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Synthesis, characterization and application of nitrogen–sulfur-doped carbon spheres as an efficient catalyst for the preparation of novel α-aminophosphonates

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Abstract

Nitrogen–sulfur-doped carbon spheres (NS-CSs) were prepared from sucrose and thiourea through a simple hydrothermal process. NS-CSs were characterized by TEM, FTIR, TGA, XRD, Raman spectroscopy and elemental analyses. The results revealed that the synthesized carbon spheres have an amorphous structure with diameters of 300–500 nm. The microspherical carbon catalyst that is recyclable has been used in the synthesis of α-aminophosphonates derived from 2-aminobenzothiazoles. Three-component reaction was performed between 2-aminobenzothiazoles, aromatic aldehydes and trimethyl phosphite in the presence of NS-CSs as microorganocatalyst at 50 °C under solvent-free conditions in high yield.

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Acknowledgements

The authors gratefully acknowledge the partial support of this study by Ferdowsi University of Mashhad Research Council (Grant No. 37992).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, 91775-1436, Mashhad, Iran

    Mina Taheri-Torbati, Hossein Eshghi, Ali Shiri & Mahdi Mirzaei

  2. Department of Materials Engineering, Birjand University of Technology, 9719866981-236, Birjand, Iran

    Seyyed Amin Rounaghi

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  1. Mina Taheri-Torbati
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  2. Hossein Eshghi
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  3. Seyyed Amin Rounaghi
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  4. Ali Shiri
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Correspondence to Hossein Eshghi.

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Taheri-Torbati, M., Eshghi, H., Rounaghi, S.A. et al. Synthesis, characterization and application of nitrogen–sulfur-doped carbon spheres as an efficient catalyst for the preparation of novel α-aminophosphonates. J IRAN CHEM SOC 14, 1971–1982 (2017). https://doi.org/10.1007/s13738-017-1135-8

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  • DOI: https://doi.org/10.1007/s13738-017-1135-8

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