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An Effective Approach on Attaining Enhanced Silicon Solar Cell Performance Through Sputter Deposited Perovskite Thin Films

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Abstract

Antireflection coatings (ARCs) have become one of the key techniques for mass production of Si solar cells. They are generally performed by vacuum processes such as thermal evaporation, sol–gel and plasma-enhanced chemical vapor deposition. In this work, RF sputtering method was adopted to prepare the ARCs for the non-textured polycrystalline Si solar cells. The RF sputter coated strontium titanate(SrTiO3), barium titatnate(BaTiO3)and SrTiO3-BaTiO3(mechanical blends). Si solar cells were inspected through various characterisation techniques. Through RF sputter deposition technique, thin films with good uniformity can be achieved easily. The influence of ARC on solar cell samples were studied through evaluation of structural, optical and electrical properties of coated and uncoated samples. The structural characterization was carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM).The electrical resistivity was measured in dark at room temperature using four-point probe technique. UV–visible spectroscopy was utilised for determining optical characterization. It was found that SrTiO3-BaTiO3blend coated cell (M3)has considerable effect on the performance of solar cell as compare to uncoated and other coated solar cells. The maximum power conversion efficiencies (PCE) of 19.58% and 21.15% were achieved for M3 solar cell in presence of solar and neodymium irradiation under open and controlled atmospheric conditions. Neodymium light radiation was similar to the natural sun light and can be used for growing plants and veterinaries under enclosed surface. Based on the results, SrTiO3-BaTiO3 blends found to be an appropriate ARC material for minimising scattering of incident photons.

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References

  1. Kemell M, Ritala M, Leskelä M (2005) Thin film deposition methods for CuInSe2 solar cells. Crit Rev Solid State Mater Sci 30:1–31. https://doi.org/10.1080/10408430590918341

    Article  CAS  Google Scholar 

  2. Habubi NF, Ismail RA, Mishjil KA, and Hassoon KI (2018) Increasing the Silicon Solar Cell Efficiency with Nanostructured SnO2 Anti-reflecting Coating Films. Silicon 1-6. https://doi.org/10.1007/s12633-017-9727-6

  3. Kaliyannan GV, Palanisamy SV, Palanisamy M, Chinnasamy M, Somasundaram S, Nagarajan N, Rathanasamy R (2019) Utilization of 2D gahnite nanosheets as highly conductive, transparent and light trapping front contact for silicon solar cells. Appl Nanosci 9:1427–1437. https://doi.org/10.1007/s13204-018-00949-4

    Article  CAS  Google Scholar 

  4. Uzum A, Kuriyama M, Kanda H, Kimura Y, Tanimoto K, Fukui H, Izumi T, Harada T, Ito S (2017) Sprayed and spin-coated multilayer antireflection coating films for nonvacuum processed crystalline silicon solar cells. Int J Photoenergy 2017:1–5. https://doi.org/10.1155/2017/3436271

    Article  CAS  Google Scholar 

  5. Kaliyannan GV, Palanisamy SV, Palanisamy M, Subramanian M, Paramasivam P, Rathanasamy R (2019) Development of sol-gel derived gahnite anti-reflection coating for augmenting the power conversion efficiency of polycrystalline silicon solar cells. Mater Sci-Pol 37:465–472. https://doi.org/10.2478/msp-2019-0066

    Article  CAS  Google Scholar 

  6. Kang D-W, Kwon J-Y, Shim J, Lee H-M, Han M-K (2012) Al2O3 antireflection layer between glass and transparent conducting oxide for enhanced light trapping in microcrystalline silicon thin film solar cells. Sol Energy Mater Sol Cells 101:22–25. https://doi.org/10.1016/j.solmat.2012.02.020

    Article  CAS  Google Scholar 

  7. Lien S-Y, Wuu D-S, Yeh W-C, Liu J-C (2006) Tri-layer antireflection coatings (SiO2/SiO2-TiO2/TiO2) for silicon solar cells using a sol-gel technique. Sol Energy Mater Sol Cells 90:2710–2719. https://doi.org/10.1016/j.solmat.2006.04.001

    Article  CAS  Google Scholar 

  8. Kesmez Ö, Akarsu E, Çamurlu HE, Yavuz E, Akarsu M, Arpaç E (2018) Preparation and characterization of multilayer anti-reflective coatings via sol-gel process. Ceram Int 44:3183–3188. https://doi.org/10.1016/j.ceramint.2017.11.088

    Article  CAS  Google Scholar 

  9. Kaliyannan GV, Palanisamy SV, Rathanasamy R, Palanisamy M, Palaniappan SK, Chinnasamy M (2020) Influence of ultrathin gahnite anti-reflection coating on the power conversion efficiency of polycrystalline silicon solar cell. J Mater Sci: Mater Electron 31:2308–2319. https://doi.org/10.1007/s10854-019-02763-2

    Article  CAS  Google Scholar 

  10. Bouhafs D, Moussi A, Chikouche A, Ruiz J (1998) Design and simulation of antireflection coating systems for optoelectronic devices: Application to silicon solar cells. Sol Energy Mater Sol Cells 52:79–93. https://doi.org/10.1016/S0927-0248(97)00273-0

    Article  CAS  Google Scholar 

  11. Kaliyannan GV, Palanisamy SV, Rathanasamy R, Palanisamy M, Nagarajan N, Sivaraj S, Anbupalani MS (2020) An Extended Approach on Power Conversion Efficiency Enhancement Through Deposition of ZnS-Al2S3 Blends on Silicon Solar Cells. J Electron Mater 49:5937–5946. https://doi.org/10.1007/s11664-020-08361-x

    Article  CAS  Google Scholar 

  12. Saga T (2010) Advances in crystalline silicon solar cell technology for industrial mass production. npg Asia Materials 2:96–102. https://doi.org/10.1038/asiamat.2010.82

    Article  Google Scholar 

  13. Khan F, Baek S-H, Mobin A, Kim JH (2014) Enhanced performance of silicon solar cells by application of low-cost sol-gel-derived Al-rich ZnO film. Sol Energy 101:265–271. https://doi.org/10.1016/j.solener.2013.12.025

    Article  CAS  Google Scholar 

  14. Verma A, Khan F, Kumar D, Kar M, Chakravarty B, Singh S, Husain M (2010) Sol-gel derived aluminum doped zinc oxide for application as anti-reflection coating in terrestrial silicon solar cells. Thin Solid Films 518:2649–2653. https://doi.org/10.1016/j.tsf.2009.08.010

    Article  CAS  Google Scholar 

  15. Liu Z, Zhang X, Murakami T, Fujishima A (2008) Sol-gel SiO2/TiO2 bilayer films with self-cleaning and antireflection properties. Sol Energy Mater Sol Cells 92:1434–1438. https://doi.org/10.1016/j.solmat.2008.06.005

    Article  CAS  Google Scholar 

  16. Sharma R, Amit G, and Ajit V (2017) Effect of single and double layer antireflection coating to enhance photovoltaic efficiency of silicon solar. 9: 02001(1–4). https://doi.org/10.21272/jnep.9(2).02001

  17. Kaliyannan GV, Palanisamy SV, Priyanka E, Thangavel S, Sivaraj S, Rathanasamy R (2020) Investigation on sol-gel based coatings application in energy sector-A review. Materials Today: Proceedings 45:1138–1143. https://doi.org/10.1016/j.matpr.2020.03.484

    Article  CAS  Google Scholar 

  18. Senthilkumar N, Arulraj A, Nandhakumar E, Ganapathy M, Vimalan M, Potheher IV (2018) Green mediated synthesis of plasmonic nanoparticle (Ag) for antireflection coating in bare mono silicon solar cell. J Mater Sci: Mater Electron 29:12744–12753. https://doi.org/10.1007/s10854-018-9392-6

    Article  CAS  Google Scholar 

  19. Sagar R, Rao A (2021) Nanoscale TiO2 and Ta2O5 as efficient antireflection coatings on commercial monocrystalline silicon solar cell. J Alloy Compd 862:158464. https://doi.org/10.1016/j.jallcom.2020.158464

    Article  CAS  Google Scholar 

  20. Zhang Y, Zheng J, Fang C, Li Z, Zhao X, Li Y, Ruan X, Dai Y (2018) Enhancement of silicon-wafer solar cell efficiency with low-cost wrinkle antireflection coating of polydimethylsiloxane. Sol Energy Mater Sol Cells 181:15–20. https://doi.org/10.1016/j.solmat.2017.10.004

    Article  CAS  Google Scholar 

  21. Khan F, Baek S-H, Kim JH (2017) Influence of oxygen vacancies on surface charge potential and transportation properties of Al-doped ZnO nanostructures produced via atomic layer deposition. J Alloy Compd 709:819–828. https://doi.org/10.1016/j.jallcom.2017.03.133

    Article  CAS  Google Scholar 

  22. Gholamrezaei S, Niasari MS, Dadkhah M, Sarkhosh B (2016) New modified sol-gel method for preparation SrTiO3 nanostructures and their application in dye-sensitized solar cells. J Mater Sci: Mater Electron 27:118–125. https://doi.org/10.1007/s10854-015-3726-4

    Article  CAS  Google Scholar 

  23. Chynoweth A (1956) Surface space-charge layers in barium titanate. Phys Rev 102:705. https://doi.org/10.1103/PhysRev.102.705

    Article  CAS  Google Scholar 

  24. Sharma A, Priyadarshini BG, Mehta B, Kumar D (2015) An amorphous barium titanate thin film improves light trapping in Si solar cells. RSC Adv 5:59881–59886. https://doi.org/10.1039/C5RA07923C

    Article  CAS  Google Scholar 

  25. Dadkhah M, Salavati-Niasari M (2014) Dye-sensitized solar cells based on tin dioxide nanoparticles prepared by a facile hydrothermal method. Mater Sci Semicond Process 20:41–48. https://doi.org/10.1016/j.mssp.2013.12.025

    Article  CAS  Google Scholar 

  26. Juneja S, Poletayev SD, Fomchenkov S, Khonina SN, Skidanov RV, and Kazanskiy NL. Reactive ion etching of indium-tin oxide films by CCl4-based Inductivity Coupled Plasma. in Journal of Physics: Conference Series. 2016. IOP Publishing. https://doi.org/10.1088/1742-6596/741/1/012105

  27. Juneja S and Kumar S (2020) Effect of Power on Crystallinity and Opto-Electronic Properties of Silicon Thin Films Grown Using VHF PECVD Process. Silicon 1-14. https://doi.org/10.1007/s12633-020-00697-7

  28. Setyadi A, Iriani Y, and Nurosyid F. Optical Properties and Microstructure of Barium Titanate Thin Film (BaTiO3) for Solar Cell Applications. in IOP Conference Series: Materials Science and Engineering. 2018. IOP Publishing. https://doi.org/10.1088/1757-899X/333/1/012035

  29. Green M, Blakers A, Shi J, Keller E, Wenham S (1984) 19.1% efficient silicon solar cell. Appl Phys Lett 44:1163–1164. https://doi.org/10.1063/1.94678

    Article  CAS  Google Scholar 

  30. Alaoui KB, Laalioui S, Ikken B, Outzourhit A (2020) Promising Shadow Masking Technique for the Deposition of High-Efficiency Amorphous Silicon Solar Cells Using Plasma-Enhanced Chemical Vapor Deposition. Frontiers in Mechanical Engineering 6:92. https://doi.org/10.3389/fmech.2020.560385

    Article  Google Scholar 

  31. Prepelita P, Filipescu M, Stavarache I, Garoi F, Craciun D (2017) Transparent thin films of indium tin oxide: Morphology-optical investigations, inter dependence analyzes. Appl Surf Sci 424:368–373. https://doi.org/10.1016/j.apsusc.2017.02.106

    Article  CAS  Google Scholar 

  32. Vallejo W, Romero E, Gordillo G (2011) Study of growth, optical and morphological properties of Zn (O; OH) S thin films synthesized by CBD method. J Braz Chem Soc 22:2286–2291. https://doi.org/10.1590/S0103-50532011001200008

    Article  CAS  Google Scholar 

  33. Yoo J, Lee J, Kim S, Yoon K, Park IJ, Dhungel S, Karunagaran B, Mangalaraj D, Yi J (2005) High transmittance and low resistive ZnO: Al films for thin film solar cells. Thin Solid Films 480:213–217. https://doi.org/10.1016/j.tsf.2004.11.010

    Article  CAS  Google Scholar 

  34. Santhosh S, Rajasekar R, Gobinath V, Moganapriya C, Arun Kumar S, and Manju Sri A (2021) Influence of Electrosprayed MoSe2 Antireflective Surface Coatings on Performance of Multicrystalline Silicon Solar Cell. Silicon 1-13. https://doi.org/10.1007/s12633-021-01385-w

  35. Firdaus C, Rusop M, Baki S, and Salimin R. Optical and electrical properties of ZnO and ZnO: TiO2 thin films prepared by sol-gel spray-spin coating technique. in 2012 10th IEEE International Conference on Semiconductor Electronics (ICSE). 2012. IEEE. https://doi.org/10.1109/SMElec.2012.6417114

  36. Kaushal A, Kaur D (2011) Pulsed laser deposition of transparent ZnO/MgO multilayers. J Alloy Compd 509:200–205. https://doi.org/10.1016/j.jallcom.2010.09.077

    Article  CAS  Google Scholar 

  37. Xue S, Zu X, Shao L, Yuan Z, Zheng W, Jiang X, Deng H (2008) Effects of annealing on optical properties of Zn-implanted ZnO thin films. J Alloy Compd 458:569–573. https://doi.org/10.1016/j.jallcom.2007.04.239

    Article  CAS  Google Scholar 

  38. Chang J, Hon M-H (2001) The effect of deposition temperature on the properties of Al-doped zinc oxide thin films. Thin Solid Films 386:79–86. https://doi.org/10.1016/S0040-6090(00)01891-5

    Article  CAS  Google Scholar 

  39. Jeong S, Lee J, Lee S, Boo J (2003) Deposition of aluminum-doped zinc oxide films by RF magnetron sputtering and study of their structural, electrical and optical properties. Thin Solid Films 435:78–82. https://doi.org/10.1016/S0040-6090(03)00376-6

    Article  CAS  Google Scholar 

  40. Shinde UP (2015) Hall coefficient, mobility and carrier concentration as a function of composition and thickness of Zn-Te thin films. Adv Appl Sci Res 6:215–220

    CAS  Google Scholar 

  41. Bhat TS, Kalekar AS, Dalavi DS, Revadekar CC, Khot AC, Dongale TD, Patil PS (2019) Hydrothermal synthesis of nanoporous lead selenide thin films: photoelectrochemical and resistive switching memory applications. J Mater Sci: Mater Electron 30:17725–17734. https://doi.org/10.1007/s10854-019-02122-1

    Article  CAS  Google Scholar 

  42. Uslu H, Altındal Ş, Dökme İ (2010) Illumination effect on electrical characteristics of organic-based Schottky barrier diodes. J Appl Phys 108:104501. https://doi.org/10.1063/1.3504598

    Article  CAS  Google Scholar 

  43. Zhang C, Luo Y, Chen X, Chen Y, Sun Z, Huang S (2016) Effective improvement of the photovoltaic performance of carbon-based perovskite solar cells by additional solvents. Nano-micro letters 8:347–357. https://doi.org/10.1007/s40820-016-0094-4

    Article  CAS  PubMed  Google Scholar 

  44. Khan F, Baek S-H, Kim JH (2014) Intensity dependency of photovoltaic cell parameters under high illumination conditions: An analysis. Appl Energy 133:356–362. https://doi.org/10.1016/j.apenergy.2014.07.107

    Article  Google Scholar 

  45. Song DH, Kim H-S, Suh JS, Jun B-H, Rho W-Y (2017) Multi-shaped Ag nanoparticles in the plasmonic layer of dye-sensitized solar cells for increased power conversion efficiency. Nanomaterials 7:136. https://doi.org/10.3390/nano7060136

    Article  CAS  PubMed Central  Google Scholar 

  46. Jung J, Jannat A, Akhtar MS, Yang O (2018) Sol-Gel Deposited Double Layer TiO2 and Al2O3 Anti-Reflection Coating for Silicon Solar Cell. J Nanosci Nanotechnol 18:1274–1278. https://doi.org/10.1166/jnn.2018.14928

    Article  CAS  PubMed  Google Scholar 

  47. Radziemska E (2003) The effect of temperature on the power drop in crystalline silicon solar cells. Renewable Energy 28:1–12. https://doi.org/10.1016/S0960-1481(02)00015-0

    Article  CAS  Google Scholar 

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Acknowledgements

The author (Mr.S. Santhosh) thank the AICTE, New Delhi for selecting as full-time research scholar under AICTE Doctoral Fellowship (ADF) scheme in 2019 (Scholar ID-1- 6382526181). Also thank Kongu Engineering College management for providing financial assistance.

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This research work is not financially supported by research funding organisations.

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All authors have performed intial discussion regarding this research work. V. K. Gobinath done set of material purchase, experiment work and interpreted the acquired data. S. Santhosh have assisted with experiments at ceratin instances. C. Moganapriya and A. Manju Sri were characterized the coatedsamples through XRD, FESEM with EDAX, AFM, IPCE spectra and temperature analysis. J. Saravana Kumar have ascertained the I-V characteristics (open and closed enviroment) of uncoated and coated samples. V. K. Gobinath was finally drafted a research manuscript. The complete research was performed under the direction of R. Rajasekar and have interpreted the obtained experimental results.

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Correspondence to R. Rajasekar.

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Gobinath, V.K., Rajasekar, R., Santhosh, S. et al. An Effective Approach on Attaining Enhanced Silicon Solar Cell Performance Through Sputter Deposited Perovskite Thin Films. Silicon 14, 9773–9788 (2022). https://doi.org/10.1007/s12633-022-01714-7

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