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Stabilization of Metastable States Generated via an Affordable Mechanochemical Route for Functional Nanocomposites

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Abstract

This short review introduces recent preparative processes of functional nanocomposites via mechanochemical routes. Three case-studies published by the present author and his colleagues are centered, i.e., (i) amorphization of molecular crystals to the state of molecular dispersion for pharmaceutics, (ii) nano-glassy and nano-crystalline complex oxides for electromagnetic applications by changing conditions of mechanical stressing and subsequent thermal relaxation, and (iii) double perovskite synthesis with high structural defects for multiferroic and spintronic applications. Mechanisms of apparent stabilization of intrinsically metastable products are discussed. Some remarks are given toward affordable material processing, irreplaceable by other nonconventional chemical processes. Conclusions are given at the end with a look into the near future.

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Acknowledgements

The author sincerely thanks the coworkers appeared in the case studies introduced, among others, Dr. Tomoyuki Watanabe (Daiichi Sankyo Company, Limited), Dr. Vladimir Šepelák (Institute of Nanotechnology, Karlsruhe Institute of Technology) and Dr. Erika Tóthová (Institute of Geotechnics, SAS).

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  1. Faculty of Science and Technology, Keio University, Yokohama, Japan

    Mamoru Senna

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Senna, M. Stabilization of Metastable States Generated via an Affordable Mechanochemical Route for Functional Nanocomposites. Trans Indian Inst Met (2023). https://doi.org/10.1007/s12666-023-03075-0

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