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Adsorptive removal of pharmaceuticals and personal care products from aqueous solutions by chemically treated fly ash

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Abstract

This study investigated the removal efficiency of pharmaceuticals from aqueous solutions supported on chemically treated fly ash. The coal fly ash was supplied by the electric power station in Krakow, Poland. There are plenty of studies showing the utilization of fly ash as a low-cost adsorbent for wastewater containing heavy metals or dyes. Adsorption and immobilization of pharmaceuticals and personal care products on fly ash is a relatively new method but it is a very promising one. In this study, the adsorptive removal of diclofenac, ketoprofen, carbamazepine, bezafibrate, bisphenol A, 17α-ethinyl estradiol and estriol by HCl- and NaOH-treated fly ash was assessed. Chemical treatment of fly ash changed structures of particles and enhanced specific surface areas. HCl-treated fly ash was characterized by the highest BET specific surface area 47.9 m2 g−1 and unburned carbon content 8.1%. Isotherms for all compounds except for 17α-ethinyl estradiol (EE2) and estriol (E3) were linear. Higher linear regression coefficients (R 2) obtained for isotherms of EE2 and E3 show that the Freundlich model better describes their sorption. Adsorption coefficients K d varied between 109.5 (L kg−1) for bisphenol A and 471.5 (L kg−1) for bezafibrate. Freundlich constants (K F) for EE2 and E3 were 62.3 and 119.9 (µg1−1/nL1/nkg−1), respectively. Acid treatment of fly ash increased adsorption of diclofenac, ketoprofen, carbamazepine, bezafibrate and bisphenol A. Comparison of the octanol–water partitioning coefficients (log K OW) with the partitioning coefficients normalized on unburned carbon content (log K UC) revealed similarities but no strong correlation. The increasing of unburned carbon increased sorption of compounds to fly ash.

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References

  • Ahmed ZT (2012) The quantification of the fly ash adsorption capacity for the purpose of characterization and use in concrete. Dissertation. Michigan Technological University

  • Ahmed MB, Zhou JL, Ngo HH, Guo W, Thomaidis NS, Xu J (2017) Progress in the biological and chemical treatment technologies for emerging contaminant removal from wastewater: a critical review. J Hazard Mater 323, Part A:274-298

  • Ali I, Asim M, Khan TA (2012) Low cost adsorbents for the removal of organic pollutants from wastewater. J Environ Manag 113:170–183

    Article  CAS  Google Scholar 

  • Banerjee S, Sharma GC, Chattopadhyaya MC, Sharma YC (2014) Kinetic and equilibrium modeling for the adsorptive removal of methylene blue from aqueous solutions on of activated fly ash (AFSH). J Environ Chem Eng 2:1870–1880

    Article  CAS  Google Scholar 

  • Cretescu I, Soreanu G, Harja M (2015) A low-cost sorbent for removal of copper ions from wastewaters based on sawdust/fly ash mixture. Int J Environ Sci Technol 12:1799–1810

    Article  CAS  Google Scholar 

  • Czuma N, Zarębska K, Baran P (2016) Analysis of the influence of fusion synthesis parameters on the SO2 sorption properties of zeolites produced out of fly ash. In: E3S Web conf, vol 10, p 00010

  • Dutta BK, Khanra S, Mallick D (2009) Leaching of elements from coal fly ash: assessment of its potential for use in filling abandoned coal mines. Fuel 88:1314–1323

    Article  CAS  Google Scholar 

  • Franus W, Wdowin M, Franus M (2014) Synthesis and characterization of zeolites prepared from industrial fly ash. Environ Monit Assess 186:5721–5729

    Article  CAS  Google Scholar 

  • Ganiyu SO, van Hullebusch ED, Cretin M, Esposito G, Oturan MA (2015) Coupling of membrane filtration and advanced oxidation processes for removal of pharmaceutical residues: a critical review. Sep Purif Technol 156, Part 3:891–914

  • Garcia-Rodríguez A, Matamoros V, Fontàs C, Salvadó V (2015) The influence of Lemna sp. and Spirogyra sp. on the removal of pharmaceuticals and endocrine disruptors in treated wastewaters. Int J Environ Sci Technol 12:2327–2338

    Article  Google Scholar 

  • Golbad S, Khoshnoud P, Abu-Zahra N (2017) Hydrothermal synthesis of hydroxy sodalite from fly ash for the removal of lead ions from water. Int J Environ Sci Technol 14:135–142

    Article  CAS  Google Scholar 

  • Huo P, Lu Z, Wang H, Pan J, Li H, Wu X, Huang W, Yan Y (2011) Enhanced photodegradation of antibiotics solution under visible light with Fe2+/Fe3+ immobilized on TiO2/fly-ash cenospheres by using ions imprinting technology. Chem Eng J 172:615–622

    Article  CAS  Google Scholar 

  • Izquierdo M, Querol X (2012) Leaching behaviour of elements from coal combustion fly ash: an overview. Int J Coal Geol 94:54–66

    Article  CAS  Google Scholar 

  • Kim AG, Kazonich G, Dahlberg M (2003) Relative solubility of cations in class F fly ash. Environ Sci Technol 37:4507–4511

    Article  CAS  Google Scholar 

  • Krzyżanowski A, Zarębska K, Baran P (2016) Effect of Li+ stabilization on smectite intercalate properties. Colloid J 78:331–334

    Article  Google Scholar 

  • Kusmierek K, Zarebska K, Swiatkowski A (2016) Hard coal as a potential low-cost adsorbent for removal of 4-chlorophenol from water. Water Sci Technol 73:2025–2030

    Article  CAS  Google Scholar 

  • Madzivire G, Gitari WM, Vadapalli VRK, Petrik LF (2015) Jet loop reactor application for mine water treatment using fly ash, lime and aluminium hydroxide. Int J Environ Sci Technol 12:173–182

    Article  CAS  Google Scholar 

  • Mofarrah A, Husain T, Bottaro C (2014) Characterization of activated carbon obtained from Saudi Arabian fly ash. Int J Environ Sci Technol 11:159–168

    Article  CAS  Google Scholar 

  • Nachiappan S, Gopinath KP (2015) Treatment of pharmaceutical effluent using novel heterogeneous fly ash activated persulfate system. J Environ Chem Eng 3:2229–2235

    Article  CAS  Google Scholar 

  • Nielsen L, Bandosz TJ (2016) Analysis of the competitive adsorption of pharmaceuticals on waste derived materials. Chem Eng J 287:139–147

    Article  CAS  Google Scholar 

  • Nosek K, Styszko K, Gołaś J (2014) Combined method of solid-phase extraction and GC–MS for determination of acidic, neutral, and basic emerging contaminants in wastewater (Poland). Int J Anal Environ Chem 94:961–974

    Article  CAS  Google Scholar 

  • Opriş O, Soran ML, Lung I, Truşcă MRC, Szoke-Nagy T, Coman C (2017) The optimization of the antibiotics extraction from wastewaters and manure using Box–Behnken experimental design. Int J Environ Sci Technol 14:473–480

    Article  Google Scholar 

  • Pal A, He Y, Jekel M, Reinhard M, Gim KY-H (2014) Emerging contaminants of public health significance as water quality indicator compounds in the urban water cycle. Environ Int 71:46–62

    Article  CAS  Google Scholar 

  • Papageorgiou M, Kosma C, Lambropoulou D (2016) Seasonal occurrence, removal, mass loading and environmental risk assessment of 55 pharmaceuticals and personal care products in a municipal wastewater treatment plant in Central Greece. Sci Total Environ 543, Part A:547–569

  • Pengthamkeerati P, Satapanajaru T, Chularuengoaksorn P (2008) Chemical modification of coal fly ash for the removal of phosphate from aqueous solution. Fuel 87:2469–2476

    Article  CAS  Google Scholar 

  • Sarbak Z, Kramer-Wachowiak M (2002) Porous structure of waste fly ashes and their chemical modifications. Powder Technol 123:53–58

    Article  CAS  Google Scholar 

  • Sharma A, Srivastava K, Devra V, Rani A (2012) Modification in properties of fly ash through mechanical and chemical activation. Am Chem Sci J 2:177–187

    Article  CAS  Google Scholar 

  • Styszko K, Drobniak A (2015) Adsorption potential of fly ash for xenobiotics removal from water solutions. Ochrona Środowiska 37:25–31

    Google Scholar 

  • Styszko K, Nosek K, Motak M, Bester K (2015) Preliminary selection of clay minerals for the removal of pharmaceuticals, bisphenol A and triclosan in acidic and neutral aqueous solutions. C R Chim 18:1134–1142

    Article  CAS  Google Scholar 

  • Styszko K, Dudarska A, Zuba D (2016) The presence of stimulant drugs in wastewater from Krakow (Poland): a snapshot. Bull Environ Contam Toxicol 97:310–315

    Article  CAS  Google Scholar 

  • Styszko-Grochowiak K, Gołaś J, Jankowski H, Koziński S (2004) Characterization of the coal fly ash for the purpose of improvement of industrial on-line measurement of unburned carbon content. Fuel 83:1847–1853

    Article  CAS  Google Scholar 

  • Swarcewicz MK, Sobczak J, Pazdzioch W (2013) Removal of carbamazepine from aqueous solution by adsorption on fly ash-amended soil. Water Sci Technol 67:1396–1402

    Article  CAS  Google Scholar 

  • Schwarzenbach RP, Gschwend PM, Imboden DM (2003) Environmental organic chemistry. Wiley, New York

  • Ternes TA, Meisenheimer M, McDowell D, Sacher F, Brauch H-J, Haist-Gulde B, Preuss G, Wilme U, Zulei-Seibert N (2002) Removal of pharmaceuticals during drinking water treatment. Environ Sci Technol 36:3855–3863

    Article  CAS  Google Scholar 

  • Wdowin M, Franus M, Panek R, Badura L, Franus W (2014) The conversion technology of fly ash into zeolites. Clean Technol Environ Policy 16:1217–1223

    Article  CAS  Google Scholar 

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Acknowledgement

This work was financed by AGH University Grant No. 11.11.210.374.

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Authors and Affiliations

  1. Faculty of Energy and Fuels, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059, Krakow, Poland

    K. Styszko, J. Szczurowski, N. Czuma, D. Makowska & Ł. Uruski

  2. Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, 1060, Vienna, Austria

    M. Kistler

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  1. K. Styszko
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  2. J. Szczurowski
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  3. N. Czuma
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  4. D. Makowska
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  5. M. Kistler
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  6. Ł. Uruski
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Correspondence to K. Styszko.

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Editorial responsibility: Ta Yeong Wu.

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Styszko, K., Szczurowski, J., Czuma, N. et al. Adsorptive removal of pharmaceuticals and personal care products from aqueous solutions by chemically treated fly ash. Int. J. Environ. Sci. Technol. 15, 493–506 (2018). https://doi.org/10.1007/s13762-017-1415-y

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  • DOI: https://doi.org/10.1007/s13762-017-1415-y

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