Skip to main content
Log in

Pure ultraviolet emission from ZnO quantum dots-based/GaN heterojunction diodes by MgO interlayer

  • Published:
Electronic Materials Letters Aims and scope Submit manuscript

Abstract

We demonstrate the fabrication and characterization of ZnO/GaN-based heterojunction light-emitting diodes (LEDs) by using air-stable and solution-processable ZnO quantum dots (QDs) with a thin MgO interlayer acting as an electron blocking layer (EBL). The ZnO QDs/MgO/p-GaN heterojunction can only display electroluminescence (EL) characteristic in reverse bias regime. Under sufficient reverse bias, a fairly pure ultraviolet EL emission located at 370 nm deriving from near band edge of ZnO with a full width at half maximum (FWHM) of 8.3 nm had been obtained, while the deep-level emission had been almost totally suppressed. The EL origination and corresponding carrier transport mechanisms were investigated qualitatively in terms of photoluminescence (PL) results and energy band diagram.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L. Qian, Y. Zheng, J. G. Xue, and P. H. Holloway, Nat. Photonics 5, 543 (2011).

    Article  Google Scholar 

  2. Y. Shirasaki, G. J. Supran, M. G. Bawendi, and V. Bulovic, Nat. Photonics 7, 13 (2013).

    Article  Google Scholar 

  3. D. I. Son, B. W. Kwon, D. H. Park, W. S. Seo, Y. J. Yi, B. Angadi, C. L. Lee, and W. K. Choi, Nat. Nanotechnol. 7, 465 (2012).

    Article  Google Scholar 

  4. J. Kwak, W. K. Bae, D. Lee, I. Park, J. Lim, M. Park, H. Cho, H. Woo, D. Yoon, K. Char, S. Lee, and C. Lee, Nano Lett. 12, 2362 (2012).

    Article  Google Scholar 

  5. X. Dai, Z. Zhang, Y. Jin, Y. Niu, H. Cao, X. Liang, L. Chen, J. Wang, and X. Peng, Nature 515, 96 (2014).

    Article  Google Scholar 

  6. Z. Tan, Y. Zhang, C. Xie, H. Su, J. Liu, C. Zhang, N. Dellas, S. E. Mohney, Y. Wang, J. Wang, and J. Xu, Adv. Mater. 23, 3553 (2011).

    Article  Google Scholar 

  7. X. Yang, D. Zhao, K. S. Leck, T. Tan, Y. X. Tang, J. Zhao, H. Demir, and X. W. Sun, Adv. Mater. 24, 4180 (2012).

    Article  Google Scholar 

  8. Y. Zhang, C. Xie, H. Su, J. Liu, S. Pickering, Y. Wang, W. Yu, J. Wang, Y. Wang, J. Hahm, N. Dellas, S. E. Mohney, and J. Xu, Nano Lett. 11, 329 (2011).

    Article  Google Scholar 

  9. K. Lee, J. Lee, W. Song, H. Ko, C. Lee, J. Lee, and H. Yang, ACS Nano 7, 7295 (2013).

    Article  Google Scholar 

  10. W. Song and H. Yang, Appl. Phys. Lett. 100, 183104 (2012).

    Article  Google Scholar 

  11. Y. Yang, Y. Zheng, W. Cao, A. Titov, J. Hyvonen, J. Manders, J. Xue, P. H. Holloway, and L. Qian, Nat. Photonics 9, 259 (2015).

    Google Scholar 

  12. H. Shen, S. Wang, H. Wang, J. Niu, L. Qian, Y. Yang, A. Titov, J. Hyvonent, Y. Zheng, and L. S. Ling, ACS Appl. Mater. Inter. 5, 4260 (2013).

    Google Scholar 

  13. Y. L. Kong, L. A. Tamargo, H. Kim, B. N. Johnson, M. K. Gupta, T. Koh, H. Chin, D. A. Steingart, B. P. Rand, and M. C. Mcalpine, Nano Lett. 14, 7017 (2014).

    Article  Google Scholar 

  14. B. Kwon, K. G. Lee, T. J. Park, H. Kim, T. J. Lee, S. J. Lee, and D. Y. Jeon, Small 8, 3257 (2012).

    Article  Google Scholar 

  15. E. Jang, S. Jun, H. Jang, J. Lim, B. Kim, and Y. Kim, Adv. Mater. 22, 3076 (2010).

    Article  Google Scholar 

  16. L. Y. Chang, R. R. Lunt, P. R. Brown, V. Bulovic, and M. G. Bawendi, Nano Lett. 13, 994 (2013).

    Article  Google Scholar 

  17. T. H. Kim, K. S. Cho, E. K. Lee, S. J. Lee, J. Chae, J. W. Kim, J. Y. Kwon, G. Amaratunga, S. Y. Lee, and B. L. Choi, Nat. Photonics 5, 176 (2011).

    Article  Google Scholar 

  18. E. M. Likovich, R. Jaramillo, K. J. Russell, S. Ramanathan, and V. Narayanamurti, Adv. Mater. 23, 4521 (2011).

    Article  Google Scholar 

  19. L. Y. Chang, R. R. Lunt, P. R. Brown, V. Bulovic, and M. G. Bawendi, Nano Lett. 13, 994 (2013).

    Article  Google Scholar 

  20. G. J. Supran, K. W. Song, G. W. Hwang, R. E. Correa, J. Scherer, E. A. Dauler, Y. Shirasaki, and M. G. Bawendi, Adv. Mater. 27, 1437 (2015).

    Article  Google Scholar 

  21. Q. Lin, H. Shen, H. Wang, A. Wang, J. Niu, L. Qian, F. Guo, and L. S. Li, Org. Electron. 25, 178 (2015).

    Article  Google Scholar 

  22. Q. Qiao, B. H. Li, C. X. Shan, J. S. Liu, J. Yu, X. H. Xie, Z. Z. Zhang, T. B. Ji, Y. Jiac, and D. Z. Shen, Mater. Lett. 74, 104 (2012).

    Article  Google Scholar 

  23. T. Omata, Y. Tani, S. Kobayashi, K. Takahashi, A. Miyanaga, Y. Maeda, and S. Otsuka-Yao-Matsuo, Appl. Phys. Lett. 100, 061104 (2012).

    Article  Google Scholar 

  24. J. B. You, X. W. Zhang, S. G. Zhang, J. X. Wang, Z. G. Yin, H. R. Tan, W. J. Zhang, P. K. Chu, B. Cui, A. M. Wowchak, A. M. Dabiran, and P. P. Chow, Appl. Phys. Lett. 96, 201102 (2010).

    Article  Google Scholar 

  25. H. Zhu, C. X. Shan, B. Yao, B. H. Li, J. Y. Zhang, Z. Z. Zhang, D. X. Zhao, D. Z. Shen, X. W. Fan, and Y. M. Lu, Adv. Mater. 21, 1613 (2009).

    Article  Google Scholar 

  26. G. Y. Zhu, J. T. Li, Z. L. Shi, Y. Lin, G. F. Chen, T. Ding, Z. S. Tian, and C. X. Xu, Appl. Phys. B: Lasers. Opt. 109, 195 (2012).

    Article  Google Scholar 

  27. H. Chen, Appl. Phys. Lett. 102, 162106 (2013).

    Article  Google Scholar 

  28. Y. Wang, N. Liu, Y. Chen, C. Yang, W. Liu, J. Su, L. Li, and Y. Gao, RSC Adv. 5, 104386 (2015).

    Article  Google Scholar 

  29. T. Toyama, H. Takeuchi, D. Yamaguchi, H. Kawasaki, K. Itatani, and H. Okamoto, J. Appl. Phys. 108, 084302 (2010).

    Article  Google Scholar 

  30. X. Mo, H. Long, H. Wang, S. Li, Z. Chen, J. Wan, Y. Feng, Y. Liu, Y. Ouyang, and G. Fang, Appl. Phys. Lett. 105, 063505 (2014).

    Article  Google Scholar 

  31. H. C. Chen, M. J. Chen, Y. H. Huang, W. C. Sun, W. C. Li, J. R. Yang, H. Kuan, and M. Shiojiri, IEEE. T. Electron. Dev. 58, 3970 (2011).

    Article  Google Scholar 

  32. W. Park and G. Yi, Adv. Mater. 16, 87 (2004).

    Article  Google Scholar 

  33. X. Mo, G. Fang, H. Long, S. Li, H. Huang, H. Wang, Y. Liu, X. Meng, Y. Zhang, and C. Pan, J. Lumin. 137, 116 (2013).

    Article  Google Scholar 

  34. A. Z. Mariano, B. Jiming, S. Ilan, Y. Wei, N. Venkatesh, and C. Federico, Nanotechnology 18, 395201 (2007).

    Article  Google Scholar 

  35. A. Z. Mariano, B. Jiming, S. Ilan, Y. Wei, Y. Joonah, N. Venkatesh, and C. Federico, Nanotechnology 18, 235205 (2007).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiangnan Dai.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, C., Liang, R., Chen, J. et al. Pure ultraviolet emission from ZnO quantum dots-based/GaN heterojunction diodes by MgO interlayer. Electron. Mater. Lett. 13, 313–317 (2017). https://doi.org/10.1007/s13391-017-6234-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13391-017-6234-2

Keywords

Navigation