Skip to main content
Log in

Characterization of curing behavior of UV-curable LSR for LED embedded injection mold

  • Articles
  • Published:
Korea-Australia Rheology Journal Aims and scope Submit manuscript

Abstract

For many applications, liquid silicone rubber (LSR) injection molding is widely used for their great design flexibility and high productivity. In particular, a sealing part for a mobile device such as smartphone and watch has been produced by injection molding. While thermally curable LSR causes deformation problem due to a high mold temperature, UV-curable LSR can be molded at room temperature, which has advantages for over-molding with inserts of temperature-sensitive materials. Ultraviolet light-emitting diodes (UV LEDs) have advantages such as a longer service life, a lower heat dissipation, and smaller size to equip into the mold than conventional halogen or mercury UV lamps. In this work, rheological behavior of UV-curable LSR during curing process was analyzed by UV LEDs available in the market. UV-LEDs of various wave lengths and intensities were tested. The steady shear test was applied to find the starting time of curing and the SAOS was applied to find the ending time of curing to estimate processing time. In addition, the hardness change with irradiation energy was compared with the rheological data to confirm the reliability of the rheological test.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Cheng, K.C., W.Y. Chiu, K.H. Hsieh, and C.C.M. Ma, 1994, Chemorheology of epoxy resin, J. Mater. Sci. 29, 887–893.

    Article  Google Scholar 

  • Cui, T., Y.J. Chao, and J.W. Van Zee, 2014, Sealing force prediction of elastomeric seal material for PEM fuel cell under temperature cycling, Int. J. Hydrog. Energy 39, 1420–1438.

    Article  Google Scholar 

  • Cui, T., Y.J. Chao, X.M. Chen, and J.W. Van Zee, 2011, Effect of water on life prediction of liquid silicone rubber seals in polymer electrolyte membrane fuel cell, J. Power Sources 196, 9536–9543

    Article  Google Scholar 

  • Ganter, B., 2013, Putting silicone rubbers into a new light, Rubber World 248, 26–30.

    Google Scholar 

  • Ganter, B., S. Boßhammer, and U. Irmer, 2013, UV-curable sil-icone rubbers open up new fields, Int. Polym. Sci. Technol. 40, 1–4.

    Google Scholar 

  • Halley, P.J. and M.E. Mackay, 1996, Chemorheology of thermosets -an overview, Polym. Eng. Sci. 35, 593–635.

    Article  Google Scholar 

  • Hwang, J.W., K.N. Kim, G.S. Lee, J.H. Nam, S.M. Noh, and H.W. Jung, 2013, Rheology and curing characteristics of dualcurable automotive clear coats using thermal radical initiator derived from O-imino-isourea and photo-initiator, Prog. Org. Coat. 76, 1666–1673.

    Article  Google Scholar 

  • Kil, G.S., S.K. Choi, D.W. Park, S.W. Kim, and S.G. Cheon, 2009, Analysis of disinfection performance of UV LEDs for a phytoplankton, J. Korean Soc. Mar. Eng. 33, 959–964.

    Article  Google Scholar 

  • Leopold, P.M., 2003, Nanomolding of silicone rubber parts and inserts in thermoplastic, Proc. ANTEC2013, Nashville, USA, 2587–2592.

    Google Scholar 

  • Na, H.Y., H.Y. Yeom, B.C. Yoon, and S.J. Lee, 2014, Cure behavior and chemorheology of low temperature cure epoxy matrix resin, Polym. Korea 38, 171–179.

    Article  Google Scholar 

  • Ryoo, J.H., I.B. Lee, H.M. Yoo, M.J. Kim, C.I. Seok, and H.C. Kwon, 2004, The polymerization rate and the degree of conversion of composite resins by different light sources, J. Korean Acad. Conserv. Dent. 29, 386–398.

    Article  Google Scholar 

  • Tae, J.S., B.O. Rhee, and S.H. Lee, 2010, Rheological characterization for the gelation process of polyaniline-emeraldine base/NMP solution by oscillatory test, Korea-Aust. Rheol. J. 22, 273–278.

    Google Scholar 

  • Toub, M., 2011, UV cured silicone elastomers: A new approach to silicone rubber fabrication, Medical Silicone Conference, 2011, Framingham, Massachusetts.

    Google Scholar 

  • Wang, Y.F., S. Boßhammer, and H. Albrecht, 2010, Silicone & medical update: UV cure technology for high speed silicone rubber extrusion and for LSR molding, Rubber World 241, 13–14.

    Google Scholar 

  • Winter, H.H. and F. Chambon, 1986, Analysis of linear viscoelasticity of a crosslinking polymer at the gel point, J. Rheol. 30, 367–382.

    Article  Google Scholar 

  • Wolf, H.P., 2013, Advances in fluorosilicone elastomers: Sustainable automotive innovation, Rubber World 248, 30–32.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Byung-Ohk Rhee.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tae, JS., Yim, KG., Rhee, BO. et al. Characterization of curing behavior of UV-curable LSR for LED embedded injection mold. Korea-Aust. Rheol. J. 28, 247–253 (2016). https://doi.org/10.1007/s13367-016-0026-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13367-016-0026-3

Keywords

Navigation