1743285514Y.0000000056
S. Harjanto, M.A. Rhamdhani, Sulfides formation in carbothermic reduction of saprolitic nickel laterite ore using low-rank coals and additives: a thermodynamic simulation analysis. Minerals 9, 631 (2019). https://doi.org/10.3390/MIN9100631
Z. Liu, T. Sun, X. Wang, E. Gao, Generation process of FeS and its inhibition mechanism on iron mineral reduction in selective direct reduction of laterite nickel ore. Int. J. Miner. Metall. Mater. 22(9), 901–906 (2015). https://doi.org/10.1007/S12613-015-1148-1
D.Q. Zhu, Y. Cui, K. Vining et al., Upgrading low nickel content laterite ores using selective reduction followed by magnetic separation. Int. J. Miner. Process. 106–109, 1–7 (2012). https://doi.org/10.1016/J.MINPRO.2012.01.003
D. Zhu, L. Pan, Z. Guo et al., Utilization of limonitic nickel laterite to produce ferronickel concentrate by the selective reduction-magnetic separation process. Adv. Powder Technol. 30, 451–460 (2019). https://doi.org/10.1016/J.APT.2018.11.024
F. Nurjaman, K. Saekhan, F. Bahfie et al., Effect of binary basicity (CaO/SiO2) on selective reduction of lateritic nickel ore. Periodico di Mineralogia 90(2), 239–245 (2021). https://doi.org/10.13133/2239-1002/17045
F.K. Crundwell, M.S. Moats, V. Ramachandran et al., Chapter 6-Smelting of laterite ores to ferronickel. in: Extractive metallurgy of nickel, cobalt and platinum group metals, (2011), pp. 67–83. https://doi.org/10.1016/B978-0-08-096809-4.10006-1
M.S. Moats, W.G. Davenport, Nickel and cobalt production. Treatise Process Metall 3, 625–669 (2014). https://doi.org/10.1016/B978-0-08-096988-6.00026-2
G. Hang, Z. Xue, J. Wang, Y. Wu, Mechanism of calcium sulphate on the aggregation and growth of ferronickel particles in the self-reduction of saprolitic nickel laterite ore. Metals 10, 423 (2020). https://doi.org/10.3390/MET10040423
L.-Y. Tian, H. Levämäki, O. Eriksson et al., Density functional theory description of the order-disorder transformation in Fe–Ni. Sci. Rep. 9(1), 1–7 (2019). https://doi.org/10.1038/s41598-019-44506-7
S. Ueki, Y. Mine, K. Takashima, Excellent mechanical properties of taenite in meteoric iron. Sci. Rep. 11(1), 1–8 (2021). https://doi.org/10.1038/s41598-021-83792-y
J. Luo, G. Li, M. Rao et al., Control of slag formation in the electric furnace smelting of ferronickel for an energy-saving production. J. Clean. Prod. 287, 125082 (2021). https://doi.org/10.1016/J.JCLEPRO.2020.125082
F. Nurjaman, I. Amely, W. Astuti, B. Suharno, The effect of ternary basicity (CaO/(Al2O3 + SiO2)) on selective reduction of limonitic nickel ore. Adv. Mater. Process. Technol. 1–11 (2021). https://doi.org/10.1080/2374068X.2021.1949539
M. Meraikib, Activity of silica in the slag of an electric arc furnace using direct reduced iron for steelmaking. ISIJ Int. 35, 845–850 (1995). https://doi.org/10.2355/ISIJINTERNATIONAL.35.845
A. Babich, D. Senk, H.W. Gudenau, K.T. Mavrommatis, Ironmaking (Textbook) (RWTH Aachen University, Department of Ferrous Metallurgy, Wissenschaftsverlag Mainz in Aachen, 2008)
Y.S. Lee, D.J. Min, S.M. Jung, S.H. Yi, Influence of basicity and FeO content on viscosity of blast furnace type slags containing FeO. ISIJ Int. 44, 1283–1290 (2004). https://doi.org/10.2355/ISIJINTERNATIONAL.44.1283
K.C. Mills, L. Yuan, R.T. Jones, Estimating the physical properties of slags. J. South. Afr. Inst. Min. Metall. 111(10), 649–658 (2011). http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S2225-62532011001000002&lng=en&tlng=en. Retrieved 17 Feb 2021
K.C. Mills, Slag Atlas, VDEh, 2nd edn. (Verlag Stahleisen GmbH, Düsseldorf, 1995)
Acknowledgements
The authors express sincere gratitude to the Ministry of Education, Culture, Research and Technology Republic of Indonesia for the financial funding of this research through Penelitian Terapan Scheme (3/AMD/E1/KP.PTNBH/2020, 1317/PKS/ITS/2020).
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This study was funded by Ministry of Education, Culture, Research and Technology Republic of Indonesia (3/AMD/E1/KP.PTNBH/2020, 1317/PKS/ITS/2020).
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Pintowantoro, S., Panggabean, P.C., Setiyorini, Y. et al. Smelting and Selective Reduction of Limonitic Laterite Ore in Mini Blast Furnace. J. Inst. Eng. India Ser. D 103, 591–600 (2022). https://doi.org/10.1007/s40033-022-00348-8
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DOI: https://doi.org/10.1007/s40033-022-00348-8