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Heterogeneous engineering of MnSe@NC@ReS2 core–shell nanowires for advanced sodium-/potassium-ion batteries

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Abstract

Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) have been attracting great attentions and widely been exploited due to the abundant sodium/potassium resources. Hence, the preparation of high-powered anode materials for SIBs/PIBs plays a decisive role for the commercial applications of SIBs/PIBs in the future. Manganese selenides are a class of potential anode materials for SIBs/PIBs because of their small band gap and high electrical conductivity. In this work, MnSe and ReS2 core–shell nanowires connecting by polydopamine derived carbon nanotube (MnSe@NC@ReS2) have been successfully synthesized from growing ReS2 nanosheets array on the surface of MnSe@NC nanowires, which present excellent Na+/K+ storage performance. While applied as SIBs anode, the specific capacity of 300 mAh·g−1 was maintained after 400 cycles at the current density of 1.0 A·g−1. Besides, it could also keep 120 mAh·g−1 specific capacity after 900 cycles at 1.0 A·g−1 for the anode of PIBs. These heterogeneous engineering and one-dimensional–two-dimensional (1D-2D) hybrid strategies could provide an ideal strategy for the synthesis of new hetero-structured anode materials with outstanding battery performance for SIBs and PIBs.

Graphical abstract

摘要

钠离子电池 (SIBs)和钾离子电池 (PIBs)因其丰富的钠/钾资源而备受关注和广泛开发。因此，高性能钠/钾离子电池负极材料的制备对它们未来的商业应用具有决定性的作用。硒化锰具有低带隙和高导电性，是钠/钾离子电池极具潜力的负极材料。本文通过在MnSe@NC纳米线表面生长ReS2纳米片阵列，成功合成了以聚多巴胺衍生碳纳米管(MnSe@NC@ReS2)连接的MnSe和ReS2核壳纳米线，具有优异的钠/钾离子存储性能。作为SIBs负极时，在1.0 A.g-1电流密度下，循环 400 次后比容量保持在300 mAh.g-1。作为 PIBs 负极时，在 1.0 A.g-1电流下 900 次循环后的比容量仍可保持 120 mAh.g-1。这种异质工程和一维-二维 (1D–2D) 杂化策略可以为合成具有优异电池性能的钠/钾离子电池新型异质结构负极材料提供理想的合成策略。

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 52101243), the Natural Science Foundation of Guangdong Province (No. 2023A1515012619) and the Science and Technology Planning Project of Guangzhou (No. 202102010373).

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Author notes

  1. Sheng-Jun Lu and Jin-Yi Lin have contributed equally to this work.

Authors and Affiliations

  1. College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang, 550025, China

    Sheng-Jun Lu, Jin-Yi Lin, Cai-Hong Wang & Yu-Fei Zhang

  2. School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, China

    Hao-Sen Fan

  3. School of Energy Science and Engineering, Nanjing Tech University, Nanjing, 211816, China

    Yi Zhang

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  1. Sheng-Jun Lu
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Correspondence to Yu-Fei Zhang or Hao-Sen Fan.

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Lu, SJ., Lin, JY., Wang, CH. et al. Heterogeneous engineering of MnSe@NC@ReS2 core–shell nanowires for advanced sodium-/potassium-ion batteries. Rare Met. (2024). https://doi.org/10.1007/s12598-024-02650-8

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