Abstract
With generation of waste plastics increasing, current EU legislation dictates high recovery rates and policy favours waste management technology choices that occupy a high position on the waste management hierarchy. Pyrolysis is a thermochemical conversion technology that can be considered a ‘feedstock recycling’ process and may play an increasing role in integrated waste management systems of the future. The objective of this article is to present a review of current state-of-the-art commercial pyrolysis processes for the production of liquid transport fuels from waste polyolefins (polyethylenes and polypropylenes). Current plastic waste generation and management practices are briefly summarised. Waste management infrastructure in Europe is reliant on landfill, incineration and mechanical recycling, while feedstock recycling plays an insignificant role. Plastic-to-liquid platforms including delocalised pyrolysis followed by centralised upgrading, stand alone facilities, and integrated waste management infrastructure concepts are briefly discussed. Commercial operations and their process configurations are compared. Reactor technology for cracking of plastic waste is presented. Important issues like fuel quality and contamination are also discussed. Fuel finishing operations and fuel additives required to achieve an engine ready fuel are described in the final section. Recently published laboratory research in thermal and catalytic pyrolysis and integrated and co-processing studies are also summarised in this review.
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References
APME: The compelling facts about plastics 2009: an analysis of European plastics production, demand and recovery for 2008. Association of Plastics Manufacturers Europe, Brussels (2009)
Nzihou, A.: Waste and biomass valorization. Waste Biomass Valoriz. 1(1), 1–2 (2010). doi:10.1007/s12649-010-9013-y
Moore, C.J.: Synthetic polymers in the marine environment: a rapidly increasing, long-term threat. Environ. Res. 108(2), 131–139 (2008)
WRAP: The Chinese markets for recovered paper and plastics. Waste and Resources Action Program, Oxan, UK (2009)
Buekens, A.: Introduction to feedstock recycling of plastics. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 1–41. Wiley, New York (2006)
Fukushima, M., Wu, B., Ibe, H., Wakai, K., Sugiyama, E., Abe, H., Kitagawa, K., Tsuruga, S., Shimura, K., Ono, E.: Study on dechlorination technology for municipal waste plastics containing polyvinyl chloride and polyethylene terephthalate. J. Mater. Cycles Waste Manag. 12(2), 108–122 (2010)
Manos, G.: Catalytic degradation of plastic waste to fuel over microporous materials. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 193–207. Wiley, New York (2006)
Scheirs, J.: Overview of commercial pyrolysis processes for waste plastics. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 381–433. Wiley, New York (2006)
Stelmachowski, M.: Thermal conversion of waste polyolefins to the mixture of hydrocarbons in the reactor with molten metal bed. Energy Convers. Manag. 51(10), 2016–2024 (2010)
Chenier, P.J.: Survey of Industrial Chemistry, 3rd edn. Kluwer Academic/Plenum Publishers, New York (2002)
DB: Oil and Gas for Beginners. Deutsche Bank AB, London (2010)
Ray, R., Thorpe, R.B.: A Comparison of gasification with pyrolysis for the recycling of plastic containing wastes. Int. J. Chem. React. Eng. 5(A85), 1–14 (2007)
Aguado, J., Serrano, D.P.: Feedstock Recycling of Plastic Waste. The Royal Society of Chemistry, Cambridge, UK (1999)
UNEP: Converting waste plastics into a resource. Compendium of technologies. United Nations Environmental Programme, Osaka/Shiga, Japan (2009)
Achilias, D.S., Antonakou, E., Roupakias, C., Megalokonomos, P., Lappas, A.: Recycling techniques of polyolefins from plastic wastes. Global Nest J. 10(1), 114–122 (2008)
Panda, A.K., Singh, R.K., Mishra, D.K.: Thermolysis of waste plastics to liquid fuel: a suitable method for plastic waste management and manufacture of value added products-A world prospective. Renew. Sustain. Energy Rev. 14(1), 233–248 (2009)
ACCR: Good practice guide on waste plastics recycling: a guide by and for local and regional authorities. Association of Cities and Regions for Recycling, Brussels, Belgium (2004)
Minister for the Environment and Local Government: Changing our Ways. Department of the Environment and Local Government, Dublin, Ireland (1998)
Forfás: Waste Management in Ireland: Benchmarking Analysis and Policy Priorities. Forfás, Dublin, Ireland (2009)
DEHLG: Waste Management. Taking Stock and Moving Forward. Department of the Environment Heritage and Local Government, Dublin (2004)
Al-Salem, S.M., Lettieri, P., Baeyens, J.: Recycling and recovery routes of plastic solid waste (PSW): a review. Waste Manage. 36(1), 103–129 (2009)
Aguado, J., Serrano, D.P., Escola, J.M.: Fuels from waste plastics by thermal and catalytic processes: a review. Ind. Eng. Chem. Res. 47(21), 7982–7992 (2008)
Aguado, J., Serrano, D.P., San Miguel, G.: European trends in the feedstock recycling of plastic wastes. Global NEST J. 9(1), 12–19 (2007)
Keane, M.A.: Catalytic transformation of waste polymers to fuel oil. ChemSusChem 2(3), 207–214 (2009)
Castaldi, M., Themelis, N.: The case for increasing the global capacity for waste to energy (WTE). Waste Biomass Valoriz 1(1), 91–105 (2010)
Psomopoulos, C.S., Bourka, A., Themelis, N.J.: Waste-to-energy: a review of the status and benefits in USA. Waste Manage. 29(5), 1718–1724 (2009)
Themelis, N.J.: Thermal treatment review. Waste Manage. World 8(4), 40–47 (2007)
WRAP: Environmental Benefits of Recycling. An International Review of Life Cycle Comparisons for Key Materials in the UK Recycling Sector. Waste and Resources Action Program, Oxon, UK (2009)
Hiskakis, M., Briassoulis, D., Teas, C., Babou, E., Liantzas, K.: Using agricultural plastic waste (APW) as alternative solid fuel (ASF) for energy recovery in a cement industry kiln—a pilot test. In: Agricultural and Biosystems Engineering for a Sustainable World. International Conference on Agricultural Engineering, Hersonissos, Crete, Greece, 23–25 June 2008, pp. OP-320. European Society of Agricultural Engineers (AgEng)
Lagan Cement: Lagan Cement to Further Reduce Fossil Fuel use, CO2 Emissions. Lagan Cement, Westmeath, Ireland (2008)
Themelis, N.J.: Developments in thermal treatment technologies. In: Castaldi, M.J., White, M. (eds.) 16th Annual North American Waste to Energy Conference, Philadelphia, PA, 19–21 May 2008, pp. 85–92. Amer Soc Mechanical Engineers
Stehlík, P.: Contribution to advances in waste-to-energy technologies. Journal of Cleaner Production 17(10), 919–931 (2009)
Malkow, T.: Novel and innovative pyrolysis and gasification technologies for energy efficient and environmentally sound MSW disposal. Waste Manage. 24(1), 53–79 (2004)
Gomez, E., Rani, D.A., Cheeseman, C.R., Deegan, D., Wise, M., Boccaccini, A.R.: Thermal plasma technology for the treatment of wastes: a critical review. J. Hazard. Mater. 161(2–3), 614–626 (2009)
Heberlein, J., Murphy, A.B.: Thermal plasma waste treatment. J. Phys. D-Appl. Phys. 41(5), 20 (2008)
Zhang, G.-H., Zhu, J.-F., Okuwaki, A.: Prospect and current status of recycling waste plastics and technology for converting them into oil in China. Resour. Conserv. Recycl. 50(3), 231–239 (2007)
Okuwaki, A.: Feedstock recycling of plastics in Japan. Polym. Degrad. Stab. 85(3), 981–988 (2004)
Garforth, A.A., Ali, S., Hernández-Martínez, J., Akah, A.: Feedstock recycling of polymer wastes. Curr. Opin. Solid State Mater. Sci. 8(6), 419–425 (2004)
Thomé-Kozmiensky, K.J., Willnow, S., Fleischer, G., Schmidt, W.-P., Christ, C., Menges, G., Bilitwski, B., Loll, U., Gromotka, H., Amsoneit, N., Baerns, M., Majunke, F., Ehrig, H.-J., Schneider, H.-J., Gossow, V., Habashi, F.: Waste. In: Ullmann’s Encyclopedia of Industrial Chemistry. Wiley, New York (2008)
Vicente, G., Aguado, J., Serrano, D.P., Sánchez, N.: HDPE chemical recycling promoted by phenol solvent. J. Anal. Appl. Pyrol. 85(1–2), 366–371 (2009)
Miller, S.J., Shah, N., Huffman, G.P.: Conversion of waste plastic to lubricating base oil. Energy Fuels 19(4), 1580–1586 (2005)
Ali, M.F., Siddiqui, M.N.: The conversion of waste plastics/petroleum residue mixtures to transportation fuels. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock recycling and pyrolysis of waste plastics, pp. 363–380. Wiley, New York (2006)
Behzadi, S., Farid, M.: Liquid fuel from plastic wastes using extrusion-rotary kiln reactors. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 531–548. Wiley, New York (2006)
Buttker, B., Giering, R., Schlotter, U., Himmelreich, B., Wittstock, K.: Full Scale Industrial Recovery trials of shredder residue in high temperature slagging-bed-gasifier in Germany. Plastics Europe, Brussels, Belgium (2005)
Lane, J.: The lowdown on Enerkem’s landmark Edmonton advanced biofuels project. http://biofuelsdigest.com/bdigest/2010/09/01/the-lowdown-on-enerkems-landmark-edmonton-advanced-biofuels-project/ (2010). Accessed 2010/09/01
Buergeler, T.: Blast Furnace Operations. In: IdentiPlast 2009 Conference, Brussels, April 20–21 (2009)
Matsumiya, T.: Steel research and development in the aspect for a sustainable society. Scandanavian J. Metall. 34(4), 256–267 (2005)
Sekine, Y., Fukuda, K., Kato, K., Yoshihiro, A., Matsuno, Y.: CO2 reduction potentials by utilizing waste plastics in steel works. Int. J. Life Cycle Assess. 14, 122–136 (2009)
Kato, K., Nomura, S., Uematsu, H.: Waste plastics recycling process using coke ovens. J. Mater. Cycles Waste Manage. 5(2), 98–101 (2003)
Aguado, J., Serrano, D.P., Escola, J.M.: Catalytic upgrading of plastic wastes. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 73–110. Wiley, New York (2006)
Lee, K.H.: Thermal and Catalytic Degradation of Waste HDPE. Feedstock Recycling and Pyrolysis of Waste Plastics. Wiley, New York (2006)
Marcilla, A., Gómez-Siurana, A., Berenguer, D.: Study of the early deactivation in pyrolysis of polymers in the presence of catalysts. J. Anal. Appl. Pyrol. 79(1–2), 443–449 (2007)
Marcilla, A., Gómez-Siurana, A., Valdés, F.: Catalytic pyrolysis of LDPE over H-beta and HZSM-5 zeolites in dynamic conditions: study of the evolution of the process. J. Anal. Appl. Pyrol. 79(1–2), 433–442 (2007)
Venderbosch, R., Prins, W.: Fast pyrolysis technology development. Biofuels, Bioproducts Biorefining 4(2), 178–208 (2010)
Lin, Y.C., Huber, G.W.: The critical role of heterogeneous catalysis in lignocellulosic biomass conversion. Energy Environ. Sci. 2(1), 68–80 (2009)
Huber, G.W., Corma, A.: Synergies between bio- and oil refineries for the production of fuels from biomass. Angew. Chem. Int. Ed. 46(38), 7184–7201 (2007)
Miskolczi, N.: Kinetic model of the chemical and catalytic recycling of waste polyethylene into fuels. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 225–247. Wiley, New York (2006)
Yanik, J., Karayildirim, T.: Liquefaction of Municipal Waste Plastics over Acidic and Nonacidic Catalysts. Feedstock Recycling and Pyrolysis of Waste Plastics. Wiley, New York (2006)
Marcilla, A., Ruiz-Femenia, R., Hernández, J., García-Quesada, J.C.: Thermal and catalytic pyrolysis of crosslinked polyethylene. J. Anal. Appl. Pyrol. 76(1–2), 254–259 (2006)
Irion, W.W., Neuwirth, O.S.: Oil Refining. In: Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim (2005)
White, R.L.: Acid-catalyzed cracking of polyolefins: primary reaction mechanisms. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 43–72. Wiley, New York (2006)
Bhaskar, T., Sakata, Y.: Liquefaction of PVC mixed plastics. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 493–529. Wiley, New York (2006)
Bakker, E.J., Rem, P.C., Fraunholcz, N.: Upgrading mixed polyolefin waste with magnetic density separation. Waste Manage. 29(5), 1712–1717 (2009)
Bezati, F., Froelich, D., Massardier, V., Maris, E.: Addition of tracers into the polypropylene in view of automatic sorting of plastic wastes using X-ray fluorescence spectrometry. Waste Manage. 30(4), 591–596 (2010)
Carvalho, M.T., Ferreira, C., Portela, A., Santos, J.T.: Application of fluidization to separate packaging waste plastics. Waste Manage. 29(3), 1138–1143 (2009)
Yoshida, M., Nakatsukasa, S., Nanba, M., Gotoh, K., Zushi, T., Kubo, Y., Oshitani, J.: Decrease of Cl contents in waste plastics using a gas-solid fluidized bed separator. Adv. Powder Technol. 21(1), 69–74 (2010)
Shent, H., Pugh, R.J., Forssberg, E.: A review of plastics waste recycling and the flotation of plastics. Resour. Conserv. Recycl. 25(2), 85–109 (1999)
Gent, M.R., Menendez, M., Toraño, J., Isidro, D., Torno, S.: Cylinder cyclone (LARCODEMS) density media separation of plastic wastes. Waste Manage. 29(6), 1819–1827 (2009)
Lee, K.-H.: Pyrolysis of municipal plastic wastes separated by difference of specific gravity. J. Anal. Appl. Pyrol. 79(1–2), 362–367 (2007)
Bhaskar, T., Negoro, R., Muto, A., Sakata, Y.: Prevention of chlorinated hydrocarbons formation during pyrolysis of PVC or PVDC mixed plastics. Green Chem. 8(8), 697–700 (2006)
Miskolczi, N., Bartha, L., Angyal, A.: Pyrolysis of polyvinyl chloride (PVC)-containing mixed plastic wastes for recovery of hydrocarbons. Energy Fuels 23(5), 2743–2749 (2009)
Hall, W.J., Williams, P.T.: Pyrolysis of brominated feedstock plastic in a fluidised bed reactor. J. Anal. Appl. Pyrol. 77(1), 75–82 (2006)
Cho, M.-H., Jung, S.-H., Kim, J.-S.: Pyrolysis of mixed plastic wastes for the recovery of benzene, toluene, and xylene (BTX) aromatics in a fluidized bed and chlorine removal by applying various additives. Energy Fuels 24(2), 1389–1395 (2009)
Jung, S.-H., Cho, M.-H., Kang, B.-S., Kim, J.-S.: Pyrolysis of a fraction of waste polypropylene and polyethylene for the recovery of BTX aromatics using a fluidized bed reactor. Fuel Process. Technol. 91(3), 277–284 (2010)
Murata, K., Brebu, M., Sakata, Y.: The effect of PVC on thermal and catalytic degradation of polyethylene, polypropylene and polystyrene by a continuous flow reactor. J. Anal. Appl. Pyrol. 86(1), 33–38 (2009)
Zadgaonkar, A.: Process and equipment for conversions of waste plastics into fuels. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 709–728. Wiley, New York (2006)
DeWhitt, K.: System for Recycling Plastics (US 7,758,729 B1). USA Patent, 20 Jul 2010
Dabelstein, W., Reglitzky, A., Schutze, A., Reders, K.: Automotive fuels. In: Ullmann’s Encyclopedia of Industrial Chemistry. Wiley, Weinheim (2007)
Kaminsky, W.: The hamburg fluidized-bed pyrolysis process to recycle polymer wastes and tires. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 475–491. Wiley, New York (2006)
Shelley, M.D., El-Halwagi, M.M.: Techno-economic feasibility and flowsheet synthesis of scrap tire/plastic waste liquefaction. J. Elastomers Plast. 31(3), 232–254 (1999)
Kaminsky, W., Sinn, H.: Petrochemical processes for recycling plastics. In: Brandrup, J., Bittner, M., Michaeli, W., Menges, G. (eds.) Recycling and Recovery of Plastics. Hansen, Munich (1996)
Kaminsky, W., Hartmann, F.: New pathways in plastics recycling. Angew. Chem. Int. Ed. 39(2), 331–333 (2000)
Mertinkat, J., Kirsten, A., Predel, M., Kaminsky, W.: Cracking catalysts used as fluidized bed material in the Hamburg pyrolysis process. J. Anal. Appl. Pyrol. 49(1–2), 87–95 (1999)
Kaminsky, W., Zorriqueta, I.-J.N.: Catalytical and thermal pyrolysis of polyolefins. J. Anal. Appl. Pyrol. 79(1–2), 368–374 (2007)
Aguado, R., Olazar, M., Gaisan, B., Prieto, R., Bilbao, J.: Kinetic study of polyolefin pyrolysis in a conical spouted bed reactor. Ind. Eng. Chem. Res. 41(18), 4559–4566 (2002)
Aguado, R., Olazar, M., San Jose, M.J., Gaisan, B., Bilbao, J.: Wax formation in the pyrolysis of polyolefins in a conical spouted bed reactor. Energy Fuels 16(6), 1429–1437 (2002)
Elordi, G., Olazar, M., Aguado, R., Lopez, G., Arabiourrutia, M., Bilbao, J.: Catalytic pyrolysis of high density polyethylene in a conical spouted bed reactor. J. Anal. Appl. Pyrol. 79(1–2), 450–455 (2007)
Elordi, G., Olazar, M., Lopez, G., Amutio, M., Artetxe, M., Aguado, R., Bilbao, J.: Catalytic pyrolysis of HDPE in continuous mode over zeolite catalysts in a conical spouted bed reactor. J. Anal. Appl. Pyrol. 85(1–2), 345–351 (2009)
Olazar, M., Lopez, G., Amutio, M., Elordi, G., Aguado, R., Bilbao, J.: Influence of FCC catalyst steaming on HDPE pyrolysis product distribution. J. Anal. Appl. Pyrol. 85(1–2), 359–365 (2009)
Salmiaton, A., Garforth, A., Fakhru’l-Razi, A.: Recycling of polymer waste with fluid catalytic cracking catalysts. J. Environ. Sci. Health A Toxic Hazard. Subst. Environ. Eng. 41, 1145–1154 (2006)
Xingzhong, Y.: Converting waste plastics into liquid fuel by pyrolysis: developments in China. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 729–755. Wiley, New York (2006)
Zeng, G.M., Yuan, X.Z., Hu, T.J., Yan, G., Yin, Y.Y., Li, J.B.: Manufacture of liquid fuel by catalytic cracking waste plastics in a fluidized bed. Energy Sourc. 25(6), 577–590 (2003)
Westerhout, R.W.J., Kuipers, J.A.M., van Swaaij, W.P.M.: Experimental determination of the yield of pyrolysis products of polyethene and polypropene. Influence of reaction conditions. Ind. Eng. Chem. Res. 37(3), 841–847 (1998)
Westerhout, R.W.J., Waanders, J., Kuipers, J.A.M., van Swaaij, W.P.M.: Recycling of polyethene and polypropene in a novel bench-scale rotating cone reactor by high-temperature pyrolysis. Ind. Eng. Chem. Res. 37(6), 2293–2300 (1998)
Westerhout, R.W.J., Waanders, J., Kuipers, J.A.M., van Swaaij, W.P.M.: Development of a continuous rotating cone reactor pilot plant for the pyrolysis of polyethene and polypropene. Ind. Eng. Chem. Res. 37(6), 2316–2322 (1998)
Westerhout, R.W.J., Waanders, J., Kuipers, J.A.M., van Swaaij, W.P.M.: Kinetics of the low-temperature pyrolysis of polyethene, polypropene, and polystyrene modeling, experimental determination, and comparison with literature models and data. Ind. Eng. Chem. Res. 36(6), 1955–1964 (1997)
Walendziewski, J.: Thermal and catalytic conversion of polyolefins. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 111–127. Wiley, New York (2006)
Murata, K., Brebu, M., Sakata, Y.: Thermal degradation of polyethylene into fuel oil over silica-alumina by a continuous flow reactor. J. Anal. Appl. Pyrol. 86(2), 354–359 (2009)
Hornung, A., Seifert, H.: Rotary Kiln pyrolysis of polymers containing heteroatoms. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 549–567. Wiley, New York (2006)
Okuwaki, A., Yoshioka, T., Asai, M., Tachibana, H., Wakai, K., Tada, K.: The Liquefaction of Plastic Containers and Packaging in Japan. Feedstock Recycling and Pyrolysis of Waste Plastics. Wiley, New York (2006)
Walendziewski, J.: Continuous flow cracking of waste plastics. Fuel Process. Technol. 86(12–13), 1265–1278 (2005)
Serrano, D.P., Aguado, J., Escola, J.M., Garagorri, E.: Conversion of low density polyethylene into petrochemical feedstocks using a continuous screw kiln reactor. J. Anal. Appl. Pyrol. 58–59, 789–801 (2001)
Aguado, J., Serrano, D.P., Escola, J.M., Garagorri, E.: Catalytic conversion of low-density polyethylene using a continuous screw kiln reactor. Catal Today 75(1–4), 257–262 (2002)
Kodera, Y., Ishihara, Y., Kuroki, T.: Novel process for recycling waste plastics to fuel gas using a moving-bed reactor. Energy Fuels 20(1), 155–158 (2006). doi:10.1021/ef0502655
Wallis, M.D., Sarathy, S., Bhatia, S.K., Massarotto, P., Kosior, E., Mercier, A.: Catalytic degradation of high-density polyethylene in a reactive extruder. Ind. Eng. Chem. Res. 47(15), 5175–5181 (2008)
Wallis, M.D., Bhatia, S.K.: Thermal degradation of high density polyethylene in a reactive extruder. Polym. Degrad. Stab. 92(9), 1721–1729 (2007)
Miskolczi, N., Bartha, L., Deák, G., Jóver, B.: Thermal degradation of municipal plastic waste for production of fuel-like hydrocarbons. Polym. Degrad. Stab. 86(2), 357–366 (2004)
Angyal, A., Miskolczi, N., Bartha, L.: Petrochemical feedstock by thermal cracking of plastic waste. J. Anal. Appl. Pyrol. 79(1–2), 409–414 (2007)
Miskolczi, N., Bartha, L., Deák, G.: Thermal degradation of polyethylene and polystyrene from the packaging industry over different catalysts into fuel-like feed stocks. Polym. Degrad. Stab. 91(3), 517–526 (2006)
Angyal, A., Miskolczi, N., Bartha, L., Tungler, A., Nagy, L., Vida, L., Nagy, G.: Production of steam cracking feedstocks by mild cracking of plastic wastes. Fuel Process. Technol. 91(11), 1717–1724 (2010)
Miskolczi, N., SÁGi, R., Bartha, L., Forcek, L.: Utilization of [alpha]-olefins obtained by pyrolysis of waste high density polyethylene to synthesize [alpha]-olefin-succinic-anhydride based cold flow improvers. J. Fuel Chem. Technol. 37(3), 302–310 (2009)
Miskolczi, N., Angyal, A., Bartha, L., Valkai, I.: Fuels by pyrolysis of waste plastics from agricultural and packaging sectors in a pilot scale reactor. Fuel Process. Technol. 90(7–8), 1032–1040 (2009)
Angyal, A., Miskolczi, N., Bartha, L., Valkai, I.: Catalytic cracking of polyethylene waste in horizontal tube reactor. Polym. Degrad. Stab. 94(10), 1678–1683 (2009)
Dispons, J.: Continuous thermal process for cracking polyolefin wastes to produce hydrocarbons. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 595–604. Wiley, New York (2006)
Oleszkiewicz, A.: Plastic power. Waste Manage. World 9(5) (2006)
T-TechnologyTM: New generation system of plastic waste recycling. www.tokarz.pl (2007). Accessed 11 Feb 2010
Ludlow-Palafox, C., Chase, H.A.: Microwave pyrolysis of plastic wastes. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 569–594. Wiley, New York (2006)
Bilgesü, A.Y., Çetin Koçak, M., Karaduman, A.: Waste plastic pyrolysis in free-fall reactors. In: Scheirs, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 605–623. Wiley, New York (2006)
Mastral, J.F., Berrueco, C., Ceamanos, J.: Pyrolysis of high-density polyethylene in free-fall reactors in series. Energy Fuels 20(4), 1365–1371 (2006)
Mikulec, J., Vrbova, M.: Catalytic and thermal cracking of selected polyolefins. Clean Technol. Environ. Policy 10(2), 121–130 (2008)
Converting waste plastic to crude oil. www.agilyx.com (2010). Accessed 1 Nov 2010
http://www.roycobeijing.com/. Accessed 2 July 2010
We Face the Future. www.alphakat.de. Accessed 20 July 2010
http://www.reentech.co.kr. Accessed 18 Jun 2010
Anon: Press release 08 Nov 2010- SITA UK, subsidary of SUEZ ENVIRONMENT, and Cynar Plc, sign a landmark recycling technology agreement for the conversion of end of life plastic (ELP) into diesel. http://www.sita.co.uk/news-and-views/press-releases/sita-uk-subsidiary-of-suez-environnement-and-cynar (2010). Accessed 04 Feb 2011
Sing, S.: World takes note of Mumbai start-up’s waste-to-fuel tech. http://www.livemint.com/2007/11/14001417/World-takes-note-of-Mumbai-sta.html (2007). Accessed 2010/10/16
Polymer Energy: Turning Waste into Energy (Company Brochure). Polymer Energy, Circle Pines (2010)
Encinar, J.M., González, J.F.: Pyrolysis of synthetic polymers and plastic wastes. Kinetic study. Fuel Process. Technol. 89(7), 678–686 (2008)
Williams, P.T., Slaney, E.: Analysis of products from the pyrolysis and liquefaction of single plastics and waste plastic mixtures. Resour. Conserv. Recycl. 51(4), 754–769 (2007)
Chowlu, A.C.K., Reddy, P.K., Ghoshal, A.K.: Pyrolytic decomposition and model-free kinetics analysis of mixture of polypropylene (PP) and low-density polyethylene (LDPE). Thermochimica Acta 485(1–2), 20–25 (2009)
Hujuri, U., Ghoshal, A.K., Gumma, S.: Modeling pyrolysis kinetics of plastic mixtures. Polym. Degrad. Stab. 93(10), 1832–1837 (2008)
Onwudili, J.A., Insura, N., Williams, P.T.: Composition of products from the pyrolysis of polyethylene and polystyrene in a closed batch reactor: effects of temperature and residence time. J. Anal. Appl. Pyrol. 86(2), 293–303 (2009)
Siddiqui, M.N., Redhwi, H.H.: Pyrolysis of mixed plastics for the recovery of useful products. Fuel Process. Technol. 90(4), 545–552 (2009)
Buah, W.K., Cunliffe, A.M., Williams, P.T.: Characterization of products from the pyrolysis of municipal solid waste. Process Saf. Environ. Prot. 85(5), 450–457 (2007)
Koç, A., Bilgesü, A.Y.: Catalytic and thermal oxidative pyrolysis of LDPE in a continuous reactor system. J. Anal. Appl. Pyrol. 78(1), 7–13 (2007)
Marcilla, A., Beltrán, M.I., Navarro, R.: Study of the deactivation process of HZSM5 zeolite during polyethylene pyrolysis. Appl. Catal. A General 333(1), 57–66 (2007)
Marcilla, A., Gómez-Siurana, A., Valdés, F.J.: Influence of the temperature on the composition of the coke obtained in the catalytic cracking of low density polyethylene in the presence of USY and HZSM-5 zeolites. Microporous Mesoporous Mater. 109(1–3), 420–428 (2008)
Obali, Z., Sezgi, N.A., Doğu, T.: Performance of acidic MCM-like aluminosilicate catalysts in pyrolysis of polypropylene. Chem. Eng. Commun. 196(1), 116–130 (2009)
Agullo, J., Kumar, N., Berenguer, D., Kubicka, D., Marcilla, A., Gómez, A., Salmi, T., Murzin, D.: Catalytic pyrolysis of low density polyethylene over H-β, H-Y, H-Mordenite, and H-Ferrierite zeolite catalysts: Influence of acidity and structures. Kinetics Catal. 48(4), 535–540 (2007)
Coelho, A., Fonseca, I.M., Matos, I., Marques, M.M., Botelho do Rego, A.M., Lemos, M.A.N.D.A., Lemos, F.: Catalytic degradation of low and high density polyethylenes using ethylene polymerization catalysts: kinetic studies using simultaneous TG/DSC analysis. Appl. Catal. A Gen. 374(1–2), 170–179 (2010)
Aguado, J., Serrano, D.P., Miguel, G.S., Escola, J.M., Rodríguez, J.M.: Catalytic activity of zeolitic and mesostructured catalysts in the cracking of pure and waste polyolefins. J. Anal. Appl. Pyrol. 78(1), 153–161 (2007)
Renzini, M.S., Sedran, U., Pierella, L.B.: H-ZSM-11 and Zn-ZSM-11 zeolites and their applications in the catalytic transformation of LDPE. J. Anal. Appl. Pyrol. 86(1), 215–220 (2009)
Aguado, J., Serrano, D.P., Escola, J.M., Peral, A.: Catalytic cracking of polyethylene over zeolite mordenite with enhanced textural properties. J. Anal. Appl. Pyrol. 85(1–2), 352–358 (2009)
Mosio-Mosiewski, J., Warzala, M., Morawski, I., Dobrzanski, T.: High-pressure catalytic and thermal cracking of polyethylene. Fuel Process. Technol. 88(4), 359–364 (2007)
Rasul Jan, M., Shah, J., Gulab, H.: Degradation of waste high-density polyethylene into fuel oil using basic catalyst. Fuel 89(2), 474–480 (2010)
Lee, K.-H.: Thermal and catalytic degradation of pyrolytic oil from pyrolysis of municipal plastic wastes. J. Anal. Appl. Pyrol. 85(1–2), 372–379 (2009)
Gulab, H., Jan, M.R., Shah, J., Manos, G.: Plastic catalytic pyrolysis to fuels as tertiary polymer recycling method: Effect of process conditions. J. Environ. Sci. Health A Toxic/Hazard Subst. Environ. Eng. 45(7), 908–915 (2009)
Park, H.J., Park, Y.-K., Dong, J.-I., Jeon, J.-K., Yim, J.-H., Jeong, K.-E.: Catalytic degradation of polyethylene over ferrierite. Res. Chem. Intermed. 34, 727–735 (2008)
Lee, Y.J., Kim, J.-H., Kim, S.H., Hong, S.B., Seo, G.: Nanocrystalline beta zeolite: an efficient solid acid catalyst for the liquid-phase degradation of high-density polyethylene. Appl. Catal. B Environ. 83(1–2), 160–167 (2008)
Lee, K.H.: Composition of aromatic products in the catalytic degradation of the mixture of waste polystyrene and high-density polyethylene using spent FCC catalyst. Polym. Degrad. Stab. 93(7), 1284–1289 (2008)
Achilias, D.S., Roupakias, C., Megalokonomos, P., Lappas, A.A., Antonakou, V.: Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP). J. Hazard. Mater. 149(3), 536–542 (2007)
Marcilla, A., Gómez-Siurana, A., Berenguer, D.: Study of the influence of the characteristics of different acid solids in the catalytic pyrolysis of different polymers. Appl. Catal. A Gen. 301(2), 222–231 (2006)
Aguado, J., Serrano, D.P., San Miguel, G., Castro, M.C., Madrid, S.: Feedstock recycling of polyethylene in a two-step thermo-catalytic reaction system. J. Anal. Appl. Pyrol. 79(1–2), 415–423 (2007)
San Miguel, G., Serrano, D.P., Aguado, J.: Valorization of waste agricultural polyethylene film by sequential pyrolysis and catalytic reforming. Ind. Eng. Chem. Res. 48(18), 8697–8703 (2009)
Miskolczi, N., Bartha, L.: Investigation of hydrocarbon fractions form waste plastic recycling by FTIR, GC, EDXRFS and SEC techniques. J. Biochem. Biophys. Methods 70(6), 1247–1253 (2008)
Zorriqueta, I.-J.N.: Pyrolysis of Polypropylene by Ziegler Natta Catalysts. University of Hamburg, Hamburg (2006)
del Remedio Hernández, M., García, Á.N., Marcilla, A.: Catalytic flash pyrolysis of HDPE in a fluidized bed reactor for recovery of fuel-like hydrocarbons. J. Anal. Appl. Pyrol. 78(2), 272–281 (2007)
Lin, Y.H., Yang, M.H.: Tertiary recycling of polyethylene waste by fluidised-bed reactions in the presence of various cracking catalysts. J. Anal. Appl. Pyrol. 83(1), 101–109 (2008)
Lin, Y.H., Yang, M.H., Wei, T.T., Hsu, C.T., Wu, K.J., Lee, S.L.: Acid-catalyzed conversion of chlorinated plastic waste into valuable hydrocarbons over post-use commercial FCC catalysts. J. Anal. Appl. Pyrol. 87(1), 154–162 (2010)
Yang, M.H., Lin, Y.H.: Catalytic conversion of postconsumer PE/PP waste into hydrocarbons using the FCC process with an equilibrium FCC commercial catalyst. J. Appl. Polym. Sci. 114(1), 193–203 (2009)
Lin, Y.-H.: Production of valuable hydrocarbons by catalytic degradation of a mixture of post-consumer plastic waste in a fluidized-bed reactor. Polym. Degrad. Stab. 94(11), 1924–1931 (2009)
Lin, Y.H., Yang, M.H.: Tertiary recycling of commingled polymer waste over commercial FCC equilibrium catalysts for producing hydrocarbons. Polym. Degrad. Stab. 94(1), 25–33 (2009)
Lin, Y.H., Yang, M.H.: Chemical catalysed recycling of waste polymers: Catalytic conversion of polypropylene into fuels and chemicals over spent FCC catalyst in a fluidised-bed reactor. Polym. Degrad. Stab. 92(5), 813–821 (2007)
Lin, Y.H., Yang, M.H.: Catalytic pyrolysis of polyolefin waste into valuable hydrocarbons over reused catalyst from refinery FCC units. Appl. Catal. A Gen. 328(2), 132–139 (2007)
Salmiaton, A., Garforth, A.: Waste catalysts for waste polymer. Waste Manage. 27(12), 1891–1896 (2007)
Marcilla, A., Hernández, M.D.R., García, Á.N.: Study of the polymer-catalyst contact effectivity and the heating rate influence on the HDPE pyrolysis. J. Anal. Appl. Pyrol. 79(1–2), 424–432 (2007)
Marcilla, A., Beltrán, M.I., Navarro, R.: Evolution of products during the degradation of polyethylene in a batch reactor. J. Anal. Appl. Pyrol. 86(1), 14–21 (2009)
Ju Park, H., Yim, J.-H., Jeon, J.-K., Man Kim, J., Yoo, K.-S., Park, Y.-K.: Pyrolysis of polypropylene over mesoporous MCM-48 material. J. Phys. Chem. Solids 69(5–6), 1125–1128 (2008)
Marcilla, A., Beltrán, M.I., Navarro, R.: Thermal and catalytic pyrolysis of polyethylene over HZSM5 and HUSY zeolites in a batch reactor under dynamic conditions. Appl. Catal. B Environ. 86(1–2), 78–86 (2009)
Marcilla, A., Gómez-Siurana, A., Odjo, A.O., Navarro, R., Berenguer, D.: Characterization of vacuum gas oil-low density polyethylene blends by thermogravimetric analysis. Polym. Degrad. Stab. 93(3), 723–730 (2008)
Mominou, N., Xian, S.B., Jiaoliang, X.: Studies on coprocessing vacuum residue oil with plastics using thermogravimetric analysis. Pet. Sci. Technol. 27(6), 588–596 (2009)
Marcilla, A., Hernández, M.D.R., García, Á.N.: Degradation of LDPE/VGO mixtures to fuels using a FCC equilibrium catalyst in a sand fluidized bed reactor. Appl. Catal. A Gen. 341(1–2), 181–191 (2008)
Torre, I., Arandes, J., Castano, P., Azkoiti, M., Bilbao, J., de Lasa, H.: Catalytic cracking of plastic pyrolysis waxes with vacuum gasoil: effect of HZSM-5 zeolite in the FCC catalyst. Int. J. Chem. Reactor Eng. 4, 19 (2006)
Arandes, J.M., Azkoiti, M.J., Torre, I., Olazar, M., Castaño, P.: Effect of HZSM-5 catalyst addition on the cracking of polyolefin pyrolysis waxes under FCC conditions. Chem. Eng. J. 132(1–3), 17–26 (2007)
Arandes, J.M., Torre, I., Azkoiti, M.J., Castaño, P., Bilbao, J., de Lasa, H.: Effect of catalyst properties on the cracking of polypropylene pyrolysis waxes under FCC conditions. Catal. Today 133–135, 413–419 (2008)
Arandes, J.M., Torre, I., Castaño, P., Olazar, M., Bilbao, J.: Catalytic cracking of waxes produced by the fast pyrolysis of polyolefins. Energy Fuels 21(2), 561–569 (2007)
Hájeková, E., Mlynková, B., Bajus, M., Spodová, L.: Copyrolysis of naphtha with polyalkene cracking products; the influence of polyalkene mixtures composition on product distribution. J. Anal. Appl. Pyrol. 79(1–2), 196–204 (2007)
Tiikma, L., Tamvelius, H., Luik, L.: Coprocessing of heavy shale oil with polyethylene waste. J. Anal. Appl. Pyrol. 79(1–2), 191–195 (2007)
Siddiqui, M.N., Redhwi, H.H.: Catalytic coprocessing of waste plastics and petroleum residue into liquid fuel oils. J. Anal. Appl. Pyrol. 86(1), 141–147 (2009)
Ali, M.F., Nahid, M., Redhwi, S.S.H.H.: Study on the conversion of waste plastics/petroleum resid mixtures to transportation fuels. J. Mater. Cycles Waste Manage. 6(1), 27–34 (2004)
Demirbas, A.: Recovery of chemicals and gasoline-range fuels from plastic wastes via pyrolysis. Energy Sourc. 27(14), 1313–1319 (2005)
Demirbas, A.: Pyrolysis of municipal plastic wastes for recovery of gasoline-range hydrocarbons. J. Anal. Appl. Pyrol. 72(1), 97–102 (2004)
Al-Salem, S.M., Lettieri, P.: Kinetic study of high density polyethylene (HDPE) pyrolysis. Chem. Eng. Res. Des. 88(12), 1599–1606 (2010)
ICIS: Indicative Chemical Prices A-Z. http://www.icis.com/StaticPages/a-e.htm (2011). Accessed 3 Feb 2011
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This study was funded under the Charles Parsons Energy Research Program (Grant Number Grant Number 6C/CP/E001) of Science Foundation Ireland (SFI).
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Butler, E., Devlin, G. & McDonnell, K. Waste Polyolefins to Liquid Fuels via Pyrolysis: Review of Commercial State-of-the-Art and Recent Laboratory Research. Waste Biomass Valor 2, 227–255 (2011). https://doi.org/10.1007/s12649-011-9067-5
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DOI: https://doi.org/10.1007/s12649-011-9067-5