Abstract
Natural fibre-based nanocomposite is a revolutionary substance developed in the past few years that is employed extensively in constructive and dynamic sectors due to its excellent strength relative to weight proportion and lightweight. The present investigation looked at how silicon nanoparticles affected the polypropylene (PP)/jute fibre's moisture absorption, mechanical properties, flammability, and dynamic mechanical features. Injection moulding was used to create composite materials made from PP, jute fibre, and silicon. The outcomes showed that increasing the weight of nano silicon di oxide (SiO2) nanoparticles up to 6% enhanced the modulus of elasticity (2100 MPa), tension strength (38.24 MPa), and elongation at breakage (1.67%) of hybrids. The bending strength and modulus of clean PP/jute were 34.19 MPa and 2160 MPa, respectively, while the bending strength and modulus of PP/jute/SiO2 were 51.78 MPa and 2780 MPa, respectively, demonstrating a 28.18% increase in bending strength. With increased nanoparticle loading, it was additionally demonstrated that water uptake (8.9%) and swollen thickness (2.01%) have significantly decreased. NanoSiO2 was added to composites to enhance their dynamic mechanical (loss and storage modulus of 4.92 & 12.80 MPa) behavior and fire characteristics (17 mm/min combustion rate, char residue of 29%). The 6 wt.% of SiO2 nanoparticles that exist in the jute fibre and PP specimens have not been exfoliated, so the manner in which they disperse has to be improved (2Ѳ = 2.32º, d-spacing of 39.01 nm and intercorrelation of 23.41%), according to X-ray diffraction (XRD) examinations. It is asserted that the char barrier's durability is significantly influenced by the chemical mixture's makeup and pattern of dispersion. The creation of char shields with higher nanosilicon dioxide content prevents burning and necessitates higher temperatures for disintegration.
Graphical Abstract
Graphical abstract of Nano SiO2/Jute Based Hybrid Polypropylene composites
Similar content being viewed by others
Data Availability
The data used to support the findings of this study are included in the article. Should further data or information be required, these are available from the corresponding author upon request.
References
Khalid MY, Al RA, Arif ZU et al (2021) Characterization of failure strain in fiber reinforced composites: Under on-axis and off-axis loading. Crystals 11:1–11. https://doi.org/10.3390/cryst11020216
Singh K, Ohlan A, Saini P, Dhawan SK (2008) composite – super paramagnetic behavior and variable range hopping 1D conduction mechanism – synthesis and characterization. Polym Adv Technol 229–236. https://doi.org/10.1002/pat
Khalid MY, Al Rashid A, Arif ZU et al (2021) Tensile strength evaluation of glass/jute fibers reinforced composites: An experimental and numerical approach. Results Eng 10:100232. https://doi.org/10.1016/j.rineng.2021.100232
Karim N, Sarker F, Afroj S, et al (2021) Sustainable and Multifunctional Composites of Graphene-Based Natural Jute Fibers. Adv Sustain Syst 5. https://doi.org/10.1002/adsu.202000228
Khalid MY, Al Rashid A, Arif ZU et al (2021) Natural fiber reinforced composites: Sustainable materials for emerging applications. Results Eng 11:100263. https://doi.org/10.1016/j.rineng.2021.100263
Khalid MY, Imran R, Arif ZU et al (2021) Developments in chemical treatments, manufacturing techniques and potential applications of natural-fibers-based biodegradable composites. Coatings 11:1–18. https://doi.org/10.3390/coatings11030293
Khalid MY, Arif ZU, Sheikh MF, Nasir MA (2021) Mechanical characterization of glass and jute fiber-based hybrid composites fabricated through compression molding technique. IntJ Mater Form 14:1085–1095. https://doi.org/10.1007/s12289-021-01624-w
Gogna E, Kumar R, Anurag et al (2019) A comprehensive review on jute fiber reinforced composites. Springer, Singapore
Velmurugan G, Babu K, Nagaraj M, Kumar AJP (2023) Investigations of Flame Retardancy, Mechanical and Thermal Properties of Woven Hemp/PP Hybrid Composite for Insulating Material Reinforced with Synthetic Silicon and Zinc Oxides. Silicon. https://doi.org/10.1007/s12633-023-02408-4
Alves C, Ferrão PMC, Silva AJ et al (2010) Ecodesign of automotive components making use of natural jute fiber composites. J Clean Prod 18:313–327. https://doi.org/10.1016/j.jclepro.2009.10.022
Khan RA, Khan MA, Zaman HU et al (2010) Comparative studies of mechanical and interfacial properties between jute and e-glass fiber-reinforced polypropylene composites. J Reinf Plast Compos 29:1078–1088. https://doi.org/10.1177/0731684409103148
Khalili P, Liu X, Zhao Z, Blinzler B (2019) Fully biodegradable composites: Thermal, flammability, moisture absorption and mechanical properties of Natural fibre-reinforced composites with nano-hydroxyapatite. Materials 12:1–13. https://doi.org/10.3390/ma12071145
Kim NK, Dutta S, Bhattacharyya D (2018) A review of flammability of natural fibre reinforced polymeric composites. Compos Sci Technol 162:64–78. https://doi.org/10.1016/j.compscitech.2018.04.016
Shah AUR, Prabhakar MN, Il SJ (2017) Current advances in the fire retardancy of natural fiber and bio-based composites – A review. Int J Precis Eng Manuf - Green Technol 4:247–262. https://doi.org/10.1007/s40684-017-0030-1
Chapple S, Anandjiwala R (2010) Flammability of natural fiber-reinforced composites and strategies for fire retardancy: A review. J Thermoplast Compos Mater 23:871–893. https://doi.org/10.1177/0892705709356338
Munikenche Gowda T, Naidu ACB, Chhaya R (1999) Some mechanical properties of untreated jute fabric-reinforced polyester composites. Compos A Appl Sci Manuf 30:277–284. https://doi.org/10.1016/S1359-835X(98)00157-2
Ashok Kumar M, Ramachandra Reddy G, Siva Bharathi Y et al (2010) Frictional coefficient, hardness, impact strength, and chemical resistance of reinforced sisal-glass fiber epoxy hybrid composites. J Compos Mater 44:3195–3202. https://doi.org/10.1177/0021998310371551
Maurya AK, Gogoi R, Manik G (2021) Mechano-chemically activated fly-ash and sisal fiber reinforced PP hybrid composite with enhanced mechanical properties. Cellulose 28:8493–8508. https://doi.org/10.1007/s10570-021-03995-4
Annie Paul S, Boudenne A, Ibos L et al (2008) Effect of fiber loading and chemical treatments on thermophysical properties of banana fiber/polypropylene commingled composite materials. Compos A Appl Sci Manuf 39:1582–1588. https://doi.org/10.1016/J.COMPOSITESA.2008.06.004
Dilfi KFA, Balan A, Bin H et al (2018) Effect of surface modification of jute fiber on the mechanical properties and durability of jute fiber-reinforced epoxy composites. Polym Compos 39:E2519–E2528. https://doi.org/10.1002/pc.24817
Wang H, Memon H, Hassan EAM, et al (2019) Effect of jute fiber modification on mechanical properties of jute fiber composite. Materials 12. https://doi.org/10.3390/ma12081226
Rajeshkumar G, Seshadri SA, Ramakrishnan S et al (2021) A comprehensive review on natural fiber/nano-clay reinforced hybrid polymeric composites: Materials and technologies. Polym Compos 42:3687–3701. https://doi.org/10.1002/pc.26110
Saba N, Tahir PM, Jawaid M (2014) A review on potentiality of nano filler/natural fiber filled polymer hybrid composites. Polymers 6:2247–2273. https://doi.org/10.3390/polym6082247
Sliding wear performance of nano-SiO2/short carbon fiber/epoxy hybrid composites - ScienceDirect. https://www.sciencedirect.com/science/article/abs/pii/S0043164808003712?casa_token=D0EEXTTNipIAAAAA:5aTNXS0oJSeWtu2ypvOmu0VJrsofUhyzH2YfEity7ggA8dgLoecpRJAWiuHMDTcWR6RsnMbhcv8U. Accessed 30 Jul 2022
Pappu A, Thakur VK (2017) Towards sustainable micro and nano composites from fly ash and natural fibers for multifunctional applications. Vacuum 146:375–385. https://doi.org/10.1016/j.vacuum.2017.05.026
Essabir H, Boujmal R, Bensalah MO et al (2016) Mechanical and thermal properties of hybrid composites: Oil-palm fiber/clay reinforced high density polyethylene. Mech Mater 98:36–43. https://doi.org/10.1016/j.mechmat.2016.04.008
Velmurugan G, Siva Shankar V, KalilRahiman M et al (2023) Experimental Investigation of High Filler Loading of SiO2 on the Mechanical and Dynamic Mechanical Analysis of Natural PALF fibre-Based Hybrid Composite. Silicon. https://doi.org/10.1007/s12633-023-02464-w
Nawafleh N, Elibol FKE, Aljaghtham M et al (2020) Static and dynamic mechanical performance of short Kevlar fiber reinforced composites fabricated via direct ink writing. J Mater Sci 55:11284–11295. https://doi.org/10.1007/s10853-020-04826-w
Velmurugan G, Natrayan L (2023) Experimental Investigations of Moisture Diffusion and Mechanical Properties of Interply Rearrangement of Glass/Kevlar-based hybrid Composites under Cryogenic Environment. J Mater Res Technol. https://doi.org/10.1016/J.JMRT.2023.02.089
Correia CA, De Oliveira LM, Valera TS (2017) The influence of bleached jute fiber filler on the properties of vulcanized natural rubber. Mater Res 20:472–478. https://doi.org/10.1590/1980-5373-mr-2017-0126
Nourbakhsh A, Farhani F, Ashori A (2011) Nano-SiO 2 filled rice husk / polypropylene composites : Physico-mechanical properties. Ind Crops Prod 33:183–187. https://doi.org/10.1016/j.indcrop.2010.10.010
Khalid MY, Nasir MA, Ali A et al (2020) Experimental and numerical characterization of tensile property of jute/carbon fabric reinforced epoxy hybrid composites. SN Appl Sci 2:1–10. https://doi.org/10.1007/s42452-020-2403-2
Kuppuraj A, Angamuthu M (2022) Investigation of mechanical properties and free vibration behavior of graphene/basalt nano filler banana/sisal hybrid composite. Polym Polym Compos 30:1–12. https://doi.org/10.1177/09673911211066719
Jesuarockiam N, Jawaid M, Zainudin ES, et al (2019) Enhanced thermal and dynamic mechanical properties of synthetic/natural hybrid composites with graphene nanoplateletes. Polymers 11. https://doi.org/10.3390/polym11071085
Farsi M (2017) Effect of Nano-SiO2 and Bark Flour Content on the Physical and Mechanical Properties of Wood-Plastic Composites. J Polym Environ 25:308–314. https://doi.org/10.1007/s10924-016-0813-4
Ozsoy I, Demirkol A, Mimaroglu A et al (2015) The influence of micro- And nano-filler content on the mechanical properties of epoxy composites. Strojniski Vestnik/J Mech Eng 61:601–609. https://doi.org/10.5545/sv-jme.2015.2632
Khalid MY, Arif ZU, Al Rashid A (2022) Investigation of tensile and flexural behavior of green composites along with their impact response at different energies. Int J Precis Eng Manuf-Green Technol 9:1399–1410
Nahar S, Khan RA, Dey K et al (2012) Comparative studies of mechanical and interfacial properties between jute and bamboo fiber-reinforced polypropylene-based composites. J Thermoplast Compos Mater 25:15–32. https://doi.org/10.1177/0892705711404725
Li L, Zou H, Shao L et al (2005) Study on mechanical property of epoxy composite filled with nano-sized calcium carbonate particles. J Mater Sci 40:1297–1299. https://doi.org/10.1007/s10853-005-6956-7
Pourjavadi A, Fakoorpoor SM, Khaloo A, Hosseini P (2012) Improving the performance of cement-based composites containing superabsorbent polymers by utilization of nano-SiO2 particles. Mater Des 42:94–101. https://doi.org/10.1016/j.matdes.2012.05.030
Kumar D, Shahapurkar K, Venkatesh C, et al (2022) Influence of graphene nano fillers and carbon nano tubes on the mechanical and thermal properties of hollow glass microsphere epoxy composites. Processes 10. https://doi.org/10.3390/pr10010040
Article R, Ramesh M, Rajeshkumar LN, et al (2022) In fl uence of fi ller material on properties of fi ber - reinforced polymer composites : A review. 898–916
Fernandes Medeiros de Queiroz H, Banea MD, Kioshi Kawasaki Cavalcanti D, De Souza e Silva Neto J (2021) The effect of multiscale hybridization on the mechanical properties of natural fiber-reinforced composites. J Appl Polym Sci 138:1–12. https://doi.org/10.1002/app.51213
Natrayan L, Kaliappan S, Sethupathy BS, et al (2022) Effect of Mechanical Properties on Fibre Addition of Flax and Graphene-Based Bionanocomposites. Int J Chem Eng 2022. https://doi.org/10.1155/2022/5086365
Agarwal S, Patidar D, Saxena NS (2012) Effect of ZnS Nanofiller and Temperature on Mechanical Properties of Poly (methyl methacrylate). J Appl Polym Sci 123:2431–2438. https://doi.org/10.1002/app.34800
Kord B (2012) Effect of nanoparticles loading on properties of polymeric composite based on Hemp Fiber/Polypropylene. J Thermoplast Compos Mater 25:793–806. https://doi.org/10.1177/0892705711412815
Saba N, Paridah AK, Ibrahim NA (2016) Dynamic mechanical properties of oil palm nano filler/kenaf/epoxy hybrid nanocomposites. Constr Build Mater 124:133–138. https://doi.org/10.1016/j.conbuildmat.2016.07.059
Ponnusamy M, Natrayan L, Patil PP, et al (2022) Multiresponse Optimization of Mechanical Behaviour of Calotropis gigantea/Nano-Silicon-Based Hybrid Nanocomposites under Cryogenic Environment. Adsorpt Sci Technol 2022. https://doi.org/10.1155/2022/4138179
Kord B (2010) Effect of Organo-Modified Layered Silicates on Flammability Performance of High-Density Polyethylene/ Rice Husk Flour Nanocomposite. Wiley Online Library. https://doi.org/10.1002/app.33215.
Malik MA, Sarkar M, Xu S, Li Q (2019) Effect of PVA/SiO2 NPs additive on the structural, durability, and fire resistance properties of geopolymers. Appl Sci (Switzerland) 9. https://doi.org/10.3390/app9091953
Qin H, Su Q, Zhang S et al (2003) Thermal stability and flammability of polyamide 66/montmorillonite nanocomposites. Polymer 44:7533–7538. https://doi.org/10.1016/j.polymer.2003.09.014
Weil ED, Levchik SV (2008) Flame retardants in commercial use or development for polyolefins. J Fire Sci 26:5–43. https://doi.org/10.1177/0734904107083309
Ribeiro MCS, Sousa SPB, Nóvoa PRO (2015) An Investigation on Fire and Flexural Mechanical Behaviors of Nano and Micro Polyester Composites Filled with SiO2 and Al2O3 Particles. Mater Today: Proc 2:8–19. https://doi.org/10.1016/j.matpr.2015.04.002
Pang H, Wang X, Zhu X et al (2015) Nanoengineering of brucite@SiO2 for enhanced mechanical properties and flame retardant behaviors. Polym Degrad Stab 120:410–418. https://doi.org/10.1016/j.polymdegradstab.2015.08.002
Sanjeevi S, Shanmugam V, Kumar S et al (2021) Effects of water absorption on the mechanical properties of hybrid natural fibre/phenol formaldehyde composites. Sci Rep 11:1–11. https://doi.org/10.1038/s41598-021-92457-9
Ganesan V, Kaliyamoorthy B (2020) Utilization of Taguchi Technique to Enhance the Interlaminar Shear Strength of Wood Dust Filled Woven Jute Fiber Reinforced Polyester Composites in Cryogenic Environment. J Nat Fibers. https://doi.org/10.1080/15440478.2020.1789021
Natrayan L, Kumar PVA, Baskara Sethupathy S, et al (2022) Water Retention Behaviour and Fracture Toughness of Coir/Pineapple Leaf Fibre with Addition of Al2O3Hybrid Composites under Ambient Conditions. Adsorpt Sci Technol 2022. https://doi.org/10.1155/2022/7209761
Natrayan L, Veeman D, Baskara Sethupathy S et al (2022) Influence of Nanosilica Particle Addition on Mechanical and Water Retention Properties of Natural Flax- and Sisal-Based Hybrid Nanocomposites under NaOH Conditions. Adsorpt Sci Technol 2022:1–11. https://doi.org/10.1155/2022/4026495
Acknowledgements
The authors thank the Institute of Agricultural Engineering, Saveetha School of Engineering (SIMATS), Tamil Nadu, India for the technical assistance.
Author information
Authors and Affiliations
Contributions
Velmurugan G and Jasgurpreet Singh: Conceptualization, Methodology.
Muhammed Abraar S.A, Sathish R and Senthil Murugan S: Writing an original draft.
Suresh Kumar S and Nagaraj M: Investigation, Review.
Elil Raja D and Siva Shankar V: Testing and Evaluations.
Corresponding author
Ethics declarations
Ethics Approval
Not applicable.
Conflicts of Interest
Nil.
Consent to Participate
Not applicable.
Competing Interests
Nil.
Consent for Publication
Yes. All permission granted.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
G., V., Chohan, J.S., S. A., M.A. et al. Investigation of Nano SiO2 Filler Loading on Mechanical and Flammability Properties of Jute-Based Hybrid Polypropylene Composites. Silicon 15, 7247–7263 (2023). https://doi.org/10.1007/s12633-023-02578-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12633-023-02578-1